Catalyst for the Conversion of Carbon Monoxide
    4.
    发明申请
    Catalyst for the Conversion of Carbon Monoxide 有权
    一氧化碳转化催化剂

    公开(公告)号:US20070259976A1

    公开(公告)日:2007-11-08

    申请号:US11381938

    申请日:2006-05-05

    IPC分类号: C07C27/06

    CPC分类号: C10K3/04

    摘要: Use of a catalyst composition comprising a metal selected from the group consisting of ruthenium, rhodium, nickel and combinations thereof, on a support selected from the group consisting of a beta-zeolite, mordenite and faujasites, is taught for carbon oxide methanation reactions for fuel cells. Specifically, when a mixture of gases containing hydrogen, carbon dioxide, carbon monoxide, and water is passed over the catalyst in a reaction zone having a temperature below the temperature at which the shift reaction occurs and above the temperature at which the selective methanation of carbon monoxide occurs, the catalyst efficiently facilitates the selective hydrogenation of carbon monoxide using H2 that is present in the reformate and reduces the concentration of the CO to levels equal to or less than about 50 ppm and demonstrates a carbon monoxide (CO) methanation selectivity of greater than about 50%.

    摘要翻译: 教导了在选自β-沸石,丝光沸石和八面沸石的载体上使用包含选自钌,铑,镍及其组合的金属的催化剂组合物用于燃料的碳氧化物甲烷化反应 细胞。 具体地说,当在低于发生变换反应的温度的温度和高于选择性甲烷化碳的温度的反应区中使含有氢气,二氧化碳,一氧化碳和水的气体的混合物通过催化剂时, 一氧化碳发生,催化剂有效地促进了使用重整产品中存在的H 2 CO 2的一氧化碳的选择性氢化,并将CO的浓度降低至等于或小于约50ppm,并显示出碳 一氧化碳(CO)甲烷化选择性大于约50%。