公开(公告)号：US5089345A

公开(公告)日：1992-02-18

申请号：US430632

申请日：1989-11-01

申请人： Yoshio Hashibe ,  Takahiro Matano ,  Takehiro Shibuya ,  Takashi Sakane ,  Yasuhiro Baba ,  Masanori Moritake

发明人： Yoshio Hashibe ,  Takahiro Matano ,  Takehiro Shibuya ,  Takashi Sakane ,  Yasuhiro Baba ,  Masanori Moritake

IPC分类号： B32B17/06 ,  C03B19/06 ,  E04C2/54

CPC分类号： C03B19/06 ,  Y10T428/24942 ,  Y10T428/252

摘要： In a crystallized glass article consisting of crystallized glass masses fusion bonded together and having a principal surface, said principal surface having a surface pattern determined by said masses in a surface layer including said principal surface, said small crystallized glass masses in said surface layer are mainly of flaky crystallized glass pieces, each being a relatively large flattened piece, said flaky pieces overlapping one another at random to make said principal surface rough, said crystallized glass masses in another layer adjacent to and fused to said surface layer being considerably smaller than said flaky pieces. The article is produced by preparing flaky pieces and the smaller masses both of a SiO.sub.2 --Al.sub.2 O.sub.3 --CaO crystallizable glass, putting the former pieces on a bottom of a mold to form a flaky-piece layer, then putting the latter masses on the flaky-piece layer to form a small-mass layer, and heat treating the both layers at a temperature higher than a softening point of the crystallizable glass to fusion bond the pieces and masses together as well as crystallizing the glass.

摘要翻译： 在由结晶化玻璃质量结合在一起并具有主表面的结晶玻璃制品中，所述主表面具有由包括所述主表面的表面层中的所述质量确定的表面图案，所述表面层中的所述小结晶玻璃质量主要 片状结晶玻璃片各自是相当大的扁平片，所述片状片随机地彼此重叠以使所述主表面粗糙，所述相邻并融合到所述表面层的另一层中的结晶玻璃质量比所述片状物 件 该制品通过制备SiO 2 -Al 2 O 3 -EA CaO可结晶玻璃的片状片和较小的质量块，将前者放在模具的底部上以形成片状层，然后将后者放在片状片上， 以形成小质量层，并且在高于可结晶玻璃的软化点的温度下对两层进行热处理，以将这些块和块结合在一起并使玻璃结晶。

公开(公告)号：US5066524A

公开(公告)日：1991-11-19

申请号：US412851

申请日：1989-09-26

申请人： Yasuhiro Baba ,  Masanori Moritake ,  Takashi Sakane ,  Yoshio Hashibe ,  Takehiro Shibuya

发明人： Yasuhiro Baba ,  Masanori Moritake ,  Takashi Sakane ,  Yoshio Hashibe ,  Takehiro Shibuya

IPC分类号： C03C10/02 ,  B44F9/04 ,  C03C10/04 ,  C03C17/04

CPC分类号： C03C17/04 ,  B44F9/04 ,  Y10T428/22 ,  Y10T428/24802

摘要： A crystallized glass article with a colored surface pattern, which comprises a crystallized glass substrate having a surface and small glass masses having a color different from the substrate and dispersed and fusion-bonded in the surface to form the colored surface pattern. The crystallized glass article is produced by depositing and dispersing small glass masses with a color on a surface of a substrate of a crystallizable glass with a different color which can precipitate crystals therein with softening and deforming by heat-treating at a heat treating temperature higher than the softening point of the crystallizable glass, then heating the substrate together with the small glass masses at the heat treating temperature.

摘要翻译： 具有着色表面图案的结晶玻璃制品，其包括具有表面的结晶玻璃基板和具有与基板不同的颜色的小玻璃块，并且在表面中分散和熔合以形成着色表面图案。 结晶化玻璃制品通过在具有不同颜色的可结晶玻璃的基材的表面上沉积和分散小玻璃块而制成，其可以通过在高于 可结晶玻璃的软化点，然后在热处理温度下与小玻璃块一起加热基底。

公开(公告)号：US5275978A

公开(公告)日：1994-01-04

申请号：US4663

申请日：1993-01-14

申请人： Takehiro Shibuya ,  Takashi Sakane ,  Yoshio Hashibe

发明人： Takehiro Shibuya ,  Takashi Sakane ,  Yoshio Hashibe

IPC分类号： C03C1/06 ,  C03C10/00 ,  C03C10/04 ,  C03C14/00

CPC分类号： C03C1/06 ,  C03C10/0036 ,  C03C14/004 ,  C03C2214/04 ,  C03C2214/20

摘要： A crystallized glass article having a surface pattern like granite, marble or other natural stones with a line pattern of a desired color or colors, which is formed by fusion bonding small masses of a crystallizable glass material mixed with inorganic pigment powder at a heat-treating temperature higher than the softening point. The surface pattern comprises crystallized glass areas defined by the small masses in the surface layer of the article and the colored line pattern defined by the pigment dispersed in the interfaces between adjacent ones of the small masses in the surface layer.

摘要翻译： 一种具有花岗岩，大理石或其他天然石材的表面图案的结晶玻璃制品，其具有所需颜色或颜色的线条图案，其通过将小块可结晶玻璃材料与无机颜料粉末混合而形成，所述可结晶玻璃材料在热处理 温度高于软化点。 表面图案包括由物品表面层中的小质量限定的结晶玻璃区域和由分散在表面层中的相邻小块之间的界面中的颜料限定的着色线图案。

公开(公告)号：US4054435A

公开(公告)日：1977-10-18

申请号：US732451

申请日：1976-10-14

申请人： Takashi Sakane ,  Shigeharu Nakamura

发明人： Takashi Sakane ,  Shigeharu Nakamura

IPC分类号： C03B19/06 ,  C03B19/08 ,  C03B32/00 ,  C03C10/00 ,  C03C12/00 ,  E04C2/54 ,  C03B23/20

CPC分类号： E04C2/54 ,  C03B19/06 ,  C03B19/08 ,  C03B32/00 ,  C03C10/00 ,  C03C12/00

摘要： A crystallized glass article formed of discrete small bodies of crystallizable glass fusion-bonded together at their interfaces is characterized in that a first layer extending from the article surface to a predetermined depth is non-porous, a predetermined thickness of second layer connected to and beneath the first layer being porous. Each of the small bodies in the first layer has needle-like .beta.-wollastonite crystals extending from the surface of the body to the interior thereof in a direction perpendicular to the surface of the body. Accordingly the article is characterized by a surface pattern defined by small bodies due to the differences of orientation of needle-like .beta.-wollastonite crystals and by a reduced specific gravity.

摘要翻译： 由可分离的可结晶玻璃体构成的结晶玻璃制品在其界面处熔合在一起，其特征在于从制品表面延伸到预定深度的第一层是无孔的，第二层的预定厚度连接到下面 第一层是多孔的。 第一层中的每个小体具有从身体表面到垂直于身体表面的方向延伸到其内部的针状β-硅灰石晶体。 因此，由于针状β-硅灰石晶体的取向差异和比重降低，制品的特征在于由小体形成的表面图案。