公开(公告)号：US20150094432A1

公开(公告)日：2015-04-02

申请号：US14381247

申请日：2013-02-22

Applicant: ARKEMA FRANCE

Inventor： Philippe Leduc ,  Thierry Lannuzel ,  Dominique Garrait ,  Serge Hub ,  Emmanuel Guiraud ,  Fabrice Domingues Dos Santos

IPC: C07C17/23 ,  C08F214/22

CPC classification number: C07C17/23 ,  B01J23/44 ,  B01J35/1009 ,  B01J35/1042 ,  C07C17/383 ,  C08F214/22 ,  H01L41/193 ,  H01L41/45 ,  C07C21/18

Abstract: The present invention relates to the preparation of trifluoroethylene (VF3 or TrFE) by hydrogenolysis of chlorotrifluoroethylene (CTFE) in the gaseous phase over a group VIII metal catalyst deposited on a support. This method can be used to obtain VF3 in an economical manner in conditions which minimize the risk of explosion of this molecule. Using a catalyst containing a group VIII metal and, more specifically, containing Pd deposited on a support and a specific series of steps of separation and purification makes it possible to obtain excellent CTFE conversion rates and high selectivity in VF3 at atmospheric pressure and at low temperatures.

Abstract translation: 本发明涉及通过在沉积在载体上的VIII族金属催化剂上在气相中氢氯三氟乙烯（CTFE）的氢解制备三氟乙烯（VF3或TrFE）。 该方法可以以最小化该分子的爆炸危险的条件经济地获得VF3。 使用含有VIII族金属的催化剂，更具体地说，含有沉积在载体上的Pd和特定的一系列分离和纯化步骤使得可以在常压和低温下获得优异的CTFE转化率和VF3的高选择性 。

公开(公告)号：US09447003B2

公开(公告)日：2016-09-20

申请号：US14381247

申请日：2013-02-22

Applicant: ARKEMA FRANCE

Inventor： Philippe Leduc ,  Thierry Lannuzel ,  Dominique Garrait ,  Serge Hub ,  Emmanuel Guiraud ,  Fabrice Domingues Dos Santos

IPC: C07C17/23 ,  C08F214/22 ,  B01J35/10 ,  B01J23/44 ,  C07C17/383 ,  H01L41/45 ,  H01L41/193

CPC classification number: C07C17/23 ,  B01J23/44 ,  B01J35/1009 ,  B01J35/1042 ,  C07C17/383 ,  C08F214/22 ,  H01L41/193 ,  H01L41/45 ,  C07C21/18

Abstract: The present invention relates to the preparation of trifluoroethylene (VF3 or TrFE) by hydrogenolyzis of chlorotrifluoroethylene (CTFE) in the gaseous phase over a group VIII metal catalyst deposited on a support. This method can be used to obtain VF3 in an economical manner in conditions which minimize the risk of explosion of this molecule. Using a catalyst containing a group VIII metal and, more specifically, containing Pd deposited on a support and a specific series of steps of separation and purification makes it possible to obtain excellent CTFE conversion rates and high selectivity in VF3 at atmospheric pressure and at low temperatures.

Abstract translation: 本发明涉及在沉积在载体上的VIII族金属催化剂上，在气相中通过三氟氯乙烯（CTFE）的氢解制备三氟乙烯（VF3或TrFE）。 该方法可以以最小化该分子的爆炸危险的条件经济地获得VF3。 使用含有VIII族金属的催化剂，更具体地说，含有沉积在载体上的Pd和特定的一系列分离和纯化步骤使得可以在常压和低温下获得优异的CTFE转化率和VF3的高选择性 。