公开(公告)号：US09617379B2

公开(公告)日：2017-04-11

申请号：US15233981

申请日：2016-08-11

申请人： Asahi Glass Company, Limited

发明人： Takashi Okazoe ,  Masayuki Miyazaki ,  Kazuya Oharu ,  Tomoyuki Fujita ,  Shinji Wada ,  Koichi Murata ,  Naoko Shirota

IPC分类号： C08G63/02 ,  C08G64/00 ,  C08G64/30 ,  C07C29/38 ,  C07C67/00 ,  C07C67/14 ,  C07C67/317 ,  C07C68/00 ,  C07C68/06 ,  C07C45/63 ,  C07C49/16 ,  C07C51/16 ,  C07C51/377 ,  C07C57/04 ,  C07C17/361 ,  C08G64/06

CPC分类号： C08G64/307 ,  C07C17/361 ,  C07C29/38 ,  C07C45/63 ,  C07C49/16 ,  C07C51/16 ,  C07C51/377 ,  C07C57/04 ,  C07C67/00 ,  C07C67/14 ,  C07C67/317 ,  C07C68/00 ,  C07C68/06 ,  C08G64/00 ,  C08G64/06 ,  C07C69/96 ,  C07C31/36 ,  C07C69/63 ,  C07C69/54

摘要： The present invention relates to a method for producing a carbonate compound and methacrylic acid or an ester thereof, containing a step (a1) of obtaining hexachloroacetone and hydrogen chloride from acetone and chlorine molecule, a step (a2) of obtaining a dialkyl carbonate and chloroform from hexachloroacetone and an alkyl alcohol, a step (b1) of obtaining 1,1,1-trichloro-2-methyl-2-propanol from chloroform and acetone, a step (b2+b3 or b4) of obtaining methacrylic acid or an ester thereof and hydrogen chloride from 1,1,1-trichloro-2-methyl-2-propanol and water or an alcohol, and a step (c1 or c2) of obtaining chlorine molecule by reacting hydrogen chloride with oxygen molecule.

公开(公告)号：US09598345B2

公开(公告)日：2017-03-21

申请号：US14991393

申请日：2016-01-08

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Tomoyuki Fujita ,  Koichi Murata ,  Naoko Shirota ,  Yusuke Suzuki ,  Daisuke Jomuta

IPC分类号： C07C67/10 ,  C07C67/00 ,  C07C51/093

CPC分类号： C07C67/10 ,  C07C51/093 ,  C07C67/00 ,  Y02P20/582 ,  C07C69/54 ,  C07C57/04

摘要： The present invention relates to a method for producing an unsaturated-acid ester or an unsaturated acid, containing a step of reacting a compound (1) represented by the following formula (1) with a compound represented by the following formula (2) (excluding the compound (1)) in the presence of a Lewis acid catalyst at a temperature of the boiling point of the compound (1) or higher and 350° C. or lower, thereby obtaining products including a compound represented by the following formula (3): (in formula (1) and formula (3), R1, R2 and R4 each independently may be hydrogen atom or an alkyl group, R3 and R5 each independently are hydrogen atom or a deuterium atom, and X is a halogen atom; in formula (2) and formula (3), R6 may be hydrogen atom, an alkyl group or an aryl group, and R7 is hydrogen atom or a deuterium atom).

公开(公告)号：US09238612B2

公开(公告)日：2016-01-19

申请号：US14636510

申请日：2015-03-03

申请人： Asahi Glass Company, Limited

发明人： Tomoyuki Fujita ,  Shinji Wada ,  Takashi Okazoe ,  Koichi Murata

IPC分类号： C07C67/317 ,  C07C67/40 ,  C07C67/00 ,  C07C51/093 ,  C07C51/377

CPC分类号： C07C67/317 ,  C07C51/093 ,  C07C51/377 ,  C07C67/00 ,  C07C67/40 ,  C07C53/19 ,  C07C69/63 ,  C07C69/653

摘要： The present invention relates to a method for producing an unsaturated acid and/or an unsaturated acid ester, containing a process A of reacting a compound (1) represented by the following formula (1) at a temperature of 0° C. to 350° C. in the presence of a Brønsted acid catalyst and/or a Lewis acid catalyst, to prepare a compound (2) represented by the following formula (2); in which each of R1, R2 and R4 independently represents a hydrogen atom, a deuterium atom or an alkyl group; each of R3 and R5 independently represents a hydrogen atom or a deuterium atom; R6 represents a hydrogen atom, a deuterium atom, or an alkyl group or an aryl group; and X represents a chlorine atom, a fluorine atom, a bromine atom, or an iodine atom.

摘要翻译： 本发明涉及一种不饱和酸和/或不饱和酸酯的制造方法，其含有将下述式（1）表示的化合物（1）在0℃〜350℃的温度下反应的方法A 在布朗斯台德酸催化剂和/或路易斯酸催化剂存在下，制备由下式（2）表示的化合物（2）; 其中R 1，R 2和R 4各自独立地表示氢原子，氘原子或烷基; R 3和R 5各自独立地表示氢原子或氘原子; R6表示氢原子，氘原子或烷基或芳基; X表示氯原子，氟原子，溴原子或碘原子。