Lamp For Photochemical Reactor With Light-Emitting Diodes

    公开(公告)号:US20230099496A1

    公开(公告)日:2023-03-30

    申请号:US17760131

    申请日:2021-02-22

    Applicant: ARKEMA FRANCE

    Abstract: A lamp for a photochemical reactor, including: a support member made of a material having a thermal conductivity greater than or equal to 100W/mK at 20° C. and including at least one channel configured to contain a coolant fluid; at least one printed circuit mounted on the support member; and at least one light-emitting diode mounted on the printed circuit. A photochemical reactor including such a lamp, and a method for preparing a cycloalkanone oxime or a lactam using such a lamp.

    METHOD FOR PREPARING LACTAMES, COMPRISING A PHOTONITROSATION STEP, FOLLOWED BY A BECKMANN TRANSPOSITION STEP
    3.
    发明申请
    METHOD FOR PREPARING LACTAMES, COMPRISING A PHOTONITROSATION STEP, FOLLOWED BY A BECKMANN TRANSPOSITION STEP 有权
    制备LACTAMES的方法,包括光催化步骤,由BECKMANN传输步骤

    公开(公告)号:US20140246303A1

    公开(公告)日:2014-09-04

    申请号:US14252610

    申请日:2014-04-14

    Applicant: ARKEMA FRANCE

    Inventor: Thierry AUBERT

    Abstract: The invention relates to a method for preparing lactames, according to which a photonitrosation of a cycloalkane is carried out using nitrosyl chloride (NOCI). According to the invention, said photonitrosation is carried out by means of LEDs emitting a monochromatic light. The method according to the invention can also include a step comprising Beckmann transposition/dechlorination of the oxime hydrochloride generated during said phonitrosation, preferably carried out in a glass microreactor.

    Abstract translation: 本发明涉及一种制备内酰胺的方法,根据该方法,使用亚硝酰氯(NOCI)进行环烷烃的光子离子化。 根据本发明,所述光子离子化是通过发射单色光的LED进行的。 根据本发明的方法还可以包括一个步骤,该步骤包括贝克曼转移/脱氯在所述发声过程中产生的肟盐酸盐,优选在玻璃微反应器中进行。

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