公开(公告)号：US06969777B2

公开(公告)日：2005-11-29

申请号：US10312360

申请日：2001-06-27

申请人： Helmut Walz ,  Willi Schönmann ,  Rolf Müller ,  Roland Krokoszinski

发明人： Helmut Walz ,  Willi Schönmann ,  Rolf Müller ,  Roland Krokoszinski

IPC分类号： C07B61/00 ,  C07C45/50 ,  C07C47/02

CPC分类号： C07C45/50 ,  C07C47/02

摘要： Olefins having from 2 to 8 carbon atoms are hydroformylated in a process in which (i) an olefin-containing feed in which a proportion of a saturated hydrocarbon having from 2 to 8 carbon atoms is present and also carbon monoxide and hydrogen are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, (ii) a stream consisting essentially of unreacted olefin and saturated hydrocarbon is separated off from the output from the reaction zone, (iii) the stream is separated into an olefin-enriched fraction and an olefin-depleted fraction by rectification, and (iv) at least part of the olefin-enriched fraction is recirculated to the reaction zone.

摘要翻译： 具有2至8个碳原子的烯烃在其中（i）含烯烃的进料中存在一部分具有2至8个碳原子的饱和烃以及一氧化碳和氢气进料到 反应区并在加氢甲酰化催化剂存在下反应，（ii）基本上由未反应的烯烃和饱和烃组成的物流与反应区的输出分离，（iii）将物流分离成富含烯烃的馏分和 通过精馏的烯烃贫化馏分，和（iv）至少部分富烯烃馏分再循环到反应区。

公开(公告)号：US06849769B2

公开(公告)日：2005-02-01

申请号：US10363660

申请日：2001-09-11

申请人： Michael Röper ,  Heinrich-Josef Blankertz ,  Armin Volker Grenacher ,  Roland Krokoszinski ,  Willi Schönmann

发明人： Michael Röper ,  Heinrich-Josef Blankertz ,  Armin Volker Grenacher ,  Roland Krokoszinski ,  Willi Schönmann

IPC分类号： B01J31/20 ,  C08F8/00 ,  C07C45/50

CPC分类号： C08F8/00 ,  Y02P20/584 ,  Y10S585/901 ,  C08F110/10

摘要： Essentially monounsaturated polyalkylenes having from 30 to 700 carbon atoms are continuously hydroformylated by a process in which i) a hydroformylation-active cobalt carbonyl catalyst is prepared from a catalyst precursor dissolved in an aqueous phase in the absence of the polyalkylenes, ii) the polyalkylenes are hydroformylated by means of synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, iii) the cobalt carbonyl catalyst is separated from the output from the reaction zone with at least partial reformation of the catalyst precursor and the catalyst precursor is recirculated to step i).

摘要翻译： 具有30至700个碳原子的基本单不饱和聚亚烷基通过以下方法连续加氢甲酰化，其中i）在不存在聚亚烷基的情况下由溶解在水相中的催化剂前体制备加氢甲酰化 - 活性钴羰基催化剂，ii）聚亚烷基 在羰基催化剂存在下，通过合成气在反应区中加氢甲酰化，iii）将钴羰基催化剂与反应区的输出分离，至少部分重新形成催化剂前体，催化剂前体再循环至 步骤i）。

公开(公告)号：US06511583B1

公开(公告)日：2003-01-28

申请号：US09937311

申请日：2001-09-24

申请人： Rolf Müller ,  Willi Schönmann

发明人： Rolf Müller ,  Willi Schönmann

IPC分类号： B01D314

CPC分类号： C07C45/50 ,  B01D3/143 ,  C07C45/82 ,  Y10S203/20 ,  C07C47/02

摘要： In a process for the fractional distillation of a liquid crude aldehyde mixture including straight-chain and branched aldehydes, the product mixture is fractionated in a first distillation column to give a product stream of branched aldehyde, a product stream of straight-chain aldehyde and a further product stream including straight-chain aldehyde and the high boiling constituents. The further product stream is then fractionated in a second distillation column whose packing volume is a factor of from 50 to 200 smaller than that of the first distillation column to give a product stream of straight-chain aldehyde and a high boiler product stream.

摘要翻译： 在包括直链和支链醛的液体粗醛混合物的分馏的方法中，将产物混合物在第一蒸馏塔中分馏，得到支链醛的产物流，直链醛的产物流和 进一步的产品流包括直链醛和高沸点成分。 然后将另外的产物流在第二蒸馏塔中分馏，其包装体积比第一蒸馏塔的填充体积小50至200倍，得到直链醛和高锅炉产物流的产物流。

公开(公告)号：US06444856B2

公开(公告)日：2002-09-03

申请号：US09867574

申请日：2001-05-31

申请人： Armin Volker Grenacher ,  Hans-Georg Hein ,  Hans Stepp ,  Hans-Jürgen Fröhlich ,  Willi Schönmann ,  Gerhard Borchert

发明人： Armin Volker Grenacher ,  Hans-Georg Hein ,  Hans Stepp ,  Hans-Jürgen Fröhlich ,  Willi Schönmann ,  Gerhard Borchert

IPC分类号： C07C4550

CPC分类号： C07C45/50 ,  B01J3/042 ,  B01J4/002 ,  B01J4/007 ,  B01J10/00 ,  B01J19/006 ,  B01J19/26 ,  B01J2219/00051 ,  B01J2219/00162 ,  C07C29/141 ,  C07C47/02 ,  C07C31/125

摘要： In a process for preparing aldehydes and/or alcohols having from 6 to 30 carbon atoms by hydroformylation of olefins by means of synthesis gas in the presence of a catalyst at from 120° C. to 210° C. and pressures of from 100 to 400 bar, a reaction mixture comprising olefins, synthesis gas and catalyst or catalyst precursor is, according to the present invention, introduced at high velocity into a high-pressure reactor via a nozzle having an adjustable flow cross section.

摘要翻译： 在通过在120℃至210℃的催化剂存在下通过合成气进行烯烃加氢甲酰化制备具有6至30个碳原子的醛和/或醇的方法和压力为100-400 根据本发明，包含烯烃，合成气和催化剂或催化剂前体的反应混合物通过具有可调流动横截面的喷嘴以高速引入高压反应器。

公开(公告)号：US06331656B1

公开(公告)日：2001-12-18

申请号：US09269421

申请日：1999-03-04

申请人： Heinrich-Josef Blankertz ,  Armin Volker Grenacher ,  Friedrich Sauer ,  Harald Schwahn ,  Willi Schönmann ,  Michael Röper

发明人： Heinrich-Josef Blankertz ,  Armin Volker Grenacher ,  Friedrich Sauer ,  Harald Schwahn ,  Willi Schönmann ,  Michael Röper

IPC分类号： C07C4500

CPC分类号： C07C29/16 ,  C07C45/50 ,  C08F8/00 ,  C07C31/18 ,  C08F110/10 ,  C07C47/02

摘要： In a process for the hydroformylation of olefins having from 12 to 100 carbon atoms in the presence of a cobalt carbonyl catalyst at pressures of from 100 to 400 bar and at from 100 to 200° C., depressurization and recovery of the cobalt catalyst by extraction with an aqueous acid solution in the presence of atmospheric oxygen, (a) the extraction is carried out in the presence of a polymeric emulsion breaker selected from the group consisting of alkoxylated compounds containing amino, imino or OH groups, and (b) to achieve complete phase separation in the organic phase still containing small amounts of aqueous phase, the formation of relatively large droplets of the dispersed aqueous phase is effected in a coalescence stage.

摘要翻译： 在羰基钴催化剂存在下，在100-400巴和100-200℃的压力下，在具有12至100个碳原子的烯烃的加氢甲酰基化方法中，通过萃取法减少和回收钴催化剂 在大气氧存在下用酸水溶液处理，（a）萃取在选自包含氨基，亚氨基或OH基团的烷氧基化合物的聚合物破乳剂存在下进行，和（b）实现 在有机相中仍然含有少量水相的完全相分离，在聚结阶段中实现分散的水相的相对大的液滴的形成。