公开(公告)号：US08940950B2

公开(公告)日：2015-01-27

申请号：US13303855

申请日：2011-11-23

Applicant: Justin M. Ellrich ,  Robert D. Strack ,  John W. Rebeck ,  Allen S. Gawlik ,  Larry L. Iaccino ,  Glenn C. Wood ,  Stephen H. Brown ,  Timothy Paul Bender

Inventor： Justin M. Ellrich ,  Robert D. Strack ,  John W. Rebeck ,  Allen S. Gawlik ,  Larry L. Iaccino ,  Glenn C. Wood ,  Stephen H. Brown ,  Timothy Paul Bender

IPC: C07C2/66 ,  C07C6/12 ,  C07C4/14 ,  C07C2/86 ,  C07C5/27 ,  C10G55/04 ,  C10G55/06 ,  C10G57/00

CPC classification number: C07C2/864 ,  B01J2219/00006 ,  C07C5/2729 ,  C07C5/2767 ,  C10G55/04 ,  C10G55/06 ,  C10G57/005 ,  C10G2400/30 ,  C07C15/08

Abstract: The process relates to the use of any naphtha-range stream containing a portion of C8+ aromatics combined with benzene, toluene, and other non-aromatics in the same boiling range to produce toluene. By feeding the A8+ containing stream to a dealkylation/transalkylation/cracking reactor to increase the concentration of toluene in the stream, a more suitable feedstock for the methylation reaction can be produced. This stream can be obtained from a variety of sources, including the pygas stream from a steam cracker, “cat naphtha” from a fluid catalytic cracker, or the heavier portion of reformate.

Abstract translation: 该方法涉及使用含有一部分C8 +芳族化合物与苯，甲苯和其它非芳族化合物在相同沸点范围内结合以产生甲苯的任何石脑油流。 通过将含A8 +的料流输送到脱烷基/烷基转移/裂化反应器以增加料流中甲苯的浓度，可以生产更合适的用于甲基化反应的原料。 该流可以从各种来源获得，包括来自蒸气裂化器的炽气流，来自流化催化裂化器的“咔咔石脑油”或重整产物的较重部分。

公开(公告)号：US08399727B2

公开(公告)日：2013-03-19

申请号：US12899193

申请日：2010-10-06

Applicant: James R. Lattner ,  Mark P. Hagemeister ,  Christopher Gordon Smalley ,  Jon Edmond Randolph Stanat ,  Timothy Paul Bender ,  Masaaki Sugita ,  Rathna P. Davuluri ,  Lu Han

Inventor： James R. Lattner ,  Mark P. Hagemeister ,  Christopher Gordon Smalley ,  Jon Edmond Randolph Stanat ,  Timothy Paul Bender ,  Masaaki Sugita ,  Rathna P. Davuluri ,  Lu Han

IPC: C07C2/66

CPC classification number: C07C2/864 ,  C07C2529/40 ,  Y02P20/52 ,  C07C15/08

Abstract: In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.

Abstract translation: 在制备对二甲苯的方法中，在固体催化剂颗粒的流化床的存在下，在反应器中，在烷基化条件下，将包含甲苯和/或苯的芳族原料与甲醇反应以产生包含对 - 二甲苯，水，未反应的甲苯和/或苯和固体催化剂细粉。 气相流出物与液态烃淬火流接触，条件是冷凝少部分气相流出物并产生含有至少一些催化剂细粒并且基本上不含水相的冷凝物。 然后将含有所述催化剂细粒的冷凝物与其余的气相流出物分离。

公开(公告)号：US20110092756A1

公开(公告)日：2011-04-21

申请号：US12899193

申请日：2010-10-06

Applicant: James R. Lattner ,  Mark P. Hagemeister ,  Christopher Gordon Smalley ,  Jon Edmond Randolph Stanat ,  Timothy Paul Bender ,  Masaaki Sugita ,  Rathna P. Davuluri ,  Lu Han

Inventor： James R. Lattner ,  Mark P. Hagemeister ,  Christopher Gordon Smalley ,  Jon Edmond Randolph Stanat ,  Timothy Paul Bender ,  Masaaki Sugita ,  Rathna P. Davuluri ,  Lu Han

IPC: C07C15/08

CPC classification number: C07C2/864 ,  C07C2529/40 ,  Y02P20/52 ,  C07C15/08

Abstract: In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.

Abstract translation: 在制备对二甲苯的方法中，在固体催化剂颗粒的流化床的存在下，在反应器中，在烷基化条件下，将包含甲苯和/或苯的芳族原料与甲醇反应以产生包含对 - 二甲苯，水，未反应的甲苯和/或苯和固体催化剂细粉。 气相流出物与液态烃淬火流接触，条件是冷凝少部分气相流出物并产生含有至少一些催化剂细粒并且基本上不含水相的冷凝物。 然后将含有所述催化剂细粒的冷凝物与其余的气相流出物分离。