公开(公告)号：US5403664A

公开(公告)日：1995-04-04

申请号：US059833

申请日：1993-05-10

申请人： Toyohide Kurahashi ,  Yoshio Hashibe ,  Masayuki Ninomiya

发明人： Toyohide Kurahashi ,  Yoshio Hashibe ,  Masayuki Ninomiya

IPC分类号： C03C10/00

CPC分类号： C03C10/0036

摘要： Marble-like glass ceramic which consists essentially of, by weight percent, 50-75% SiO.sub.2, 1-15% Al.sub.2 O.sub.3, 6-16.5% CaO, 0.1-5% Li.sub.2 O, 0-1.5% B.sub.2 O.sub.3, 10-17.5% CaO+Li.sub.2 O+B.sub.2 O.sub.3, 2.5-12% ZnO, 0-12% BaO, 0.1-15% Na.sub.2 O+K.sub.2 O, and 0-10% coloring agents, said ceramic comprising .beta.-wollastonite precipitated as a major crystal. The coloring agents comprises at least one selected from a group of Fe.sub.2 O.sub.3, NiO, CoO, MnO.sub.2, Cr.sub.2 O.sub.3, and CuO. The marble-like glass ceramic may further comprises at least one of As.sub.2 O.sub.3 and Sb.sub.2 O.sub.3 of up to 1% as refining agents, at least one of up to 1.5% MgO and up to 1.5% SrO so as to improve meltability of the glass, and at least one of up to 1% TiO.sub.2, up to 1% ZrO.sub.2, and up to 1% P.sub.2 O.sub.5 so as to make the glass stable and less devitrifiable.

摘要翻译： 大理石状玻璃陶瓷，其重量百分数为50-75％SiO 2，1-15％Al 2 O 3，6-16.5％CaO，0.1-5％Li 2 O，0-1.5％B 2 O 3，10-17.5％CaO + Li2O + B2O3,2.5-12％ZnO，0-12％BaO，0.1-15％Na2O + K2O和0-10％着色剂，所述陶瓷包含沉淀为主晶体的β-硅灰石。 着色剂包括选自Fe 2 O 3，NiO，CoO，MnO 2，Cr 2 O 3和CuO中的至少一种。 大理石状玻璃陶瓷可以进一步包含As2O3和Sb2O3至少一种作为澄清剂的至少1％，至多1.5％的MgO和至多1.5％的SrO中的至少一种，以提高玻璃的熔融性，以及 至多1％的TiO 2，至多1％的ZrO 2和至多1％的P 2 O 5中的至少一种，以使玻璃稳定和较少失透。

公开(公告)号：US07083857B2

公开(公告)日：2006-08-01

申请号：US10371818

申请日：2003-02-21

申请人： Masahiro Sawada ,  Yoshio Hashibe

发明人： Masahiro Sawada ,  Yoshio Hashibe

IPC分类号： B32B17/06

CPC分类号： C03C17/3417 ,  B32B17/10036 ,  B32B17/10174 ,  B32B17/1033 ,  B32B17/1055 ,  B32B17/10752 ,  B32B17/10779 ,  C03C17/3435 ,  Y10S428/92 ,  Y10S428/921 ,  Y10T428/315

摘要： A fire-protection glass product having a heat shielding characteristic comprises a fireproof glass plate, a heat ray reflection film formed on one or both of opposite surfaces of the fireproof glass plate, and an oxidation prevention film formed on the heat ray reflection film.

公开(公告)号：US5061307A

公开(公告)日：1991-10-29

申请号：US636873

申请日：1991-01-02

申请人： Takahiro Matano ,  Yoshio Hashibe ,  Masayuki Ninomiya ,  Takehiro Shibuya

发明人： Takahiro Matano ,  Yoshio Hashibe ,  Masayuki Ninomiya ,  Takehiro Shibuya

IPC分类号： C03C10/00 ,  C03C10/04

CPC分类号： C03C10/0045 ,  C03C10/0054

摘要： A crystallized glass having natural-marble-like surface patterns comprising 45 to 75 wt. % of SiO.sub.2, 1 to 25 wt. % of Al.sub.2 O.sub.3, 1 to 20 wt. % of CaO, 0.5 to 17 wt. % of MgO, 0.1 to 18 wt. % of BaO, 0 to 18 wt. % of ZnO, 1 to 15 wt. % of Na.sub.2 O, 0 to 7 wt. % of K.sub.2 O, 0 to 5 wt. % of Li.sub.2 O, 0 to 10 wt. % of B.sub.2 O.sub.3, 0 to 10 wt. % of P.sub.2 O.sub.5, 0 to 1 wt. % of As.sub.2 O.sub.3, and 0 to 1 wt. % of Sb.sub.2 O.sub.3, substantially free from nucleating agent, in which diopside type crystals are precipitated, and a method of producing the crystallized glass are disclosed.

摘要翻译： 具有天然大理石样表面图案的结晶玻璃，其包含45至75重量％ ％的SiO 2，1〜25wt。 ％的Al 2 O 3，1〜20wt。 CaO％，0.5〜17重量％ ％的MgO，0.1〜18wt。 ％的BaO，0〜18wt。 ％的ZnO，1〜15wt。 ％的Na 2 O，0〜7wt。 K 2 O％，0〜5重量％ ％的Li 2 O，0〜10wt。 ％的B2O3，0〜10wt。 ％的P 2 O 5，0〜1重量％ ％As2O3，0〜1wt。 基本上不含成核剂的Sb 2 O 3，其中析出透辉石型晶体的％，以及生产结晶玻璃的方法。

公开(公告)号：US5275978A

公开(公告)日：1994-01-04

申请号：US4663

申请日：1993-01-14

申请人： Takehiro Shibuya ,  Takashi Sakane ,  Yoshio Hashibe

发明人： Takehiro Shibuya ,  Takashi Sakane ,  Yoshio Hashibe

IPC分类号： C03C1/06 ,  C03C10/00 ,  C03C10/04 ,  C03C14/00

CPC分类号： C03C1/06 ,  C03C10/0036 ,  C03C14/004 ,  C03C2214/04 ,  C03C2214/20

摘要： A crystallized glass article having a surface pattern like granite, marble or other natural stones with a line pattern of a desired color or colors, which is formed by fusion bonding small masses of a crystallizable glass material mixed with inorganic pigment powder at a heat-treating temperature higher than the softening point. The surface pattern comprises crystallized glass areas defined by the small masses in the surface layer of the article and the colored line pattern defined by the pigment dispersed in the interfaces between adjacent ones of the small masses in the surface layer.

摘要翻译： 一种具有花岗岩，大理石或其他天然石材的表面图案的结晶玻璃制品，其具有所需颜色或颜色的线条图案，其通过将小块可结晶玻璃材料与无机颜料粉末混合而形成，所述可结晶玻璃材料在热处理 温度高于软化点。 表面图案包括由物品表面层中的小质量限定的结晶玻璃区域和由分散在表面层中的相邻小块之间的界面中的颜料限定的着色线图案。

公开(公告)号：US5089345A

公开(公告)日：1992-02-18

申请号：US430632

申请日：1989-11-01

申请人： Yoshio Hashibe ,  Takahiro Matano ,  Takehiro Shibuya ,  Takashi Sakane ,  Yasuhiro Baba ,  Masanori Moritake

发明人： Yoshio Hashibe ,  Takahiro Matano ,  Takehiro Shibuya ,  Takashi Sakane ,  Yasuhiro Baba ,  Masanori Moritake

IPC分类号： B32B17/06 ,  C03B19/06 ,  E04C2/54

CPC分类号： C03B19/06 ,  Y10T428/24942 ,  Y10T428/252

摘要： In a crystallized glass article consisting of crystallized glass masses fusion bonded together and having a principal surface, said principal surface having a surface pattern determined by said masses in a surface layer including said principal surface, said small crystallized glass masses in said surface layer are mainly of flaky crystallized glass pieces, each being a relatively large flattened piece, said flaky pieces overlapping one another at random to make said principal surface rough, said crystallized glass masses in another layer adjacent to and fused to said surface layer being considerably smaller than said flaky pieces. The article is produced by preparing flaky pieces and the smaller masses both of a SiO.sub.2 --Al.sub.2 O.sub.3 --CaO crystallizable glass, putting the former pieces on a bottom of a mold to form a flaky-piece layer, then putting the latter masses on the flaky-piece layer to form a small-mass layer, and heat treating the both layers at a temperature higher than a softening point of the crystallizable glass to fusion bond the pieces and masses together as well as crystallizing the glass.

摘要翻译： 在由结晶化玻璃质量结合在一起并具有主表面的结晶玻璃制品中，所述主表面具有由包括所述主表面的表面层中的所述质量确定的表面图案，所述表面层中的所述小结晶玻璃质量主要 片状结晶玻璃片各自是相当大的扁平片，所述片状片随机地彼此重叠以使所述主表面粗糙，所述相邻并融合到所述表面层的另一层中的结晶玻璃质量比所述片状物 件 该制品通过制备SiO 2 -Al 2 O 3 -EA CaO可结晶玻璃的片状片和较小的质量块，将前者放在模具的底部上以形成片状层，然后将后者放在片状片上， 以形成小质量层，并且在高于可结晶玻璃的软化点的温度下对两层进行热处理，以将这些块和块结合在一起并使玻璃结晶。

公开(公告)号：US5066524A

公开(公告)日：1991-11-19

申请号：US412851

申请日：1989-09-26

申请人： Yasuhiro Baba ,  Masanori Moritake ,  Takashi Sakane ,  Yoshio Hashibe ,  Takehiro Shibuya

发明人： Yasuhiro Baba ,  Masanori Moritake ,  Takashi Sakane ,  Yoshio Hashibe ,  Takehiro Shibuya

IPC分类号： C03C10/02 ,  B44F9/04 ,  C03C10/04 ,  C03C17/04

CPC分类号： C03C17/04 ,  B44F9/04 ,  Y10T428/22 ,  Y10T428/24802

摘要： A crystallized glass article with a colored surface pattern, which comprises a crystallized glass substrate having a surface and small glass masses having a color different from the substrate and dispersed and fusion-bonded in the surface to form the colored surface pattern. The crystallized glass article is produced by depositing and dispersing small glass masses with a color on a surface of a substrate of a crystallizable glass with a different color which can precipitate crystals therein with softening and deforming by heat-treating at a heat treating temperature higher than the softening point of the crystallizable glass, then heating the substrate together with the small glass masses at the heat treating temperature.

摘要翻译： 具有着色表面图案的结晶玻璃制品，其包括具有表面的结晶玻璃基板和具有与基板不同的颜色的小玻璃块，并且在表面中分散和熔合以形成着色表面图案。 结晶化玻璃制品通过在具有不同颜色的可结晶玻璃的基材的表面上沉积和分散小玻璃块而制成，其可以通过在高于 可结晶玻璃的软化点，然后在热处理温度下与小玻璃块一起加热基底。