摘要:
Systems and methods are provided for producing high quality synthesis gas from a fluidized coking system that includes an integrated gasifier. Additionally or alternately, systems and methods are provided for integrating a fluidized coking process, a coke gasification process, and processes for production of compounds from the synthesis gas generated during the coke gasification. The integrated process can also allow for reduced or minimized production of inorganic nitrogen compounds by using oxygen from an air separation unit as the oxygen source for gasification. Although the amount of nitrogen introduced as a diluent into the gasification will be reduced, minimized, or eliminated, the integrated process can also allow for gasification of coke while reducing, minimizing, or eliminating production of slag or other glass-like substances in the gasifier. Examples of compounds that can be produced from the synthesis gas include, but are not limited to, methanol, ammonia, and urea.
摘要:
The present invention pertains to new methods for generating energy and useful nitrogen compounds from captured carbon dioxide. It involves employing an osmotic engine, draw solution, and feed solution. An osmotic gradient between the solutions assists in generating energy and a solution of ammonium carbonate, ammonium bicarbonate or mixture thereof. This solution may be decomposed to form ammonia, carbon dioxide, a precipitate, or a mixture thereof.
摘要:
A method for synthesizing ammonia for agricultural fertilizers employs water (H2O) as the source of hydrogen (H2) in ammonia (NH3) synthesis, and gathers carbon monoxide (CO) as a limiting reagent for combining in a WGS (Water-Gas-Shift) reaction for producing hydrogen. The WGS reaction employs CO with the water to produce Carbon Dioxide (CO2) and H2, consuming undesirable CO from other industrial applications. A by-product of the process includes generating 1.5 mole of CO2 for each mole of ammonia synthesized. An intermediate step consumes 3 moles of hydrogen for each mole of Nitrogen (N2). The use of methane gas is avoided as the process employs CO and the WGS reaction as an exclusive source of H2 without introducing methane (CH4). A downstream synthesis of ammonia can be done through a fuel cell to produce electricity for the ammonia synthesis for further sustainability.
摘要:
The present invention pertains to new methods for generating energy and useful nitrogen compounds from captured carbon dioxide. It involves employing an osmotic engine, draw solution, and feed solution. An osmotic gradient between the solutions assists in generating energy and a solution of ammonium carbonate, ammonium bicarbonate or mixture thereof. This solution may be decomposed to form ammonia, carbon dioxide, a precipitate, or a mixture thereof.
摘要:
A method of forming urea by integration of an ammonia production process with that of a urea production process, as well as a system for the method is disclosed. Also, an alternative method of forming urea by integration of a part of an ammonia production process with that of a urea production process, as well as a system for the alternative method.
摘要:
A modular system and method for producing urea from bio-mass includes means and steps for “homogenizing” a biomass feedstock stream having components with different bulk density BTU content into a stream having a consistent bulk density BTU content. The steps include cleaning the incoming bio-mass feedstock stream to remove non-organic matter, blending the cleaned bio-mass feedstock stream to obtain a homogeneous blend having a consistent bulk density BTU content, and milling the homogeneous blend bio-mass feedstock stream to a predetermined size no greater than 12 mm.
摘要:
The present invention is directed to providing a method of producing synthetic fuels and organic chemicals from atmospheric carbon dioxide. Carbon dioxide gas is extracted from the atmosphere, hydrogen gas is obtained by splitting water, a mixture of the carbon dioxide gas and the hydrogen gas (synthesis gas) is generated, and the synthesis gas is converted into synthetic fuels and/or organic products. The present invention is also directed to utilizing a nuclear power reactor to provide power for the method of the present invention.
摘要:
A method for the simultaneous modernization of a plant for ammonia synthesis and a plant for urea synthesis, provides—inter alia—the arrangement of a carbamate synthesis section and a carbamate decomposition section, in order to obtain a predetermined amount of carbamate in aqueous solution and of hydrogen and nitrogen in gaseous phase which are fed to the existing sections for urea synthesis, respectively ammonia synthesis. Thanks to this method of modernization it is possible to remarkably increase the production capacity and at the same time to reduce the energy consumption of the urea and ammonia plants without being forced to replace or anyway overload the existing sections of decarbonation, methanation and compression, in general.
摘要:
The combined production of ammonia and urea by the reaction of gases containing hydrocarbons with steam is conducted by using a steam reformer, downstream secondary reformer, and shift converter. The ammonia synthesis gas (hydrogen, nitrogen and carbon dioxide) is subjected to a high pressure scrubbing step with a physical solvent, to remove the acid impurities, especially CO.sub.2. The pressure on the loaded solvent is reduced to a first intermediate pressure for degasing of the coabsorbed inerts and then to a second intermediate pressure for removal of the bulk of the absorbed CO.sub.2, which is then used for urea synthesis. To remove residual CO.sub.2, the solvent is stripped with air and the resultant air stream containing the stripped residual CO.sub.2 is fed to the secondary reformer.
摘要:
In an integrated flexible installation for producing ammonia and urea, the improved method which consists in that a portion of the gaseous stream comprising carbon dioxide, hydrogen and nitrogen is fed to a complementary decarbonation area and then admixed with a portion of a similar, but non-decarbonated stream of gas prior to entering the carbon-dioxide-absorption unit. Liquid ammonia is recovered from a portion of the ammoniated aqueous solution used for abating the ammonia and sent to a distillation column to recover liquid ammonia therefrom.