公开(公告)号：US3856925A

公开(公告)日：1974-12-24

申请号：US28140972

申请日：1972-08-17

申请人： AGENCY IND SCIENCE TECHN

发明人： FUKUDA K ,  KODERA Y ,  TODO N

IPC分类号： C01B3/04 ,  B01J27/00 ,  B01J27/04 ,  B01J37/20 ,  C01B3/12 ,  C01B17/04 ,  C01B31/26 ,  C01B1/03

CPC分类号： C01B3/12 ,  B01J27/04 ,  B01J37/20 ,  C01B32/70 ,  Y02E60/364 ,  Y02P20/584

摘要： Hydrogen is produced from hydrogen sulfide by using, as a catalyst, the sulfide of a metal selected from the class consisting of transition metals of Group V such as vanadium, of Group IV such as molybdenum, tungsten and chromium and of group VIII such as iron, cobalt, nickel, palladium and rhodium of the Periodic Table of the Elements. When hydrogen sulfide is supplied to a reaction system using therein the said catalyst, it is separated into hydrogen and sulfur and the sulfur thus separated is deposited and accumulated on the catalyst. Regeneration of the catalyst is accomplished by causing carbon monoxide or nitrogen monoxide to react on the deposited sulfur so that the sulfur is removed from the catalyst in the form of carbonyl sulfide or nitrogen oxysulfide.

摘要翻译： 通过使用选自V族过渡金属如钒，IV族如钨，钨和铬等第Ⅷ族金属和第Ⅷ族铁的金属的硫化物作为催化剂，从硫化氢中产生氢。 ，元素周期表的钴，镍，钯和铑。 当向其中使用所述催化剂的反应系统供给硫化氢时，将其分离成氢气和硫气，并将所分离的硫沉积并积累在催化剂上。 催化剂的再生通过使一氧化碳或一氧化氮在沉积的硫上反应来实现，使得硫以硫化羰或硫氧化硫的形式从催化剂中除去。

公开(公告)号：US3751496A

公开(公告)日：1973-08-07

申请号：US3751496D

申请日：1969-08-07

申请人： AGENCY IND SCIENCE TECHN

发明人： KURITA M ,  SATO T ,  TODO N ,  HAGIWARA H

IPC分类号： B01J21/00 ,  B01J27/00 ,  C07B61/00 ,  C07C17/00 ,  C07C17/156 ,  C07C21/09 ,  C07C67/00 ,  C07C21/00

CPC分类号： C07C17/156 ,  C07C21/09

摘要： A PROCESS FOR PREPARING DICHLOROBUTENE WHICH COMPRISES REACTING TOGETHER BUTADIENE, HYDROGEN CHLORIDE AND OXYGEN AT A TEMPERATURE OF 80*C. TO 300*C. IN THE PRESENCE OF A CATALYST CONSISTING OF A COPPER SALT, PHOSPHORIC ACID AND AN ALKALI CHLORIDE OR OF A COPPER SALT AND AN ALKALI METAL PHOSPHATE WHICH CATALYST IS SUPPORTED ON A CARRIER.