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33 条记录 (耗时 0.028 秒)

    Desulfurizing organosulfur heterocycles in feeds with supported sodium
    1.
    发明授权
    Desulfurizing organosulfur heterocycles in feeds with supported sodium 有权
    用负载的钠脱硫有机硫杂环

    公开(公告)号：US07507327B2

    公开(公告)日：2009-03-24

    申请号：US11227802

    申请日：2005-09-14

    申请人： Jeffrey M. Dysard ,  Zhigou Hou ,  Jonathan M. McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William E. Lewis

    发明人： Jeffrey M. Dysard ,  Zhigou Hou ,  Jonathan M. McConnachie ,  Andrzej Malek ,  Ramesh Gupta ,  William E. Lewis

    IPC分类号： C10G19/073 ,  C10G29/04

    CPC分类号： C10G45/02 ,  C10G19/073 ,  C10G29/04 ,  C10G65/04 ,  C10G67/10

    摘要： Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than about 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.

    摘要翻译： 在含有难溶性硫杂环化合物的烃流中，特别是那些表现出空间位阻的烃流中发现的耐火或硬硫通过与包含负载在固体支持组分上的具有游离钠的钠组分的钠试剂接触而从流中除去。 如果烃流含有更多的不稳定或易硫化物，那么通常通过加氢脱硫来处理至少大部分不稳定的硫，然后再与钠试剂接触。 这对于使用常规的加氢脱硫催化剂和条件将中等馏出物燃料流（例如柴油和喷气燃料馏分）的硫含量降低到低于约10wppm的水平是有用的。

    Method for reducing viscosity increase in sooted diesel oils
    4.
    发明授权
    Method for reducing viscosity increase in sooted diesel oils 失效
    减少柴油柴油粘度增加的方法

    公开(公告)号：US5837657A

    公开(公告)日：1998-11-17

    申请号：US982681

    申请日：1997-12-02

    申请人： Howard L. Fang ,  Jonathan M. McConnachie ,  Edward Ira Stiefel

    发明人： Howard L. Fang ,  Jonathan M. McConnachie ,  Edward Ira Stiefel

    IPC分类号： C10M135/18 ,  C10M137/10 ,  C10M159/18 ,  C10M135/00 ,  C10M139/00

    CPC分类号： C10M159/18 ,  C10M135/18 ,  C10M137/10 ,  C10M2219/068 ,  C10M2223/045 ,  C10M2227/09 ,  C10N2210/06 ,  C10N2240/102 ,  C10N2240/103

    摘要： The present invention is directed to a method for improving the performance of a sooted diesel oil and controlling soot induced viscosity increase by adding to a major amount of a diesel oil a minor amount of a composition comprising at least one compound having the formula Mo.sub.3 S.sub.k L.sub.n Q.sub.z and mixtures thereof wherein the L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 through 10, Q is selected from the group of neutral electron donating compounds such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes nonstoichiometric values.

    摘要翻译： 本发明涉及一种通过向主要量的柴油中加入少量含有至少一种具有式Mo3SkLnQz的化合物的组合物和混合物的混合物来提高烟灰柴油的性能并控制烟灰诱导的粘度增加的方法 其中L是具有足够数目的碳原子的具有有机基团的独立选择的配体，以使化合物在油中可溶或可分散，n为1至4，k从4至10变化，Q选自 中性给电子化合物如水，胺，醇，膦和醚，z范围为0至5，并包括非化学计量值。

    Fullerene compositions and preparation
    5.
    发明授权
    Fullerene compositions and preparation 失效
    富勒烯组成和制备

    公开(公告)号：US5372798A

    公开(公告)日：1994-12-13

    申请号：US207645

    申请日：1994-03-08

    申请人： Jonathan M. McConnachie ,  Edward I. Stiefel

    发明人： Jonathan M. McConnachie ,  Edward I. Stiefel

    IPC分类号： C01B19/00 ,  C01B31/02 ,  C01B31/00 ,  C01B7/00 ,  C01B17/00

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B19/002 ,  C01B31/0206 ,  C01B31/0213 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2006/10 ,  Y10S423/39 ,  Y10S977/737

    摘要： The invention relates to a composition that is the reaction of a fullerene containing at least one corrannulene ring structure and Y.sub.2 X.sub.2, wherein Y is Se or S, and X is Cl or Br. Generally, these compounds may be represented by the formula C.sup.f.sub.n X.sub.6 Y.sub.2 or more particularly C.sup.f.sub.n X.sub.5 (YYX). In the formula C.sup.f.sub.n more specifically, is a fullerene having at least one corrannulene ring structure. The compositions may be made by reacting fullerenes with Se.sub.2 X.sub.2 or S.sub.2 X.sub.2 wherein X is Cl or Br, preferably in liquid form and preferably heated for a time sufficient to produce the novel compositions. The compositions may be isolated in crystalline form by precipitation with a solvent such as hexane. In crystalline form the compositions may be represented by the generic formula C.sup.f.sub.n X.sub.8 Y.sub.4, or more particularly, C.sup.f.sub.n X.sub.5 (YYX).mY.sub.2 X.sub.2 because in crystalline form the compositions are typically associated with .mY.sub.2 X.sub.2 molecules wherein m is an integer at least equal to 1. The compositions have utility as crosslinking agents and lubricating oil and polymer additives, particularly as vulcanizing agents.

    摘要翻译： 本发明涉及一种组合物，其是含有至少一个corrannulene环结构的富勒烯与Y2X2的反应，其中Y为Se或S，X为Cl或Br。 通常，这些化合物可以由式CfnX6Y2或更特别是CfnX5（YYX）表示。 在式Cfn中更具体地，是具有至少一个corrannulene环结构的富勒烯。 组合物可以通过使富勒烯与Se2X2或S2X2反应制备，其中X是Cl或Br，优选液体形式，优选加热足以产生新组合物的时间。 组合物可以通过用溶剂如己烷沉淀而以结晶形式分离。 在结晶形式中，组合物可以由通式CfnX8Y4，或更具体地，CfnX5（YYX）.YYX2X2表示，因为在结晶形式中，组合物通常与.mY2X2分子缔合，其中m是至少等于1的整数。组合物 可用作交联剂和润滑油和聚合物添加剂，特别是作为硫化剂。

    Desulfurization of heavy hydrocarbons and conversion of resulting hydrosulfides utilizing a transition metal oxide
    8.
    发明申请
    Desulfurization of heavy hydrocarbons and conversion of resulting hydrosulfides utilizing a transition metal oxide 有权
    使用过渡金属氧化物对重质烃进行脱硫和转化所得氢硫化物

    公开(公告)号：US20100084316A1

    公开(公告)日：2010-04-08

    申请号：US12586824

    申请日：2009-09-29

    申请人： James R. Bielenberg ,  Jonathan M. McConnachie ,  Daniel P. Leta ,  Chris A. Wright ,  Leo D. Brown

    发明人： James R. Bielenberg ,  Jonathan M. McConnachie ,  Daniel P. Leta ,  Chris A. Wright ,  Leo D. Brown

    IPC分类号： C10G45/04 ,  C10G19/08

    CPC分类号： C10G19/08

    摘要： The present invention is a process for desulfurizing hydrocarbon feedstreams with alkali metal compounds and regenerating the alkali metal compounds via the use of a transition metal oxide. The present invention employs the use of a transition metal oxide, preferably copper oxide, in order to convert spent alkali metal hydrosulfides in the regeneration of the alkali hydroxide compounds for reutilization in the desulfurization process for the hydrocarbon feedstreams. Additionally, in preferred embodiments of the processes disclosed herein, carbonates which may be detrimental to the overall desulfurization process and related equipment are removed from the regenerated alkali metal stream.

    摘要翻译： 本发明是一种用碱金属化合物对烃类进料流进行脱硫和通过使用过渡金属氧化物再生碱金属化合物的方法。 本发明使用过渡金属氧化物，优选氧化铜，以便在碱性氢氧化物化合物的再生中转化废碱金属氢硫化物，以便在烃进料流的脱硫过程中再利用。 另外，在本文公开的方法的优选实施方案中，可从再生的碱金属流中除去可能对整个脱硫过程和相关设备有害的碳酸盐。