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公开(公告)号:US4297419A
公开(公告)日:1981-10-27
申请号:US189888
申请日:1980-09-24
CPC分类号: H01M4/9016 , H01M4/8621 , H01M8/142 , H01M2004/8684 , H01M2008/147 , H01M2300/0051 , H01M8/0295 , Y02E60/526
摘要: A molten carbonate fuel cell anode-matrix composite and a molten carbonate fuel cell including such composite are described. The anode-matrix material comprises carbonate electrolyte in intimate combination with ceria anode-matrix material. The anode-matrix material shows substantially no phase change or reaction with the electrolyte after at least 2000 hours under molten carbonate fuel cell operating conditions.
摘要翻译: 描述了一种熔融碳酸盐燃料电池阳极 - 基质复合材料和包括这种复合材料的熔融碳酸盐燃料电池。 阳极基体材料包括与二氧化铈阳极基质材料紧密结合的碳酸盐电解质。 在熔融碳酸盐燃料电池工作条件下,阳极基质材料在至少2000小时后基本上不显示出与电解质的相变或反应。
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公开(公告)号:US4028324A
公开(公告)日:1977-06-07
申请号:US641204
申请日:1975-12-16
IPC分类号: H01M2/02 , C08L1/00 , C08L27/00 , C08L27/12 , C08L27/18 , C09K3/10 , H01M2/08 , H01M8/08 , C08K5/02 , C10M5/18 , C10M7/28
CPC分类号: H01M8/08 , C08L27/18 , C09K3/1028 , H01M2/08 , C09K2200/0208 , C09K2200/0243 , C09K2200/0411 , C09K2200/0637 , C09K2200/0692 , Y02P70/56
摘要: An extruded seal material which is stable in phosphoric acid is composed of fibrillating polytetrafluoroethylene, a halogenated oil, and a filler. Preferably the oil is a fluorocarbon oil and the filler is either non-fibrillating polytetrafluoroethylene, silicon carbide or graphite, all of which are stable in phosphoric acid at temperatures up to at least 400.degree. F. This seal material is particularly suited for use in the environment of a phosphoric acid fuel cell.
摘要翻译: 在磷酸中稳定的挤出密封材料由原纤化聚四氟乙烯,卤化油和填料组成。 优选地,油是氟碳油,并且填料是非原纤化聚四氟乙烯,碳化硅或石墨,所有这些在高达至少400°F的温度下在磷酸中是稳定的。该密封材料特别适用于 磷酸燃料电池的环境。
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公开(公告)号:US4937220A
公开(公告)日:1990-06-26
申请号:US230385
申请日:1988-08-08
CPC分类号: H01M4/926 , B01J23/64 , H01M4/92 , H01M2004/8689 , H01M2300/0008
摘要: The rate of noble metal crystallite recrystallization on a carbon-supported noble metal catalyst is reduced by dispersing two or more different kinds of noble metal-containing crystallites onto the surface of the carbon support. The crystallites have either different unit cell configurations or different unit cell sizes. The reduced rate of noble metal crystallite recrystallization results, over a period of time, in higher crystallite surface area and therefore, better catalyst performance compared to conventional carbon-supported noble metal catalysts. Fuel cells which incorporate such improved catalysts as cathode catalysts are capable of operating at maximum power production for longer periods of time than fuel cells which use conventional catalysts as cathode catalysts.
摘要翻译: 通过将两种或更多种不同种类的含贵金属的微晶分散在碳载体的表面上,可以降低在碳负载的贵金属催化剂上贵金属微晶重结晶的速率。 微晶具有不同的晶胞结构或不同的晶胞尺寸。 在一段时间内,贵金属微晶重结晶速率降低导致较高的微晶表面积,因此与传统的碳负载型贵金属催化剂相比,催化剂性能更好。 结合这种改进的催化剂作为阴极催化剂的燃料电池能够比使用常规催化剂作为阴极催化剂的燃料电池更长时间地进行最大功率生产。
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公开(公告)号:US4317866A
公开(公告)日:1982-03-02
申请号:US189887
申请日:1980-09-24
CPC分类号: H01M4/8621 , H01M8/14 , H01M2004/8684 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要: A molten carbonate fuel cell ceria anode and a molten carbonate fuel cell including such anode are described. The ceria anode, in addition to having the requisite electrolyte compatibility, catalytic activity, and electron conductivity, has improved oxidation resistance and structural stability as well.
摘要翻译: 描述了熔融碳酸盐燃料电池二氧化铈阳极和包括这种阳极的熔融碳酸盐燃料电池。 二氧化铈阳极除了具有所需的电解质相容性,催化活性和电子传导性之外,还具有改善的抗氧化性和结构稳定性。
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公开(公告)号:US3945844A
公开(公告)日:1976-03-23
申请号:US172655
申请日:1971-08-18
CPC分类号: H01M8/04074
摘要: An electrochemical cell comprising an anode, a cathode, and an electrolyte in combination with support or coolant plates fabricated from a polymer/metal composite, such as polysulfone/nickel, is described. The plates are relatively inexpensive, easily fabricated, have good thermal conductivity, low electrical resistance, and good structural stability.
摘要翻译: 描述了包括阳极,阴极和电解质以及由聚合物/金属复合物如聚砜/镍制成的支撑体或冷却剂板的电化学电池。 这些板相对便宜,易于制造,具有良好的导热性,低电阻和良好的结构稳定性。
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公开(公告)号:US4652411A
公开(公告)日:1987-03-24
申请号:US612952
申请日:1984-05-23
IPC分类号: B28B1/32 , C04B26/02 , C04B35/01 , C04B35/634 , C04B35/636 , C04B38/00 , C04B38/08 , H01M4/86 , H01M4/88 , H01M4/90 , H01M8/14 , B29C67/20
CPC分类号: C04B35/63404 , B28B1/32 , C04B26/02 , C04B35/01 , C04B35/634 , C04B35/63416 , C04B35/6365 , C04B38/009 , C04B38/08 , H01M4/8621 , H01M4/8828 , H01M4/8857 , H01M4/8882 , H01M4/9016 , H01M8/141 , H01M2004/8684 , H01M2004/8689 , H01M2008/147 , H01M2300/0051 , H01M4/8647 , Y02E60/526
摘要: A method of forming thin porous sheets of ceramic material for use as electrodes or other components in a molten carbonate fuel cell is disclosed. The method involves spray drying a slurry of fine ceramic particles in liquid carrier to produce generally spherical agglomerates of high porosity and a rough surface texture. The ceramic particles may include the electrode catalyst and the agglomerates can be calcined to improve mechanical strength. After slurrying with suitable volatile material and binder tape casting is used to form sheets that are sufficiently strong for further processing and handling in the assembly of a high temperature fuel cell.
摘要翻译: 公开了一种在熔融碳酸盐燃料电池中形成用作电极或其它组分的陶瓷材料薄多孔片的方法。 该方法包括将液体载体中的细陶瓷颗粒的浆料喷雾干燥以产生高孔隙率和粗糙表面纹理的大致球形的聚集体。 陶瓷颗粒可以包括电极催化剂,并且可以煅烧附聚物以提高机械强度。 在用合适的挥发性物质浆料化之后,使用粘合剂带铸造形成足够强的片材,用于在高温燃料电池组件中的进一步加工和处理。
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公开(公告)号:US4808354A
公开(公告)日:1989-02-28
申请号:US64358
申请日:1987-06-22
申请人: Richard C. Nickols
发明人: Richard C. Nickols
IPC分类号: C04B35/52 , C04B35/532 , B29C43/02 , B29C45/00 , B29L31/34
CPC分类号: C04B35/52 , C04B35/532
摘要: A method for fabricating electrical discharge machining electrodes includes forming a thin electrode shell by compression molding a mixture of carbon particles and an organic binder. The electrode shell is then thermally processed to graphitize the organic binder and carbon producing an electrode with the structural integrity needed so as to be useful in electrical discharge machining.
摘要翻译: 一种制造放电加工电极的方法包括通过压缩模制碳颗粒和有机粘合剂的混合物来形成薄电极壳。 然后对电极壳进行热处理以对有机粘合剂和碳进行石墨化,产生具有所需结构完整性的电极,从而可用于放电加工。
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公开(公告)号:US4755429A
公开(公告)日:1988-07-05
申请号:US926274
申请日:1986-11-03
申请人: Richard C. Nickols , Paul R. Watson
发明人: Richard C. Nickols , Paul R. Watson
CPC分类号: F16B11/006 , B29C65/4815 , B29C66/02245 , B29C66/1162 , B29C66/14 , B29C66/30322 , B29C66/43 , B29C66/7212 , C04B35/63436 , C04B35/645 , C04B37/008 , H01M8/0297 , B29C66/919 , B29C66/929 , B29K2995/0082 , C04B2235/656 , C04B2235/6567 , C04B2237/363 , C04B2237/64 , C04B2237/704 , C04B2237/708 , Y02P70/56 , Y10S403/05 , Y10T403/655 , Y10T428/195 , Y10T428/24777 , Y10T428/30
摘要: A graphite separator plate for an electrochemical cell stack is formed from component parts which are joined together edge to edge. The edges of the plates are scarfed to increase the bond area and a heat activated fluoropolymer adhesive is used to bond adjacent plates together. This allows production of plates with a larger surface areas thereby improving the economics of the cell stack.
摘要翻译: 用于电化学电池堆的石墨隔板由从边到边连接在一起的部件形成。 板的边缘被切割以增加粘合面积,并且使用热活化的氟聚合物粘合剂将相邻的板粘合在一起。 这允许生产具有更大表面积的板,从而改善电池堆的经济性。
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公开(公告)号:US4609595A
公开(公告)日:1986-09-02
申请号:US661850
申请日:1984-10-17
申请人: Richard C. Nickols
发明人: Richard C. Nickols
CPC分类号: H01M8/0247 , H01M8/0206 , H01M8/021 , H01M8/0228 , H01M8/0271 , H01M8/244 , H01M2008/147 , H01M2300/0051 , Y02E60/526
摘要: In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.
摘要翻译: 在熔融碳酸盐燃料电池的堆叠阵列中,燃料电池分离器位于相邻的燃料电池之间,以提供隔离以及它们之间的导电路径。 燃料电池分离器的中心部分包括大致矩形的扁平电导体。 围绕隔板的平坦部分的周边设置有多个细长的弹性凸缘,其围绕燃料电池的边缘形成气密密封。 通过一个细长的凸缘弹性地接合分离器的中心部分的相应边缘,优选地由诸如钇,铁,铝或铬的合金的非腐蚀性材料组成的密封凸缘形成紧密的湿密封件 将燃料电池的腐蚀元件限制在其中。 这种布置允许可能高度受到腐蚀和溶解的良好导电材料与熔融碳酸盐燃料电池的燃料电池隔板中的耐腐蚀材料组合使用,以改善燃料电池导电性和气密湿密封 。
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公开(公告)号:US3940285A
公开(公告)日:1976-02-24
申请号:US532565
申请日:1974-12-13
IPC分类号: H01M8/04
CPC分类号: H01M8/04029
摘要: The internal coolant system of a fuel cell power plant utilizes a gas in the coolant fluid to inhibit the corrosion of those fuel cell components that corrode due to shunt currents flowing through the coolant fluid. In a preferred embodiment hydrogen gas is used.
摘要翻译: 燃料电池发电厂的内部冷却剂系统利用冷却剂流体中的气体来抑制由于流过冷却剂流体的分流电流而腐蚀的那些燃料电池部件的腐蚀。 在优选的实施方案中,使用氢气。
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