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公开(公告)号：US20100217031A1
公开(公告)日：2010-08-26
申请号：US12679045
申请日：2008-10-29
IPC分类号： C07C67/46
CPC分类号： C07C67/327 , C07C67/46 , Y02P20/582 , C07C69/734 , C07C69/708
摘要： The present invention relates to a continuous process for preparing alkyl 3,3-dialkoxy-propionates of the formula (RO)2CHCH2CO2R, wherein R is C1-6 alkyl, by reacting ketene with an ortho formate of formula (RO)3CH in the presence of an acidic catalyst, characterized in that the reaction is carried out in a loop reactor.
摘要翻译： 本发明涉及在存在下通过使乙烯酮与式（RO）3CH的原甲酸酯反应来制备式（RO）2 CHCH 2 CO 2 R的烷基3,3-二烷氧基 - 丙酸酯，其中R为C 1-6烷基的连续方法 的酸性催化剂，其特征在于反应在环管反应器中进行。
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公开(公告)号：US08337796B2
公开(公告)日：2012-12-25
申请号：US13061813
申请日：2009-09-15
申请人： Paul Hanselmann , Ellen Klegraf , Wolfgang Wenger
发明人： Paul Hanselmann , Ellen Klegraf , Wolfgang Wenger
IPC分类号： C01C3/04
CPC分类号： C01C3/003
摘要： Process for removing hydrogen cyanide from ethanedinitrile by contacting hydrogen cyanide-containing ethanedinitrile with an organic reagent under formation of a covalent bond.
摘要翻译： 通过使含氰化氢的乙二腈与共价键形成的有机试剂接触，从乙二腈中除去氰化氢的方法。
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公开(公告)号：US08283497B2
公开(公告)日：2012-10-09
申请号：US13147416
申请日：2010-01-26
IPC分类号： C07F5/02
CPC分类号： C07F5/02
摘要： The present invention relates to novel tricyanoborates of the general formula Catn+[B(CN)3(XR1)]—n, wherein R1 is C1-6 alkyl, C2-6 alkenyl, C6-10 aryl or benzyl; X is oxygen or sulfur; and Catn+ is a cation with n being 1 or 2, which is selected from the group consisting of an inorganic cation and an organic cation; and also their preparation and use.
摘要翻译： 本发明涉及通式为Catn + [B（CN）3（XR1）] - n的新型三氰基硼酸酯，其中R 1为C 1-6烷基，C 2-6烯基，C 6-10芳基或苄基; X是氧或硫; 并且Catn +是n为1或2的阳离子，其选自无机阳离子和有机阳离子; 以及他们的准备和使用。
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公开(公告)号：US20120018676A1
公开(公告)日：2012-01-26
申请号：US13147416
申请日：2010-01-26
CPC分类号： C07F5/02
摘要： The present invention relates to novel tricyanoborates of the general formula Catn+ [B(CN)3(XR1)]—n, wherein R1 is C1-6 alkyl, C2-6 alkenyl, C6-10 aryl or benzyl; X is oxygen or sulfur; and Catn+ is a cation with n being 1 or 2, which is selected from the group consisting of an inorganic cation and an organic cation; and also their preparation and use.
摘要翻译： 本发明涉及通式为Catn + [B（CN）3（XR1）] - n的新型三氰基硼酸酯，其中R 1为C 1-6烷基，C 2-6烯基，C 6-10芳基或苄基; X是氧或硫; 并且Catn +是n为1或2的阳离子，其选自无机阳离子和有机阳离子; 以及他们的准备和使用。
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5.发明授权Process for the selective preparation of acetaldehyde from acrolein and one or more ammonium salts dissolved in water 失效从丙烯醛和一种或多种溶解在水中的铵盐选择性制备乙醛的方法公开(公告)号：US08044246B2
公开(公告)日：2011-10-25
申请号：US12844571
申请日：2010-07-27
申请人： Wolfgang Wenger , Andreas Heyl , Lothar Ott , Herbert Vogel , Paul Hanselmann , Gökhan Aras
发明人： Wolfgang Wenger , Andreas Heyl , Lothar Ott , Herbert Vogel , Paul Hanselmann , Gökhan Aras
IPC分类号： C07C45/61
CPC分类号： C07C45/52 , C07C45/673 , C07C47/22 , C07C47/04 , C07C47/06
摘要： The present invention relates to a process for the selective preparation of acetaldehyde, characterized in that acrolein and one or more ammonium salts dissolved in water are reacted continuously under high pressures and at temperatures of 300-400° C.
摘要翻译： 本发明涉及一种选择性制备乙醛的方法，其特征在于丙烯醛和一种或多种溶于水的铵盐在高压和300-400℃的温度下连续反应
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公开(公告)号：US20110195012A1
公开(公告)日：2011-08-11
申请号：US13061813
申请日：2009-09-15
申请人： Paul Hanselmann , Ellen Klegraf , Wolfgang Wenger
发明人： Paul Hanselmann , Ellen Klegraf , Wolfgang Wenger
IPC分类号： C01C3/00 , C07C59/153
CPC分类号： C01C3/003
摘要： Process for removing hydrogen cyanide from ethanedinitrile by contacting hydrogen cyanide-containing ethanedinitrile with an organic reagent under formation of a covalent bond.
摘要翻译： 通过使含氰化氢的乙二腈与共价键形成的有机试剂接触，从乙二腈中除去氰化氢的方法。
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7.发明申请PROCESS FOR THE SELECTIVE PREPARATION OF ACETALDEHYDE FROM ACROLEIN AND ONE OR MORE AMMONIUM SALTS DISSOLVED IN WATER 失效从ACROLEIN中选择性制备乙炔的方法和一种或多种在水中溶解的铵盐公开(公告)号：US20110028764A1
公开(公告)日：2011-02-03
申请号：US12844571
申请日：2010-07-27
申请人： Wolfgang WENGER , Andreas HEYL , Lothar OTT , Herbert VOGEL , Paul HANSELMANN , Gökhan ARAS
发明人： Wolfgang WENGER , Andreas HEYL , Lothar OTT , Herbert VOGEL , Paul HANSELMANN , Gökhan ARAS
IPC分类号： C07C45/62
CPC分类号： C07C45/52 , C07C45/673 , C07C47/22 , C07C47/04 , C07C47/06
摘要： The present invention relates to a process for the selective preparation of acetaldehyde, characterized in that acrolein and one or more ammonium salts dissolved in water are reacted continuously under high pressures and at temperatures of 300-400° C.
摘要翻译： 本发明涉及一种选择性制备乙醛的方法，其特征在于丙烯醛和一种或多种溶于水的铵盐在高压和300-400℃的温度下连续反应
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8.发明申请PROCESS FOR THE SELECTIVE PREPARATION OF 3-METHYLPYRIDINE (3-PICOLINE) FROM ACROLEIN AND ONE OR MORE AMMONIUM SALTS DISSOLVED IN WATER 审中-公开从丙酮酸和一种或多种在水中溶解的氨基磺酸选择性制备3-甲基吡啶（3-吡啶）的方法公开(公告)号：US20110028727A1
公开(公告)日：2011-02-03
申请号：US12844267
申请日：2010-07-27
申请人： Wolfgang WENGER , Andreas HEYL , Lothar OTT , Herbert VOGEL , Paul HANSELMANN , Gökhan ARAS
发明人： Wolfgang WENGER , Andreas HEYL , Lothar OTT , Herbert VOGEL , Paul HANSELMANN , Gökhan ARAS
IPC分类号： C07D213/12
CPC分类号： C07D213/12
摘要： The present invention relates to a process for the selective preparation of 3-methylpyridine, characterized in that acrolein and one or more ammonium salt(s) dissolved in water are reacted continuously under high pressures and at temperatures of 200-400° C.
摘要翻译： 本发明涉及一种选择性制备3-甲基吡啶的方法，其特征在于丙烯醛和一种或多种溶解在水中的铵盐在高压和200-400℃的温度下连续反应
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9.发明申请Method for the production of 6,6,6-trihalo-3,5-dioxohexanoic acid esters 失效6,6,6-三卤代-3,5-二氧代己酸酯的制备方法公开(公告)号：US20080161582A1
公开(公告)日：2008-07-03
申请号：US12071991
申请日：2008-02-28
申请人： Paul Hanselmann , Wolfgang Wenger
发明人： Paul Hanselmann , Wolfgang Wenger
IPC分类号： C07D309/30
CPC分类号： C07C69/738 , C07C67/03 , C07D309/38 , C07C69/716
摘要： A method for the production of 6,6,6-trihalo-3,5-dioxohexanic acid esters of formula (I): in addition to the enols thereof and E and Z isomers, wherein X independently represents fluorine, chlorine or bromine and R1 represents alkyl, cycloalkyl, aryl or aralkyl. A method for the production of enol ethers of formula (Ib): and the enols thereof (E and Z isomers) wherein X and R1 have the above-mentioned meanings.
摘要翻译： 制备式（I）的6,6,6-三卤代-3,5-二氧代己酸酯的方法：除了其烯醇和I E和Z I之外， >异构体，其中X独立地表示氟，氯或溴，R 1表示烷基，环烷基，芳基或芳烷基。 制备式（Ib）的烯醇醚的方法及其烯醇（E和Z异构体）其中X和R 1具有上述含义。
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10.发明授权Method for the production of 6,6,6-trihalo-3,5-dioxohexanoic acid esters 失效6,6,6-三卤代-3,5-二氧代己酸酯的制备方法公开(公告)号：US07351851B2
公开(公告)日：2008-04-01
申请号：US10577070
申请日：2004-10-22
申请人： Paul Hanselmann , Wolfgang Wenger
发明人： Paul Hanselmann , Wolfgang Wenger
CPC分类号： C07C69/738 , C07C67/03 , C07D309/38 , C07C69/716
摘要： A method for the production of 6,6,6-trihalo-3,5-dioxohexanoic acid esters of formula (I): in addition to the enols thereof and E and Z isomers, wherein X independently represents fluorine, chlorine or bromine and R1 represents alkyl, cycloalkyl, aryl or aralkyl. A method for the production of enol ethers of formula (Ib): and the enols thereof (E and Z isomers) wherein X and R1 have the above-mentioned meanings.
摘要翻译： 制备式（I）的6,6,6-三卤代-3,5-二氧代己酸酯的方法：除了其烯醇和I E和Z I之外， >异构体，其中X独立地表示氟，氯或溴，R 1表示烷基，环烷基，芳基或芳烷基。 制备式（Ib）的烯醇醚的方法及其烯醇（E和Z异构体）其中X和R 1具有上述含义。
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