公开(公告)号：US5472996A

公开(公告)日：1995-12-05

申请号：US224521

申请日：1994-04-07

申请人： Ryutaro Hayashi ,  Masahiro Aoki ,  Toyoji Tomita ,  Yoshinori Kato ,  Takeo Tsukamoto ,  Takeshi Awata

发明人： Ryutaro Hayashi ,  Masahiro Aoki ,  Toyoji Tomita ,  Yoshinori Kato ,  Takeo Tsukamoto ,  Takeshi Awata

IPC分类号： C08L101/02 ,  C08F291/00 ,  C08K5/25 ,  C08L51/00 ,  C08L101/00 ,  C09D5/00 ,  C09D5/02 ,  C09D5/28 ,  C09D151/00 ,  C09D201/02 ,  C09J201/00 ,  C09J201/02 ,  C08F8/30

CPC分类号： C09D151/00 ,  C08F291/00 ,  C08K5/25 ,  C08L51/003 ,  Y10S525/902

摘要： An aqueous dispersed resin composition comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C., and (d) not more than 99% by weight of an unsaturated monomer other than the monomers (a) to (c) in the presence of dispersed resin particles serving as an inner layer and (B) a hydrophilic compound comprising a hydrazine derivative containing at least two hydrazino groups in the molecule thereof, in which the resin constituting the outermost layer of the carbonyl-containing resin particles has a degree of solubilization of at least 5% by weight, and the resin constituting the inner layer has a degree of solubilization lower than that of the resin constituting the outermost layer. The composition provides a film excellent in water resistance, adhesion to a substrate, smoothness, gloss, and resistance to whitening on contact with water.

摘要翻译： 一种含水分散树脂组合物，其包含（A）具有内层和最外层的含羰基树脂颗粒的水分散体，其通过单体混合物的乳液聚合获得，所述单体混合物包含（a）不小于0.5重量％ 在分子中含有至少一个醛基或酮基和一个可聚合不饱和双键的含羰基单体，（b）不小于0.5重量％的烯属不饱和羧酸，（c）不大于99重量％ 在20℃下水溶性不超过8g / 100ml的单体的重量，和（d）不大于99重量％的单体（a）至（c）以外的不饱和单体， 在作为内层的分散树脂粒子的存在下，和（B）包含其分子中含有至少两个肼基的肼衍生物的亲水性化合物，其中构成含羰基的res的最外层的树脂 颗粒的增溶度为至少5重量％，构成内层的树脂的溶解度低于构成最外层的树脂的增溶度。 该组合物提供了耐水性，对基材的粘合性，平滑性，光泽度和与水接触时的美白抗性优异的膜。

公开(公告)号：US5447970A

公开(公告)日：1995-09-05

申请号：US224518

申请日：1994-04-07

申请人： Toyoji Tomita ,  Masahiro Aoki ,  Takeo Tsukamoto ,  Takeshi Awata ,  Ryutaro Hayashi

发明人： Toyoji Tomita ,  Masahiro Aoki ,  Takeo Tsukamoto ,  Takeshi Awata ,  Ryutaro Hayashi

IPC分类号： C08K5/25 ,  C08L51/00 ,  C09D151/00 ,  C09J151/00 ,  C08F8/30

CPC分类号： C09D151/003 ,  C08K5/25 ,  C08L51/003 ,  C09J151/003 ,  Y10S525/902

摘要： An aqueous dispersed resin composition is disclosed, comprising (A) an aqueous dispersion of carbonyl-containing resin particles having an inner layer and an outermost layer, which is obtained by emulsion polymerization of a monomer mixture comprising (a) not less than 0.5% by weight of a carbonyl-containing monomer containing at least one aldo group or keto group and one polymerizable unsaturated double bond in the molecule thereof, (b) not less than 0.5% by weight of an ethylenically unsaturated carboxylic acid, (c) not more than 99% by weight of a monomer having a water-solubility of not more than 8 g/100 ml at 20.degree. C., and (d) not more than 99% by weight of an unsaturated monomer other than the monomers (a) to (c) in an aqueous medium in the presence of dispersed resin particles serving as an inner layer, (B) a hydrophilic compound comprising a hydrazine derivative containing at least two hydrazino groups in the molecule thereof, and (C) an epoxy-containing compound containing at least two epoxy groups in the molecule thereof, in which the resin constituting said outermost layer of said carbonyl-containing resin particles has a degree of solubilization of at least 5% by weight, and the resin constituting the whole resin particles has a degree of solubilization of from 4 to 50% by weight. The composition is easily crosslinked at room temperature to provide a film excellent in water resistance, resistance to whitening on contact with water, antiblocking properties, heat resistance, solvent resistance, adhesion and hardness, and is particularly useful as an adhesive composition.

摘要翻译： 公开了一种含水分散树脂组合物，其包含（A）具有内层和最外层的含羰基树脂颗粒的水分散体，其通过单体混合物的乳液聚合获得，所述单体混合物包含（a）不小于0.5％ 在分子中含有至少一个醛基或酮基和一个可聚合不饱和双键的含羰基单体的重量，（b）不小于0.5重量％的烯属不饱和羧酸，（c）不大于 在20℃下，99重量％的水溶性不超过8g / 100ml的单体，和（d）不大于99重量％的除单体（a）〜 （C）在分散有作为内层的分散树脂颗粒存在下的水性介质中，（B）包含分子中含有至少两个肼基的肼衍生物的亲水性化合物，（C）含环氧化合物 包含在 其中构成所述含羰基树脂颗粒的最外层的树脂的溶解度至少为5重量％，构成整个树脂颗粒的树脂具有增溶程度的分子中至少两个环氧基团 为4至50重量％。 该组合物在室温下易于交联，从而提供耐水性优异，与水接触时的耐白化性，防粘连性，耐热性，耐溶剂性，粘附性和硬度，并且特别可用作粘合剂组合物。