Desulfurizing organosulfur heterocycles in feeds with supported sodium
    1.
    发明授权
    Desulfurizing organosulfur heterocycles in feeds with supported sodium 有权
    用负载的钠脱硫有机硫杂环

    公开(公告)号:US07507327B2

    公开(公告)日:2009-03-24

    申请号:US11227802

    申请日:2005-09-14

    IPC分类号: C10G19/073 C10G29/04

    摘要: Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than about 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.

    摘要翻译: 在含有难溶性硫杂环化合物的烃流中,特别是那些表现出空间位阻的烃流中发现的耐火或硬硫通过与包含负载在固体支持组分上的具有游离钠的钠组分的钠试剂接触而从流中除去。 如果烃流含有更多的不稳定或易硫化物,那么通常通过加氢脱硫来处理至少大部分不稳定的硫,然后再与钠试剂接触。 这对于使用常规的加氢脱硫催化剂和条件将中等馏出物燃料流(例如柴油和喷气燃料馏分)的硫含量降低到低于约10wppm的水平是有用的。

    Two stage hydroprocessing with vapor-liquid interstage contacting for
vapor heteroatom removal
    2.
    发明授权
    Two stage hydroprocessing with vapor-liquid interstage contacting for vapor heteroatom removal 有权
    双级加氢处理,气 - 液间级接触气相除去杂原子

    公开(公告)号:US5968346A

    公开(公告)日:1999-10-19

    申请号:US153921

    申请日:1998-09-16

    摘要: A hydroprocessing process includes two hydroprocessing reaction stages, both of which produce a liquid and a vapor effluent, and a liquid-vapor contacting stage. The first stage vapor effluent contains impurities, such as heteroatom compounds, which are removed from the vapor by contact with processed liquid effluent derived from one or both reaction stages and, optionally, also liquid recovered from processed vapor. The first and contact stage liquid effluents are passed into the second stage to finish the hydoprocessing. The contact and second stage vapor effluents are cooled to recover additional hydroprocessed product liquid.

    摘要翻译: 加氢处理方法包括两个加氢处理反应阶段,它们都产生液体和蒸汽流出物,以及液 - 气接触阶段。 第一级蒸汽流出物含有诸如杂原子化合物的杂质,其通过与来自一个或两个反应级的处理液体流出物接触而从蒸气中除去,并且任选地还含有从经处理的蒸气回收的液体。 第一阶段和接触阶段的液体流出物进入第二阶段以完成加氢处理。 将接触和第二级蒸汽流出物冷却以回收另外的加氢处理产物液体。

    Co-processing of diesel biofeed and heavy oil
    6.
    发明授权
    Co-processing of diesel biofeed and heavy oil 有权
    柴油生物饲料和重油的协同加工

    公开(公告)号:US08632675B2

    公开(公告)日:2014-01-21

    申请号:US12653459

    申请日:2009-12-15

    IPC分类号: C10G65/04 C10G65/10 C10G45/02

    摘要: Processes are provided for producing a diesel fuel product having a sulfur content of 10 ppm by weight or less from feed sources that include up to 50% by weight of a biocomponent feedstock. The biocomponent feedstock is co-processed with a heavy oil feed in a severe hydrotreating stage. The product from the severe hydrotreatment stage is fractionated to separate out a diesel boiling range fraction, which is then separately hydrotreated.

    摘要翻译: 提供了用于生产具有包含至多50重量%的生物组分原料的进料源的硫含量为10重量ppm以下的柴油燃料产品的方法。 生物组分原料在重质加氢处理阶段与重油进料共处理。 将来自严重加氢处理阶段的产物分馏以分离柴油沸程馏分,然后分别加氢处理。

    Hydrocracker post-treat catalyst for production of low sulfur fuels
    8.
    发明申请
    Hydrocracker post-treat catalyst for production of low sulfur fuels 有权
    用于生产低硫燃料的加氢裂化器后处理催化剂

    公开(公告)号:US20070278135A1

    公开(公告)日:2007-12-06

    申请号:US11446251

    申请日:2006-06-02

    IPC分类号: C10G65/00 C10G69/00

    摘要: A hydrocracking process for converting a petroleum feedstock to higher gravity, lower sulfur products, especially ultra low sulfur road diesel fuel. The process may be operated as a single-stage or two-stage hydrocracking. In each case, a hydrocracking step is followed directly by a post-treat hydrodesulfurization zone using a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals with a ratio of Group VIB metal to Group VIII non-noble metal is from about 10:1 to about 1:10. In the two-stage option with interstage ammonia removal, the initial hydrocracking step may be followed by hydrodesulfurization using the bulk multimetallic catalyst prior to the ammonia removal which is followed by the second hydrocracking step. A final hydrodesulfurization over the bulk multimetallic catalyst may follow. The hydrodesulfurization over the bulk multimetallic catalyst is carried out at a pressure of at least 25 barg and preferably at least 40 barg.

    摘要翻译: 用于将石油原料转化为更高重力,较低硫产物,特别是超低硫道路柴油的加氢裂化方法。 该方法可以作为单级或两级加氢裂化操作。 在每种情况下,加氢裂化步骤直接通过后处理加氢脱硫区,使用由至少一种VIII族非贵金属和至少两种VIB族金属与VIII族的VIB族金属组成的本体多金属催化剂 非贵金属为约10:1至约1:10。 在阶段氨除去的两阶段选择中,初始加氢裂化步骤之后可以在除氨之前使用大量多金属催化剂进行加氢脱硫,其后是第二加氢裂化步骤。 可以遵循大量多金属催化剂的最终加氢脱硫。 本体多金属催化剂上的加氢脱硫在至少25barg,优选至少40barg的压力下进行。

    Container for freezable liquid
    10.
    发明授权
    Container for freezable liquid 失效
    集装箱可冻结液体

    公开(公告)号:US4656840A

    公开(公告)日:1987-04-14

    申请号:US802735

    申请日:1985-11-29

    IPC分类号: B65D21/024 F25D3/08

    摘要: A container filled with a freezable liquid for use in refrigerating or temporarily cooling purposes. The container of the invention is generally rectangular and has two plugs each on its face and one side. Opposite these plugs and in contra position to the plugs, on the back and other side of the container, are corresponding recesses. The recesses and plugs are formed in order that the plugs of one container fit into the recesses of a like container, thus allowing the containers to be fastened together. Thus, when filled with freezable liquid and frozen, two or more containers may be connected, at either their sides or face-to-back, to form blocks of frozen containers. In addition to the advantages of using containers filled with freezable liquid over using water-ice as a coolant, which advantages have been found in the prior art, use of blocks of the frozen containers of the present invention provides longer lasting cooling capability and the convenience of the cooling medium being adaptable to the size and shape of the cooling compartment.

    摘要翻译: 填充有用于制冷或临时冷却目的的可冷冻液体的容器。 本发明的容器通常是矩形的,并且在其表面和一侧上具有两个插头。 与这些插头相反并且与容器的背面和另一侧上的塞子相反的位置是相应的凹槽。 形成凹部和塞子,使得一个容器的塞子装配到类似的容器的凹部中,从而允许容器紧固在一起。 因此,当填充有可冷冻液体并冷冻时,两个或更多个容器可以在其两侧或面对面地连接以形成冷冻容器块。 除了使用装有可冷冻液体的容器以使用水冰作为冷却剂的优点之外,在现有技术中已经发现了这些优点,因此本发明的冷冻容器块的使用提供了更持久的冷却能力和便利性 的冷却介质适于冷却室的尺寸和形状。