公开(公告)号：US06881803B2

公开(公告)日：2005-04-19

申请号：US10033673

申请日：2001-12-28

申请人： Toshio Endo ,  Tatsumi Fujii ,  Yasuo Tsuji ,  Morihito Saito

发明人： Toshio Endo ,  Tatsumi Fujii ,  Yasuo Tsuji ,  Morihito Saito

IPC分类号： C08F6/12 ,  C08F216/16 ,  C08F222/06 ,  C08F2/00

CPC分类号： C08F222/06 ,  C08F6/12 ,  C08F216/16

摘要： In the first aspect of the present invention, there is disclosed a method for producing a copolymer of an alkyl vinyl ether and maleic anhydride which comprises removing an organic solvent used in a reaction under a temperature so that a slurry state can be maintained. According to the first aspect, such a copolymer of the alkyl vinyl ether and maleic anhydride which contains a little amount of the solvent remaining therein as disclosed in the second aspect of the present invention, can be obtained.Further, it can be avoided that a specific viscosity of the copolymer of the alkyl vinyl ether and maleic anhydride is lowered, by means of a method for producing a copolymer of alkyl vinyl ether and maleic anhydride which comprises shielding oxygen in a polymerization, as disclosed in the third aspect of the present invention.

摘要翻译： 在本发明的第一方面，公开了一种烷基乙烯基醚和马来酸酐的共聚物的制造方法，其包括在温度下除去反应中使用的有机溶剂，从而可以保持浆料状态。 根据第一方面，可以获得如本发明第二方面所公开的含有少量溶剂的烷基乙烯基醚和马来酸酐的共聚物。 此外，可以避免通过烷基乙烯基醚和马来酸酐的共聚物的制备方法降低烷基乙烯基醚和马来酸酐的共聚物的比粘度，其包括在聚合中屏蔽氧，如所公开的 在本发明的第三方面。

公开(公告)号：US4379915A

公开(公告)日：1983-04-12

申请号：US352607

申请日：1982-02-23

申请人： Shoji Watanabe ,  Takuya Miho ,  Tatsumi Fujii

发明人： Shoji Watanabe ,  Takuya Miho ,  Tatsumi Fujii

IPC分类号： C08G63/00 ,  C08G18/42 ,  C08G63/08 ,  C08G63/78 ,  C08G63/82 ,  C08G63/10

CPC分类号： C08G18/4277 ,  C08G63/08 ,  C08G63/823

摘要： A lactone polymer has a narrow molecular weight distribution where a ratio of the weight average molecular weight to the number average molecular weight is in the range of from 1.1 to 2.0 and the molecular weight is 500 to 5,000.

摘要翻译： 内酯聚合物具有窄分子量分布，其中重均分子量与数均分子量的比例在1.1至2.0的范围内，分子量为500至5,000。

公开(公告)号：US5100999A

公开(公告)日：1992-03-31

申请号：US403434

申请日：1989-09-06

申请人： Takaaki Murai ,  Tatsumi Fujii

发明人： Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08G18/44 ,  C08G64/02 ,  C08G64/18

CPC分类号： C08G64/183 ,  C08G18/44 ,  C08G64/0208 ,  C08G2101/0008 ,  C08G2101/0025

摘要： A polycarbonatediol composition is disclosed having carbonate bonds and from about 1 to 40 ether bonds to one carbonate bond in a molecule, which can provide polyurethanes having high mechanical strength and heat and moisture resistibility, and furthermore having improved properties at low temperatures.Further disclosed is a polyurethane resin prepared by reaction of an organic diisocyanate compound with the polycarbonatediol composition. The polyurethane resin has excellent properties under low temperature conditions, while retaining high levels of mechanical strength, excellent resistibility under high heat and moisture conditions, etc., thereby maintaining a good balance of properties. The polyurethane resin in accordance with the present invention is useful in a very wide variety of forms, including spandex, rigid or flexible urethane foams, thermoplastic urethane elastomers and thermosetting urethane elastomers, adhesives, synthetic leather, paints, etc.

公开(公告)号：US5143997A

公开(公告)日：1992-09-01

申请号：US595423

申请日：1990-10-11

申请人： Toshio Endo ,  Takaaki Murai ,  Tatsumi Fujii

发明人： Toshio Endo ,  Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08F299/02 ,  C08G18/44 ,  C08G18/81 ,  C08G64/02

CPC分类号： C08G64/0291 ,  C08F299/024 ,  C08G18/44 ,  C08G18/8175 ,  C08G64/0216

摘要： A polycarbonate polyol composition which can be used to prepare polycarbonate(meth)acrylate and urethane(meth)acrylate compositions is obtained by the ester interchange reaction of a polycarbonate diol composition with a triol and/or tetraol. The (meth)acrylate compositions have excellent photo and electron beam curability and the cured layers prepared therefrom have excellent heat resistance under moisture conditions.

公开(公告)号：US4978691A

公开(公告)日：1990-12-18

申请号：US356909

申请日：1989-05-25

申请人： Takaaki Murai ,  Tatsumi Fujii

发明人： Takaaki Murai ,  Tatsumi Fujii

IPC分类号： C08G18/44 ,  C08G64/02

CPC分类号： C08G18/44 ,  C08G64/0208 ,  C08G2101/0008 ,  C08G2101/0025

摘要： A polycarbonatediol composition is disclosed having the property of being liquid at room temperature because of its crystallinity being disordered due to random structures, which comprises a mixture of 1,6-hexanediol and polyvalent alcohol having at least one side chain. Accordingly, the disclosed composition has excellent processability in the case of preparing a polyurethane resin, etc.Further disclosed is a polyurethane resin prepared by reaction of an organic diisocyanate compound with the polycarbonatediol composition. The polyurethane resin has excellent properties under low temperature conditions, while retaining high levels of mechanical strength, excellent resistibility under high heat and moisture conditions, etc., thereby maintaining a good balance of properties. The polyurethane resin in accordance with the present invention, is useful in a very wide variety of forms, including spandex, rigid or flexible urethane foams, thermoplastic urethane elastomers and thermosetting urethane elastomers, adhesives, synthetic leather, and paints, etc.

公开(公告)号：US20070238819A1

公开(公告)日：2007-10-11

申请号：US10574912

申请日：2004-10-07

申请人： Shuso Iyoshi ,  Tatsumi Fujii

发明人： Shuso Iyoshi ,  Tatsumi Fujii

IPC分类号： C08G18/42 ,  C09D175/10

CPC分类号： C09D175/06 ,  C08G18/4269

摘要： The present invention relates to a process for producing a curing agent for a polyurethane paint, which comprises an aliphatic or alicyclic diisocyanate and a polyester polyol, wherein the polyester polyol is a copolymerized lactone polyol obtained by a ring-opening copolymerization of at least two members of cyclic lactone compounds each represented by the following formula (I) in the presence of a low molecular weight compound having at least two active hydrogen groups as an initiator. By using at least two members of cyclic lactone compounds, there is provided a curing agent for a polyurethane paint which is capable of forming a paint film having high mechanical strength, particularly high flexibility or impact resistance under low temperatures, and excellent in gloss retention.

摘要翻译： 本发明涉及一种聚氨酯涂料固化剂的制造方法，其包括脂肪族或脂环族二异氰酸酯和聚酯多元醇，其中，所述聚酯多元醇是通过至少两个成员的开环共聚得到的共聚内酯多元醇 的各种由下式（I）表示的环状内酯化合物在具有至少两个活性氢基团的低分子量化合物作为引发剂存在下进行。 通过使用至少两种环状内酯化合物，可提供一种聚氨酯涂料用固化剂，其能够形成在低温下具有高机械强度，特别高的柔韧性或耐冲击性的漆膜，并且具有优异的保光性。

公开(公告)号：US20070232773A1

公开(公告)日：2007-10-04

申请号：US11727098

申请日：2007-03-23

申请人： Toshio Endo ,  Hidetoshi Omori ,  Tatsumi Fujii

发明人： Toshio Endo ,  Hidetoshi Omori ,  Tatsumi Fujii

IPC分类号： C08G18/00 ,  C08G63/82

CPC分类号： C08G63/78 ,  C08G18/0823 ,  C08G18/0866 ,  C08G18/12 ,  C08G18/4018 ,  C08G18/4277 ,  C08G18/4854 ,  C08G18/755 ,  C08G63/08 ,  C08G63/912 ,  C08G18/3234

摘要： A cyclic ester (e.g., a lactone such as ε-caprolactone) is ring-opening addition polymerized with a dihydroxycarboxylic acid in the presence of a basic compound (e.g., an amine). In a polyester polyol obtained by such a process, at least part of a carboxyl group of the polyester polyol forms a carboxylate with the basic compound, and the content of the dihydroxycarboxylic acid in a free form can be remarkably reduced (for example, reduced to not more than 5% by weight relative to the total polyester polyol). According to the present invention, a polyester polyol having a reduced content of a free or unreacted dihydroxycarboxylic acid is provided even in the case of using a dihydroxycarboxylic acid (e.g., a dimethylolalkanoic acid such as dimethylolpropionic acid) as an initiator.

摘要翻译： 环状酯（例如内酯如ε-己内酯）在碱性化合物（例如胺）的存在下与二羟基羧酸加成聚合。 在通过这种方法获得的聚酯多元醇中，聚酯多元醇的至少一部分羧基与碱性化合物形成羧酸酯，并且游离形式的二羟基羧酸的含量可以显着降低（例如，降低至 相对于总聚酯多元醇为5重量％以下）。 根据本发明，即使使用二羟基羧酸（例如二羟甲基链烷酸如二羟甲基丙酸）作为引发剂，也提供了游离或未反应的二羟基羧酸含量降低的聚酯多元醇。