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1.发明授权
公开(公告)号：US4714586A
公开(公告)日：1987-12-22
申请号：US823718
申请日：1986-01-29
申请人： Thomas E. Swarr , Wayne G. Wnuck
发明人： Thomas E. Swarr , Wayne G. Wnuck
CPC分类号： H01M8/141 , C22C1/1078 , C22C32/0026 , H01M4/8882 , H01M2004/8684 , H01M2008/147 , H01M2300/0051 , H01M4/8652 , Y02E60/526
摘要： A method is disclosed for preparing a dimensionally stable electrode structure, particularly nickel-chromium anodes, for use in a molten carbonate fuel cell stack. A low-chromium to nickel alloy is provided and oxidized in a mildly oxidizing gas of sufficient oxidation potential to oxidize chromium in the alloy structure. Typically, a steam/H.sub.2 gas mixture in a ratio of about 100/1 and at a temperature below 800.degree. C. is used as the oxidizing medium. This method permits the use of less than 5 weight percent chromium in nickel alloy electrodes while obtaining good resistance to creep in the electrodes of a fuel cell stack.
摘要翻译： 公开了一种用于制备用于熔融碳酸盐燃料电池堆的尺寸稳定的电极结构，特别是镍 - 铬阳极的方法。 提供低铬至镍合金并在具有足够氧化电势的温和氧化气体中氧化以氧化合金结构中的铬。 通常，使用约100/1的比例和低于800℃的蒸汽/ H 2气体混合物作为氧化介质。 该方法允许在镍合金电极中使用小于5重量％的铬，同时在燃料电池堆的电极中获得良好的蠕变阻力。
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公开(公告)号：US4652411A
公开(公告)日：1987-03-24
申请号：US612952
申请日：1984-05-23
IPC分类号： B28B1/32 , C04B26/02 , C04B35/01 , C04B35/634 , C04B35/636 , C04B38/00 , C04B38/08 , H01M4/86 , H01M4/88 , H01M4/90 , H01M8/14 , B29C67/20
CPC分类号： C04B35/63404 , B28B1/32 , C04B26/02 , C04B35/01 , C04B35/634 , C04B35/63416 , C04B35/6365 , C04B38/009 , C04B38/08 , H01M4/8621 , H01M4/8828 , H01M4/8857 , H01M4/8882 , H01M4/9016 , H01M8/141 , H01M2004/8684 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , H01M4/8647 , Y02E60/526
摘要： A method of forming thin porous sheets of ceramic material for use as electrodes or other components in a molten carbonate fuel cell is disclosed. The method involves spray drying a slurry of fine ceramic particles in liquid carrier to produce generally spherical agglomerates of high porosity and a rough surface texture. The ceramic particles may include the electrode catalyst and the agglomerates can be calcined to improve mechanical strength. After slurrying with suitable volatile material and binder tape casting is used to form sheets that are sufficiently strong for further processing and handling in the assembly of a high temperature fuel cell.
摘要翻译： 公开了一种在熔融碳酸盐燃料电池中形成用作电极或其它组分的陶瓷材料薄多孔片的方法。 该方法包括将液体载体中的细陶瓷颗粒的浆料喷雾干燥以产生高孔隙率和粗糙表面纹理的大致球形的聚集体。 陶瓷颗粒可以包括电极催化剂，并且可以煅烧附聚物以提高机械强度。 在用合适的挥发性物质浆料化之后，使用粘合剂带铸造形成足够强的片材，用于在高温燃料电池组件中的进一步加工和处理。
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公开(公告)号：US4800052A
公开(公告)日：1989-01-24
申请号：US943232
申请日：1986-12-17
申请人： Thomas E. Swarr , John C. Trocciola
发明人： Thomas E. Swarr , John C. Trocciola
CPC分类号： H01M4/9016 , H01M4/32 , H01M4/8621 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： Molten carbonate fuel cell cathodes formed from a composition comprising oxides of nickel, lithium salts and barium salts having improved strength. These cathodes are fabricated by prefiring oxides of nickel and optionally lithium salts. The prefired powder is optionally leached with an organic acid and optional barium salts may be added. These powders are formed into an electrode and sintered. The resulting electrodes have improved strength.
摘要翻译： 由包含具有改进的强度的镍，锂盐和钡盐的氧化物的组合物形成的熔融碳酸盐燃料电池阴极。 这些阴极通过预处理镍和任选的锂盐的氧化物来制造。 预制粉末任选地用有机酸浸出，并且可以加入任选的钡盐。 将这些粉末形成电极并烧结。 所得电极具有改善的强度。
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公开(公告)号：US5001021A
公开(公告)日：1991-03-19
申请号：US450420
申请日：1989-12-14
CPC分类号： H01M8/126 , C04B35/50 , Y02E60/525 , Y02P70/56
摘要： A ceria electrolyte composition is disclosed. The composition provides high ionic conductivity and low electronic conductivity under reducing conditions. Fuel cells employing the disclosed composition exhibit improved efficiency and power density.
摘要翻译： 公开了二氧化铈电解质组合物。 该组合物在还原条件下提供高离子导电性和低电子导电性。 使用所公开的组合物的燃料电池显示出提高的效率和功率密度。
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公开(公告)号：US4708917A
公开(公告)日：1987-11-24
申请号：US812218
申请日：1985-12-23
申请人： Thomas E. Swarr , John C. Trocciola
发明人： Thomas E. Swarr , John C. Trocciola
CPC分类号： H01M4/9016 , H01M4/32 , H01M4/8621 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要： Molten carbonate fuel cell cathodes formed from a composition comprising oxides of nickel, lithium salts and barium salts having improved strength. These cathodes are fabricated by prefiring oxides of nickel and optionally lithium salts. The prefired powder is optionally leached with an organic acid and optional barium salts may be added. These powders are formed into an electrode and sintered. The resulting electrodes have improved strength.
摘要翻译： 由包含具有改进的强度的镍，锂盐和钡盐的氧化物的组合物形成的熔融碳酸盐燃料电池阴极。 这些阴极通过预处理镍和任选的锂盐的氧化物来制造。 预制粉末任选地用有机酸浸出，并且可以加入任选的钡盐。 将这些粉末形成电极并烧结。 所得电极具有改善的强度。
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