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1.发明授权1:1 alternating copolymers of carbonyl or thiocarbonyl-containing non-conjugated compounds and conjugated compounds and method of preparation 失效1：1替代苯乙烯或含巯基的非共轭化合物和共轭化合物的共聚物及其制备方法
公开(公告)号：US3671492A
公开(公告)日：1972-06-20
申请号：US2008770
申请日：1970-03-16
申请人： SUMITOMO CHEMICAL CO
CPC分类号： C08F4/12 , C08F214/00 , C08F220/14 , C08F236/18
摘要： A novel alternating copolymer is prepared by copolymerizing a compound having a polar group, such as a carbonyl or thiocarbonyl group, at a non-conjugated position and a conjugated vinyl compound in the presence of an organoaluminum halide. Alternating copolymers thus-produced are superior in thermal stability to conventional random copolymers and is resistant to coloration. Alternating copolymers obtained by copolymerizing vinyl acetate and methyl acrylate or acrylonitrile are preferred examples of these products.
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2.发明授权Metal nitride catalysts for preparing triazines and cross-linked nitrile polymers 失效用于制备TRIAZINES和交联NITRILE聚合物的金属氮化物催化剂
公开(公告)号：US3637628A
公开(公告)日：1972-01-25
申请号：US3637628D
申请日：1970-11-12
申请人： HOOKER CHEMICAL CORP
发明人： DORFMAN EDWIN , EMERSON WILLIAM E
CPC分类号： C08F8/00
摘要： THIS INVENTION RELATES (A) TO A PROCESS FOR PRODUCING A TRIAZINE BY REACTION OF A PERFLUOROALKANE NITRILE IN THE PRESENCE OF A CATALYTIC AMOUNT OF A METAL NITRIDE AND (B) THE CROSS-LINKING OF A POLYMER OR COPOLYMER CONTAINING AT LEAST GREATER THAN AN AVERAGE OF ONE CYANOHALOALKYL GROUP ON THE CHAIN OF THE POLYMER OR COPOLYMER, TO FORM A CROSS-LINKED POLYMER OR COPOLYMER, IN THE PRESENCE OF A METAL NITRIDE.
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3.发明授权Coating compositions comprising drying oil acid esters of styrene-acrolein copolymer-polymer reaction products 失效包含苯乙烯 - 丙烯共聚物聚合物反应产物的干燥油酸酯的涂料组合物
公开(公告)号：US3449277A
公开(公告)日：1969-06-10
申请号：US3449277D
申请日：1966-02-03
申请人： GULF OIL CORP
发明人： SMITH WAYNE E , MANTELL GERALD J , CHAPIN EARL C
CPC分类号： C08F8/00 , C08F2800/20 , C08F2810/50 , C08F8/48 , C08F212/08
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4.发明授权Polymerization of ethylenically unsaturated monomers with a 1,1,2,2-tetracarboalkoxy-diaryl-ethane 失效具有1,1,2,2-三氟甲氧基二乙酸乙酯的乙烯基不饱和单体的聚合
公开(公告)号：US3896099A
公开(公告)日：1975-07-22
申请号：US40160473
申请日：1973-09-28
申请人： AKZO NV
IPC分类号： C07C49/697 , C07C49/755 , C08F4/00 , C08F283/01 , C08K5/11 , C07C69/76 , C08F3/74 , C08F7/04
CPC分类号： C08K5/11 , C07C49/697 , C07C49/755 , C08F4/00 , C08F283/01 , Y10S525/904
摘要： A process for the free radical-initiated polymerization of ethylenically unsaturated monomers in the presence of a free radical initiator compound comprising a 1,1,2,2-tetracarboalkoxydiaryl-ethane.
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公开(公告)号：US3711448A
公开(公告)日：1973-01-16
申请号：US3711448D
申请日：1971-06-07
申请人： SUTURES INC
CPC分类号： C07D295/185 , B01D71/44 , C08F26/06 , C08F28/06
摘要： MONOMERS HAVING THE FORMULA:
CH2=C(-C*N)-CO-N
WHEREIN X IS OXYGEN, SULFUR OR -CH2-, AND FILM-FORMING POLYMERS THEREOF. THE MONOMERS ARE USEFUL TO FORM POLYMERIC ADHESIVES.-
6.发明授权
公开(公告)号：US3647753A
公开(公告)日：1972-03-07
申请号：US86677569
申请日：1969-10-15
申请人： SUMITOMO CHEMICAL CO
CPC分类号： C08F4/12 , C08F214/00 , C08F220/14 , C08F236/18
摘要： A COMPOUND HAVING A C$N OR C=O GROUP IN THE CONJUGATED POSITION RELATIVE TO THE C=C BOND FORMS A COMPLEX WITH AN ORGANOHALIDE OF ALUMINUM OR BORON. AN ALTERNATING COPOLYMER IS OBTAINED FROM A MONOMER SATISFYING SAID REQUIREMENT AND INNER OLEFINIC MONOMERS OR POLYMERS OR ACETYLENES HAVING A DONOR PROPERTY. IN THIS CASE, AN ORGANOALUMINUM HALIDE OR AN ORGANOBORON HALIDE IS SUITABLE AS THE CATALYST FOR SAID COPOLYMERIZATION. THIS TYPE OF ACITIVE SPECIES CAN ALSO BE OBTAINED BY MIXING AN ORGANIC COMPOUND OF A METAL OF GROUP II, III OR IV OF THE PERIODIC TABLE WITH A HALIDE OF A METAL OF GROUP III OR IV IN THE PRESENCE OF THE ABOVE-MENTIONED CONJUGATED MONOMER.
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7.发明授权Silver salt catalysts for preparing triazines and cross-linked nitrile polymers 失效用于制备TRIAZINES和交联NITRILE聚合物的银盐催化剂
公开(公告)号：US3637629A
公开(公告)日：1972-01-25
申请号：US3637629D
申请日：1970-11-12
申请人： HOOKER CHEMICAL CORP
发明人： DORFMAN EDWIN , EMERSON WILLIAM E
CPC分类号： C08F8/00 , C08G73/0661
摘要： THIS INVENTION RELATES (A) TO A PROCESS FOR PRODUCING A TRIAZINE BY REACTION OF A PERFLUOROALKANE NITRILE IN THE PRESENCE OF A CATALYTIC AMOUNT OF A SILVER SALT, AND (B) THE CROSS-LINKING POLYMER OR COPOLYMER CONTAINING GREATER THAN THE AVERAGE OF ONE CYANOHALOALKYL GROUP PER MOLECULE OF THE POLYMER OR COPOLYMER, TO FORM A CROSS-LINKED POLYMER OR COPOLYMER, IN THE PRESENCE OF A SILVER SALT.
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8.发明授权1:1 alternating copolymers of substituted conjugated vinyl compounds and olefinic compounds and process for producing the same 失效1：1取代的联苯乙烯化合物和烯烃化合物的交替共聚物及其生产方法
公开(公告)号：US3629215A
公开(公告)日：1971-12-21
申请号：US3629215D
申请日：1969-10-31
申请人： SUMITOMO CHEMICAL CO
CPC分类号： C08F4/12 , C08F214/00 , C08F220/14 , C08F236/18
摘要： AN ALTERNATING COPOLYMER CONSISTS OF (A) A TERMINALLY UNSATURATED OLEFINIC COMPOUND, FOR EXAMPLE, AN A-OLEFIN, AN ISOOLEFIN, OR A HALOGENATED OLEFINIC COMPOUND (VINYL) CHLORIDE, VINYLIDENE CHLORIDE, ALLYL CHLORIDE OR THE LIKE) AND (B) A SUBSTITUTED CONJUGATED VINYL COMPOUND, SUCH AS A SUBSTITUTED ARCYLONITRILE OR A SUBSTITUTED ARCYL ACID DERIVATIVE (ESTERS, AMIDES, ACIDS, ACID HALIDES, KETONES, ACOLEIN AND THE LIKE WHICH HAS A SUBSTITUENT, SUCH AS A HYDROCARBON, HALOGENETED HYDROCARBON OR HALOGEN SUBSTITUENT ON THE A-OR B-POSITION. SAID ALTERNATING COPOLYMER CAN BE PREPARED BY SUBJECTING SAID MONOMERS TO COPOLYMERIZATION WITH AN ORGANOALUMINUM HALIDE OR AN ORGANOBORON HALIDE OR A PRODUCT OF REACTION BETWEEN AN ORGANIC COMPOUND OF A METAL OF GROUPS IIIB, IIIB AND IVB OF THE PERIODIC TABLE AND A HALIDE OF A METAL OF GROUPS IIIB AND IVB OF THE PERIODIC TABLE IN THE PRESENCE OF AT LEAST SAID SUBSTITUTED CONJUGATED VINYL COMPOUND, AT LEAST ONE OF SAIG ORGANIC COMPOUND AND HALIDE BEING ALUMINUM OR BORON-CONTAING COMPOUND.
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公开(公告)号：US3503945A
公开(公告)日：1970-03-31
申请号：US3503945D
申请日：1966-12-02
申请人： DOW CORNING
发明人： KIM YUNG KI
IPC分类号： C07C17/278 , C07C51/093 , C07C53/21 , C07C57/52 , C07F7/08 , C08F20/22 , C08F20/52 , C08F20/62 , C09D127/12 , C08F3/62 , C08F3/74 , C08F3/90
CPC分类号： C10M3/00 , C07C17/278 , C07C51/093 , C07C53/21 , C07C57/52 , C07F7/0892 , C08F20/22 , C08F20/62 , C10M2213/00 , C10M2213/04 , C10M2213/06 , C10M2217/024 , C10M2217/026 , C10M2217/06 , C07C19/14
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10.发明授权Method for initiating polymerization of cyanoacrylate monomers and comonomer blends thereof to give reproducible and predetermined gel/transition time characteristics 失效用于引发氰基丙烯酸酯单体和共聚单体共混物的聚合的方法，以提供可再现和预定的凝胶/转变时间特征
公开(公告)号：US3903055A
公开(公告)日：1975-09-02
申请号：US42204773
申请日：1973-12-05
申请人： JOHNSON & JOHNSON
发明人： BUCK CARL J
IPC分类号： A61K6/00 , A61K6/083 , C08F22/30 , C08F22/32 , C08F122/32 , C09D4/00 , C09J4/00 , C09J5/00 , C08F3/74 , C08G33/02
CPC分类号： A61K6/0023 , A61K6/005 , A61K6/083 , C08F22/30 , C08F22/32 , C08F122/32 , C09D4/00 , C09J4/00 , C09J5/00 , Y10S528/92 , C08F222/00 , C08L35/04
摘要： A method is disclosed for initiating the polymerization of small amounts of relatively sensitive liquid monomer compositions, comprising esters of cyanoacrylic acid, by means of a polymerization catalyzing particle adapted to be added to the monomer composition and then separated from the same prior to gelation of the monomer. The catalyzing particle may be in the form of a discrete particle such as beads, chips, or the like, or in the form of a rod sufficiently long so that the same can be used to simultaneously stir and activate the monomer.
摘要翻译： 公开了一种用于通过适于加入到单体组合物中的聚合催化剂颗粒引发少量相对敏感的液体单体组合物聚合的方法，其包括氰基丙烯酸酯，然后在凝胶化之前与其分离 单体。 催化颗粒可以是离散颗粒的形式，例如珠粒，碎屑等，或以足够长的棒的形式，使得它们可以用于同时搅拌和活化单体。
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