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公开(公告)号:US4235740A
公开(公告)日:1980-11-25
申请号:US20012
申请日:1979-03-13
CPC分类号: G21C3/623 , C01G56/003 , C01G56/004 , C01P2004/61 , C01P2006/10 , C01P2006/11 , C01P2006/12 , C01P2006/20 , C01P2006/80 , Y02E30/38 , Y10S376/901
摘要: Manufacture of uranium/plutonium oxide mixed crystals soluble in nitric acid in which a solution of uranium nitrate and plutonium nitrate are oxidized to cause the plutonium to reach valence VI. The oxidized solution is admixed with ammonium carbonate, oxalate or carbamate and the pH adjusted to 8.1 to 8.5 to precipitate an ammonium uranyl plutonyl carbonate, oxalate or carbamate. The precipitate is calcined to uranium/plutonium oxide.
摘要翻译: 制造可溶于硝酸的铀/钚氧化物混合晶体,其中硝酸铀和硝酸钚的溶液被氧化,导致钚达到VI。 将氧化的溶液与碳酸铵,草酸盐或氨基甲酸铵混合,并将pH调节至8.1至8.5,以沉淀碳酸铀酰基脯氨酸碳酸酯,草酸盐或氨基甲酸铵。 将沉淀物煅烧成铀/钚氧化物。
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公开(公告)号:US4687941A
公开(公告)日:1987-08-18
申请号:US690155
申请日:1985-01-10
CPC分类号: B25J21/02 , G21F7/053 , Y10T137/87048
摘要: A glove box with tubular lines for harmful fluids and with shutoff valves inserted in the tubular lines and, respectively, formed of an actuating member and a valve body includes an exterior wall forming part of the glove box, the shutoff valves being disposed adjacent one another on the wall, the valve bodies of the shutoff valves being located on the inside of the exterior wall, and the actuating members of the valve bodies being located on the outside of the exterior wall; and a drive for driving the actuating members also located on the outside of the exterior wall and having a device for docking with the respective actuating members, the drive means being guidably displaceable in a plane parallel to said exterior wall to the respective actuating members for docking with the respective actuating members.
摘要翻译: 具有用于有害流体的管状线和插入管状线中的截止阀的手套箱和分别由致动构件和阀体形成的包括形成手套箱的一部分的外壁,截止阀彼此相邻地设置 在壁上,截止阀的阀体位于外壁的内侧,阀体的致动构件位于外壁的外侧; 以及用于驱动致动构件的驱动器,其也位于外壁的外侧上并且具有用于与相应的致动构件对接的装置,所述驱动装置可在与所述外壁平行的平面中可引导地移位到相应的致动构件以进行对接 与相应的致动构件。
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公开(公告)号:US4565672A
公开(公告)日:1986-01-21
申请号:US556638
申请日:1983-11-30
IPC分类号: C01G56/00
CPC分类号: C01G56/005 , C01G56/003 , C01P2006/80
摘要: A method for manufacturing Pu.sub.2 -containing crystals by oxidizing plutonium in a heavily contaminated nitric acid starting solution to Pu.sup.6+, precipitating ammonium plutonyl carbonate containing crystals by reaction with ammonium- and carbonate ions and subsequent separating and calcining of these crystals. The nitric acid solution with the oxidized Pu.sup.6+ as well as carbonate and/or acetate ions and NH.sub.3 are dosed into an aqueous starting solution of ammonium carbonate or ammonium acetate in a concentration such that the mol ratio of carbonate and/or acetate ions to the Pu.sup.6+ -ions in the solution is at least 4:1 and plutonium containing carbonato- or acetato complex compounds which remain dissolved in the receiver solution, are formed, while difficult-to-dissolve metal hydroxide compounds are precipitated. Thereupon NH.sub.3 and carbonate ions are added to precipitate the ammonium plutonyl carbonate containing crystals.
摘要翻译: 通过将重度污染的硝酸起始溶液中的钚氧化成Pu6 +,通过与铵和碳酸根离子反应沉淀出含有结晶的铵基磷酸酯,随后分离和煅烧这些晶体,从而制造含Pu2的晶体的方法。 将具有氧化的Pu6 +以及碳酸盐和/或乙酸根离子和NH 3的硝酸溶液配制成碳酸铵或乙酸铵的起始水溶液,其浓度使得碳酸盐和/或乙酸根离子与Pu6 + 形成溶液中至少4:1,并且难以溶解的金属氢氧化物化合物沉淀而形成保留溶解在接收溶液中的钚的碳酸或乙酸络合物化合物。 因此,加入NH 3和碳酸根离子以沉淀含有含磷酸onyl基碳酸酯的晶体。
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公开(公告)号:US4431580A
公开(公告)日:1984-02-14
申请号:US228247
申请日:1981-01-26
IPC分类号: C01G43/00 , B01J39/04 , C01G56/00 , C22B60/02 , C22B60/04 , G21C19/46 , G21F9/00 , G21F9/12 , C09K11/04
CPC分类号: C22B60/0265 , C22B60/04 , G21F9/12
摘要: Purifying a nitric acid solution containing U/Pu ions and contaminated by metal impurities by(a) oxidizing the U/Pu ions of the solution to the hexavalent form,(b) conducting the solution after oxidation through a cation exchanger column in which the impurities, especially americium, are retained,(c) flushing the cation exchanger column to remove impurities therefrom, which may be taken to waste processing or utilization plant.
摘要翻译: 通过(a)将溶液的U / Pu离子氧化成六价形式,净化含有U / Pu离子并被金属杂质污染的硝酸溶液,(b)在氧化后通过阳离子交换柱进行溶液,其中杂质 (特别是ium),(c)冲洗阳离子交换柱以除去其中的杂质,其可以被带到废物处理或利用厂。
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