公开(公告)号：US3567792A

公开(公告)日：1971-03-02

申请号：US3567792D

申请日：1968-12-26

申请人： AMERIPOL INC

发明人： BOZIK JOHN E ,  SWIFT HAROLD E ,  WU CHING YONG

IPC分类号： B01J31/14 ,  B01J31/16 ,  B01J31/24 ,  B01J31/26 ,  C07C2/04 ,  C07C2/76 ,  C07C3/00

CPC分类号： B01J31/143 ,  B01J31/16 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/26 ,  B01J2531/847 ,  C07C2/04 ,  C07C2/76 ,  C07C2527/00 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/21

摘要： PROCESS FOR THE PREPARATION OF TRIOLEFINS COMPRISING CONDENSING DIOLEFINS AND OLEFINS IN CONTACT WITH A CATALYST SYSTEM COMPRISED OF: (1) A NICKEL SALT, (2) AN ORGANOALUMINUM COMPOUND AND (3) A SECONDARY PHOSPHINE LIGAND.

公开(公告)号：US3678022A

公开(公告)日：1972-07-18

申请号：US3678022D

申请日：1970-07-09

申请人： AMERIPOL INC

发明人： BOZIK JOHN E ,  SWIFT HAROLD E ,  WU CHING YONG

IPC分类号： C08F4/12 ,  C08F36/04 ,  C08G65/12 ,  C08F3/22 ,  C08F3/74

CPC分类号： C08G65/12 ,  C08F4/12 ,  C08F10/00 ,  C08F36/04 ,  C08F4/7027 ,  C08F4/7006 ,  C08F4/68146 ,  C08F4/69146 ,  C08F4/60058 ,  C08F4/70

摘要： Process for polymerizing olefins, diolefins and alkylene oxides in the presence of a catalyst system comprised of an iron complex, a trialkyl aluminum compound and a bidentate ligand capable of both p i ( pi and sigma ( sigma ) banding to form a five or six-membered ring.

摘要翻译： 在由铁络合物，三烷基铝化合物和双齿配位体组成的催化剂体系存在下聚合烯烃，二烯烃和烯化氧的方法，其能够将pi（pi和σ（σ）条带化）形成五或六元 环。

公开(公告)号：US3677968A

公开(公告)日：1972-07-18

申请号：US3677968D

申请日：1970-07-09

申请人： AMERIPOL INC

发明人： DOZIK JOHN E ,  SWIFT HAROLD E ,  WU CHING-YONG

IPC分类号： C08F4/12 ,  C08F10/00 ,  C08F36/04 ,  C08G65/12 ,  C08D3/06 ,  C08D3/08

CPC分类号： C08G65/12 ,  C08F4/12 ,  C08F36/04 ,  C08F2410/03 ,  C08F4/7027 ,  C08F4/68146 ,  C08F4/69146 ,  C08F4/60058 ,  C08F4/7032 ,  C08F4/7006 ,  C08F4/70

摘要： A COORDINATION CATALYST FOR POLYMERIZING OLEFINS, DIOLEFINS AND ALKYLENE OXIDES, CONSISTING ESSENTIALLY OF

(A) AN IRON COMPLEX COMPRISING A LIGAND CONTAINING OXYGEN DONOR ATOMS AND SELECTED FROM THE GROUP CONSISTING OF IRON ACETYLACETONATE, IRON OCTOATE AND IRON NAPHTHENATE; (B) A TRIALKYL ALUMINUM COMPOUND; AND (C) A BIDENATE LIGAND CAPABLE OF BOTH PI AND SIGMA BONDING TO FORM A FIVE- OR SIX-MEMBERED CHELATE RING, SAID LIGAND BEING CHARACTERIZED BY THE STRUCTURAL FORMULA

((R)Y-PYRID-2-YL)-(C(-R)2)X-C(-R)M=N-(Q)M

WHEREIN M IS A NUMBER FROM 0 TO 1, X IS A NUMBER FROM 0 TO 1, Y IS A NUMBER FROM 0 TO ABOUT 4, R IS A RADICAL SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL, ARYL, HALOGEN, HYDROXYL, AND ACETOXY, AND Q IS A RADICAL SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL, HALOGEN, HYDROXYL AND ACETOXY, THE MAJOR PORTION OF SAID SIGMA BONDING BEING ATTRIBUTABLE TO THE RING NITROGEN, WHEREIN THE MOLAR RATIO OF TRIALKYL ALUMINUM COMPOUND TO IRON COMPLEX IS FROM ABOUT 1/1 TO 4/1 AND THE MOLAR RATIO OF BIDENTATE LIGAND TO THE IRON COMPLEX IS FROM ABOUT 0.1/1 TO ABOUT 2.5/1.