公开(公告)号：US06852446B2

公开(公告)日：2005-02-08

申请号：US10289784

申请日：2002-11-07

申请人： Thomas J. Barbarich

发明人： Thomas J. Barbarich

IPC分类号： H01M6/16 ,  H01M2/16 ,  H01M4/02 ,  H01M4/131 ,  H01M4/133 ,  H01M4/136 ,  H01M4/38 ,  H01M4/40 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/36 ,  H01M6/04

CPC分类号： H01M6/166 ,  H01M2/1653 ,  H01M4/131 ,  H01M4/133 ,  H01M4/136 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5815 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M2004/028

摘要： A non-aqueous electric current producing electrochemical cell is provided comprising an anode and a cathode, an ionically permeable separator interposed between the anode and the cathode, and a non-aqueous electrolyte, the electrolyte comprising an ionically conducting salt in a non-aqueous medium, the ionically conducting salt corresponding to the formula: M+(Z*(J*)j(X*)x)−, wherein: M is a lithium atom, Z* is an anion group containing two or more Lewis basic sites and comprising less than 50 atoms not including hydrogen atoms, J* independently each occurance is a Lewis acid coordinated to at least one Lewis basic site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, X* independently each occurrence is selected from the group consisting of H, C1-C4 alkyl, alkoxide, halide and mixtures thereof, j is an integer from 2 to 12, and x is an integer from 0 to 4.

摘要翻译： 提供了一种非水电流生成电化学电池，其包括阳极和阴极，介于阳极和阴极之间的离子渗透隔离体和非水电解质，电解质在非水介质中包含离子导电盐 对应于下式的离子导电盐：其中：M是锂原子，Z *是含有两个或更多个路易斯碱性位点并且包含小于50个不包括氢原子的原子的阴离子基团，J *独立地是一个路易斯 酸与Z *的至少一个路易斯碱基位点配位，并且任选地两个或更多个这样的J *基团可以在具有多个路易斯酸性官能团的部分中连接在一起，X *独立地每次出现时选自H，C1 -C4烷基，醇盐，卤化物及其混合物，j为2〜12的整数，x为0〜4的整数。

公开(公告)号：US20090269676A1

公开(公告)日：2009-10-29

申请号：US12431792

申请日：2009-04-29

申请人： Thomas J. Barbarich

发明人： Thomas J. Barbarich

IPC分类号： H01M10/26 ,  H01M6/16

CPC分类号： H01M10/0568 ,  H01B1/122 ,  H01M6/168 ,  H01M10/052 ,  H01M10/0569

摘要： A non-aqueous electrolyte for an electric current producing electrochemical cell is provided comprising an ionically conductive salt and an additional ionically conducting salt in a non-aqueous medium, the additional ionically conducting salt corresponding to the formula M+(Z*(J*)j)−, wherein: M is a lithium atom, Z* is an anion group containing two or more Lewis basic sites and comprising less than 50 atoms not including hydrogen atoms, J* independently each occurrence is a Lewis acid coordinated to at least one Lewis basic site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, and j is an integer from 2 to 12. The addition of these ionically conducting salts to electrolyte solutions containing LiPF6 (and/or other lithium compounds) improves the stability of the electrolyte solution.

摘要翻译： 提供一种用于产生电流的电化学电池的非水电解质，其包含在非水介质中的离子导电盐和另外的离子导电盐，对应于式M +（Z *（J *）j ） - ，其中：M是锂原子，Z *是含有两个或更多个路易斯碱性位点并且包含小于50个不包括氢原子的原子的阴离子基团，J *各自独立地是与至少一个路易斯配位的路易斯酸 Z *的碱性位点和任选的两个或更多个这样的J *基团可以在具有多个路易斯酸性官能团的部分中连接在一起，并且j是2至12的整数。将这些离子导电盐加入到含有LiPF 6的电解质溶液中 （和/或其他锂化合物）提高了电解质溶液的稳定性。

公开(公告)号：US06221941B1

公开(公告)日：2001-04-24

申请号：US09151852

申请日：1998-09-11

申请人： Steven H. Strauss ,  Benjamin G. Nolan ,  Thomas J. Barbarich ,  Juston J. Rockwell

发明人： Steven H. Strauss ,  Benjamin G. Nolan ,  Thomas J. Barbarich ,  Juston J. Rockwell

IPC分类号： C08K500

CPC分类号： H01G9/155 ,  C07F5/003 ,  C07F5/022 ,  C07F5/069 ,  C07F7/003 ,  C07F7/025 ,  C07F9/005 ,  C07F9/5325 ,  C07F9/68 ,  C07F9/902 ,  H01M6/181 ,  H01M10/0565 ,  H01M10/0568 ,  Y02E60/13 ,  Y02T10/7022

摘要： A compound comprising a polyfluorinated anion of the formula [M1(XC(CFa(R1)b)(CFc(R2)d)R3)m(R4)n]−p and the use thereof is provided. Specifically, the present invention provides a compound comprising a anion which comprises a polyfluorinated alkoxide coordinated to a transition metal, or a Group III, IV or V element.

摘要翻译： 包含式[M1（XC（CFa（R1）b）（CFc（R2）d）R3）m（R4）n] -p的多氟化阴离子的化合物及其用途。 具体地说，本发明提供一种包含阴离子的化合物，该阴离子包括与过渡金属配位的多氟化烷氧基化物，或III，IV或V族元素。

公开(公告)号：US5895771A

公开(公告)日：1999-04-20

申请号：US870354

申请日：1997-06-05

申请人： Ronald A. Epstein ,  Thomas J. Barbarich

发明人： Ronald A. Epstein ,  Thomas J. Barbarich

IPC分类号： B01J31/14 ,  B01J31/22 ,  C08F4/642 ,  C08F4/6592 ,  C08F10/00 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

CPC分类号： B01J31/143 ,  B01J31/2295 ,  C08F10/00 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65925 ,  Y10S526/943

摘要： Catalyst compositions for the polymerization of an olefin are disclosed which comprise a neutral metallocene and, as the ionizing agent an anionic aluminum-containing complex which is a fluorinated alkoxy and/or aryloxy aluminate. The fluorinated alkoxy aluminate can be of the formula A.sup.+ (Al(OR).sub.4).sup.-, where A.sup.+ is a cation capable of reacting with the neutral metallocene to produce a cationic metallocene and a non-reacting neutral species and R is a fluorinated alkyl and/or aryl group, with a representative group for A.sup.+ being (C.sub.6 H.sub.5).sub.3 C.sup.+ and with the representative fluorinated alkoxy aluminates including �Al(OC(Ph)(CF.sub.3).sub.2).sub.4 !.sup.-, where Ph is phenyl, and �Al(OC(CH.sub.3)(CF.sub.3).sub.2).sub.4 !.sup.-.

摘要翻译： 公开了用于烯烃聚合的催化剂组合物，其包含中性茂金属，并且作为电离剂是作为氟化烷氧基和/或芳氧基铝酸盐的阴离子含铝络合物。 氟化烷氧基铝酸盐可以是式A +（Al（OR）4） - ，其中A +是能够与中性茂金属反应以产生阳离子茂金属和非反应中性物质的阳离子，R是氟化烷基， 具有代表性的基团为A +为（C 6 H 5）3 C +，代表性的氟化烷氧基铝酸盐包括[Al（OC（Ph）（CF 3）2）4] - ，其中Ph为苯基，[Al （CH 3）（CF 3）2）4] - 。