公开(公告)号：US07507327B2

公开(公告)日：2009-03-24

申请号：US11227802

申请日：2005-09-14

申请人： Jeffrey M. Dysard ,  Zhigou Hou ,  Jonathan M. McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William E. Lewis

发明人： Jeffrey M. Dysard ,  Zhigou Hou ,  Jonathan M. McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William E. Lewis

IPC分类号： C10G19/073 ,  C10G29/04

CPC分类号： C10G45/02 ,  C10G19/073 ,  C10G29/04 ,  C10G65/04 ,  C10G67/10

摘要： Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than about 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.

摘要翻译： 在含有难溶性硫杂环化合物的烃流中，特别是那些表现出空间位阻的烃流中发现的耐火或硬硫通过与包含负载在固体支持组分上的具有游离钠的钠组分的钠试剂接触而从流中除去。 如果烃流含有更多的不稳定或易硫化物，那么通常通过加氢脱硫来处理至少大部分不稳定的硫，然后再与钠试剂接触。 这对于使用常规的加氢脱硫催化剂和条件将中等馏出物燃料流（例如柴油和喷气燃料馏分）的硫含量降低到低于约10wppm的水平是有用的。

公开(公告)号：US20060065577A1

公开(公告)日：2006-03-30

申请号：US11227802

申请日：2005-09-14

申请人： Jeffrey Dysard ,  Zhigou Hou ,  Jonathan McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William Lewis

发明人： Jeffrey Dysard ,  Zhigou Hou ,  Jonathan McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William Lewis

IPC分类号： C10G29/04 ,  C10G67/00

CPC分类号： C10G45/02 ,  C10G19/073 ,  C10G29/04 ,  C10G65/04 ,  C10G67/10

摘要： Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than about 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.