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公开(公告)号：US08492593B2
公开(公告)日：2013-07-23
申请号：US13210986
申请日：2011-08-16
IPC分类号： C07C45/50 , C07C233/00 , C07F9/02 , C07F9/26 , B01J31/02
CPC分类号： C07F9/26
摘要： Amido-fluorophosphite compounds and catalyst systems comprising at least one amido-fluorophosphite ligand compound in combination with a transition metal are described. Moreover, the use of amido-fluorophosphite containing catalysts for transition metal catalyzed processes, especially to the hydroformylation of various olefins to produce aldehydes are also described.
摘要翻译： 描述了包含至少一种酰胺 - 氟亚磷酸酯配体化合物与过渡金属的酰胺 - 氟亚磷酸酯化合物和催化剂体系。 此外，还描述了使用含酰基 - 氟亚磷酸酯的催化剂用于过渡金属催化的方法，特别是各种烯烃的加氢甲酰化以产生醛。
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公开(公告)号：US07420093B2
公开(公告)日：2008-09-02
申请号：US11854210
申请日：2007-09-12
IPC分类号： C07C45/50
摘要： Disclosed are processes for the preparation of glycolaldehyde in which formaldehyde is contacted with carbon monoxide and hydrogen in the presence of a rhodium catalyst and a solvent containing at least one N,N-dihexylbutyramide. The glycolaldehyde product is recovered by extraction with water. The process provides high selectivity to glycolaldehyde and efficient separation of hydroformylation products from the solvent and rhodium catalyst.
摘要翻译： 公开了在铑催化剂和含有至少一种N，N-二己基丁酰胺的溶剂的存在下，甲醛与一氧化碳和氢气接触的方法。 通过用水萃取来回收乙醇醛产物。 该方法为乙二醇提供高选择性，并且有效地从溶剂和铑催化剂中分离加氢甲酰化产物。
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公开(公告)号：US20080154067A1
公开(公告)日：2008-06-26
申请号：US11941217
申请日：2007-11-16
CPC分类号： B01J31/1865 , B01J31/28 , B01J2231/321 , B01J2531/004 , B01J2531/822
摘要： Disclosed are catalyst solutions for preparing aldehydes with variable normal- to iso-aldehyde ratios comprising one or more phosphonite ligands, rhodium, and a hydroformylation solvent. Also disclosed is a process for preparing aldehydes with variable normal- to iso-aldehyde ratios comprising contacting an olefin, hydrogen, and carbon monoxide with one or more phosphonite ligands, rhodium, and a hydroformylation solvent. The phosphonite-based catalyst solutions provide the ability to manipulate the normal- to iso-aldehyde ratio by varying one or more process variables including carbon monoxide partial pressure, temperature, and gram moles ligand to gram atoms rhodium.
摘要翻译： 公开了用于制备含有一种或多种亚膦酸酯配体，铑和加氢甲酰化溶剂的具有不同正醛与异醛比例的醛的催化剂溶液。 还公开了一种制备具有可变正醛与异醛比例的醛的方法，包括使烯烃，氢气和一氧化碳与一种或多种亚膦酸盐配体，铑和加氢甲酰化溶剂接触。 基于亚膦酸酯的催化剂溶液通过改变一种或多种工艺变量（包括一氧化碳分压，温度和克数摩尔配体与克原子铑）来提供操纵正醛与异醛比的能力。
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公开(公告)号：US06906225B2
公开(公告)日：2005-06-14
申请号：US10896666
申请日：2004-07-22
CPC分类号： C07F15/065 , B01J31/185 , B01J2531/80 , B01J2531/821 , B01J2531/824 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/0093 , C07C47/02
摘要： Disclosed are novel catalyst systems comprising (1) a diorgano fluorophosphite ligand; (2) rhodium, wherein the ratio of gram moles fluorophosphite ligand (1) to gram atoms of rhodium is at least 1:1; and (3) a Group VIII metal, other than rhodium, or Group VIII metal-containing compound, in an amount effective to reduce the formation of HF during the use of the catalyst system. The presence of the other Group VIII metal decreases the amount of hydrogen fluoride produced during the use of the catalyst system. The hydrogen fluoride originates from very low level degradation of the ligand. Also disclosed are novel catalyst solutions of the aforesaid catalyst system and the use of the catalyst system in the hydroformylation of olefins to produce aldehydes.
摘要翻译： 公开了新型催化剂体系，其包括（1）二有机氟亚磷酸酯配体; （2）铑，其中氟亚磷酸酯配体（1）的克摩尔与铑的克原子之比至少为1:1; 和（3）Ⅷ族金属，除了铑或含Ⅷ族金属的化合物之外，其量可以有效地在催化剂体系的使用过程中减少HF的形成。 其他VIII族金属的存在降低了在使用催化剂体系期间产生的氟化氢的量。 氟化氢源于配体极低水平的降解。 还公开了上述催化剂体系的新型催化剂溶液以及催化剂体系在烯烃加氢甲酰化中用于生产醛的用途。
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公开(公告)号：US07615671B2
公开(公告)日：2009-11-10
申请号：US12274787
申请日：2008-11-20
IPC分类号： C07C29/149 , C07C29/141 , C07C29/145
CPC分类号： C07C29/149 , C07C31/207 , C07C31/202 , C07C31/205
摘要： Disclosed is a process for the preparation of 1,2-glycols by hydrogenation of 1,2-dioxygenated organic compounds in the presence of a catalyst composition comprising a ruthenium compound, a trivalent phosphorus compound selected from 1,1,1-tris(diarylphosphinomethyl)alkyl or substituted alkyl, and a promoter selected from Lewis acids, protic acids having an ionization constant (Ki) of 5×10−3 or greater, and onium salts. The process is useful for the hydrogenation of glycolic acid or derivatives thereof to ethylene glycol.
摘要翻译： 公开了在催化剂组合物存在下1,2-二氧化有机化合物的氢化制备1,2-二醇的方法，该催化剂组合物包含钌化合物，三价磷化合物，其选自1,1,1-三（二芳基膦基甲基 ）烷基或取代的烷基，以及选自路易斯酸，电离常数（Ki）为5×10 -3或更大的质子酸和鎓盐的促进剂。 该方法可用于将乙醇酸或其衍生物氢化成乙二醇。
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公开(公告)号：US20080081931A1
公开(公告)日：2008-04-03
申请号：US11854210
申请日：2007-09-12
IPC分类号： C07C45/49
摘要： Disclosed are processes for the preparation of glycolaldehyde in which formaldehyde is contacted with carbon monoxide and hydrogen in the presence of a rhodium catalyst and a solvent containing at least one N,N-dihexylbutyramide. The glycolaldehyde product is recovered by extraction with water. The process provides high selectivity to glycolaldehyde and efficient separation of hydroformylation products from the solvent and rhodium catalyst.
摘要翻译： 公开了在铑催化剂和含有至少一种N，N-二己基丁酰胺的溶剂的存在下，甲醛与一氧化碳和氢气接触的方法。 通过用水萃取来回收乙醇醛产物。 该方法为乙二醇提供高选择性，并且有效地从溶剂和铑催化剂中分离加氢甲酰化产物。
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7.发明授权
公开(公告)号：US6130358A
公开(公告)日：2000-10-10
申请号：US173771
申请日：1998-10-16
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07C47/12 , C07F9/146 , C07F9/6574 , C07F15/00
CPC分类号： C07F15/008 , B01J31/185 , C07C45/50 , B01J2231/321 , B01J2531/822
摘要： This invention relates to a hydroformylation process for preparing an aldehyde, which comprises reacting an olefin with hydrogen and carbon monoxide in the presence of a catalyst solution comprising of rhodium, a hydroformylation solvent and a chlorophosphite compound having the general formula ##STR1##
摘要翻译： 本发明涉及一种用于制备醛的加氢甲酰化方法，其包括在包含铑，加氢甲酰化溶剂和具有通式
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公开(公告)号：US20090299099A1
公开(公告)日：2009-12-03
申请号：US12128414
申请日：2008-05-28
CPC分类号： C07F9/65742 , C07F9/65744 , Y02P20/142
摘要： This invention is directed to a class of compounds that can be both monodentate and bidentate in their association with a transition metal to form a catalyst for reactions such as the hydroformylation of olefins to produce aldehydes. The compounds contain two phosphorus atoms having different steric and/or electronic nature. In hydroformylation catalysts, the compounds advantageously can produce a variable n/iso product mixture of aldehyde products that can be varied by simply changing process variables such as [H2]/[CO] partial pressure gas ratio or temperature/inert gas partial pressure.
摘要翻译： 本发明涉及一类可以与过渡金属缔合形成单齿和二齿的化合物，以形成用于反应的催化剂，例如烯烃的加氢甲酰化以产生醛。 这些化合物含有两个具有不同立体和/或电子性质的磷原子。 在加氢甲酰化催化剂中，化合物有利地可以产生醛产物的可变的n /异产物混合物，其可以通过简单地改变诸如[H 2] / [CO]分压气体比或温度/惰性气体分压的过程变量来改变。
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9.发明授权Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process 有权氟代亚磷酸盐 - 金属催化剂体系在加氢甲酰化过程中的环氧化稳定性公开(公告)号：US06693219B2
公开(公告)日：2004-02-17
申请号：US10145922
申请日：2002-05-15
申请人： Thomas Allen Puckette , Ginette Struck Tolleson , Thomas James Devon , Jerome L. Stavinoha, Jr.
发明人： Thomas Allen Puckette , Ginette Struck Tolleson , Thomas James Devon , Jerome L. Stavinoha, Jr.
IPC分类号： C07C4549
摘要： A process for stabilizing a fluorophosphite ligand in a hydroformylation reaction mixture having an &agr;-olefin, hydrogen, carbon monoxide and a catalyst composition having a combination of a rhodium containing compound and one or more fluorophosphite compounds having the general formula: wherein R1 and R2 are hydrocarbyl radicals which contain a total of up to about 40 carbon atoms, the process includes the step of adding to the reaction mixture an epoxide in a sufficient amount to reduce the degradation of the fluorophosphite ligand.
摘要翻译： 一种用于在具有α-烯烃，氢气，一氧化碳和具有铑化合物和一种或多种具有以下通式的氟代亚磷酸酯化合物的组合的催化剂组合物的加氢甲酰基化反应混合物中稳定氟亚磷酸酯配体的方法：其中R 1， 并且R 2是含有总共高达约40个碳原子的烃基，该方法包括向反应混合物中加入足够量的环氧化物以降低氟亚磷酸酯配体降解的步骤。
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10.发明授权
公开(公告)号：US5840647A
公开(公告)日：1998-11-24
申请号：US929687
申请日：1997-09-15
IPC分类号： B01J31/18 , C07C45/50 , C07F9/6571 , B01J27/188 , A01N43/30 , B01J27/13 , C07D209/82
CPC分类号： C07C45/50 , B01J31/1845 , C07F9/6571 , B01J2231/321 , B01J2531/80 , B01J2531/822
摘要： Disclosed are catalyst systems comprising one or more transition metals selected from the Group VIII metals and rhenium and one or more fluorophosphite compounds having the general formula ##STR1## wherein R.sup.1 and R.sup.2 are hydrocarbyl radicals. Also disclosed are catalyst solutions comprising one or more the above fluorophosphite compounds, rhodium and a hydroformylation solvent, and hydroformylation processes wherein olefins are contacted with carbon monoxide, hydrogen and the catalyst solution to produce aldehydes.
摘要翻译： 公开了包含一种或多种选自VIII族金属和铼的过渡金属和一种或多种具有通式（I）的氟亚磷酸酯化合物的催化剂体系，其中R 1和R 2是烃基。 还公开了包含一种或多种上述氟代亚磷酸酯化合物，铑和加氢甲酰化溶剂的催化剂溶液，以及其中烯烃与一氧化碳，氢气和催化剂溶液接触以产生醛的加氢甲酰化方法。
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