公开(公告)号：US20140287240A1

公开(公告)日：2014-09-25

申请号：US14298267

申请日：2014-06-06

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Eisuke MUROTANI ,  Taiki Hoshino ,  Akira Isobe ,  Daisuke Shirakawa ,  Daisuke Jomuta ,  Nobuyuki Otozawa

IPC分类号： C09D7/12 ,  C23C14/12 ,  B05D1/02 ,  B05D1/28 ,  B05D1/18 ,  C07C43/12 ,  B05D1/00

CPC分类号： C09D7/63 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B05D1/28 ,  C07C43/126 ,  C07F7/1804 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D5/1637 ,  C09D171/00 ,  C23C14/12 ,  Y10T428/31504

摘要： To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid, whereby it is possible to form a surface-treated layer which has high initial water/oil repellency and which is excellent in abrasion resistance and fingerprint stain removability, and a substrate having a surface-treated layer and a method for its production.A fluorinated ether compound which has a poly(oxyperfluoroalkylene) chain (αβ) having a C4 oxyperfluoroalkylene unit (α) and an oxyperfluoroalkylene unit (β) other than the unit (α) and which has a hydrolysable silyl group on at least one terminal of the poly(oxyperfluoroalkylene) chain (αβ) via a linking group.

摘要翻译： 为了提供氟化醚化合物，氟化醚组合物和涂布液，由此可以形成具有高的初始拒水拒油性并且耐磨性和指纹污渍除去性优异的表面处理层，以及基材 具有表面处理层及其制造方法。 具有除了单元（α）之外的具有C4全氟亚烷基单元（α）和氧全氟亚烷基单元（＆bgr）的聚（全氟全氟亚烷基）链（α＆bgr））并且在至少一个上具有可水解甲硅烷基的氟化醚化合物 通过连接基团的聚（全氟亚烷基）链（α和bgr）的末端。

公开(公告)号：US09969890B2

公开(公告)日：2018-05-15

申请号：US14821941

申请日：2015-08-10

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Kiyotaka Takao ,  Nobuyuki Otozawa ,  Daisuke Jomuta ,  Kuniko Okano ,  Taiki Hoshino

IPC分类号： C07C261/00 ,  C09D5/16 ,  C09D133/14 ,  C07C69/63 ,  C07C271/22 ,  C07C43/12 ,  C09D4/00 ,  G02B1/14 ,  C08G65/00 ,  C08G65/329 ,  C09D171/00 ,  C08G65/333

CPC分类号： C09D5/16 ,  C07C43/126 ,  C07C69/63 ,  C07C271/22 ,  C08G65/007 ,  C08G65/329 ,  C08G65/33348 ,  C08G2650/48 ,  C09D4/00 ,  C09D133/14 ,  C09D171/00 ,  G02B1/14 ,  Y10T428/3154

摘要： Provided is a fluorinated ether compound capable of imparting excellent antifouling properties such as oil-based ink repellency, fingerprint stain removability, to a hard coating layer; a composition for forming a hard coating layer, and an article having an antifouling hard coating layer formed from the composition. The fluorinated ether compound has either a poly(oxyperfluoroalkylene) chain having a repeated unit that includes a C1-2 oxyperfluoroalkylene group and a C3-6 oxyperfluoroalkylene group, bonded to each other, or a poly(oxyperfluoroalkylene) chain having a repeated unit that contains a C4 oxyperfluoroalkylene group and a different oxyperfluoroalkylene group, bonded to each other, a linking group bonded to a first terminal of the poly(oxyperfluoroalkylene) chain, and at least one (meth)acryloyl group bonded to the linking group.

公开(公告)号：US20140302332A1

公开(公告)日：2014-10-09

申请号：US14311948

申请日：2014-06-23

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Eisuke MUROTANI ,  Taiki Hoshino ,  Akinobu Kunimoto ,  Daisuke Jomuta ,  Nobuyuki Otozawa

IPC分类号： C07F7/18 ,  C23C14/06 ,  B05D1/00 ,  B05D1/30 ,  B05D1/18 ,  B05D1/20 ,  B05D1/28 ,  C09D7/12 ,  B05D1/02

CPC分类号： C07F7/1804 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B05D1/204 ,  B05D1/28 ,  B05D1/30 ,  C03C17/30 ,  C03C17/328 ,  C03C2217/76 ,  C07F7/18 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D7/63 ,  C09D171/00 ,  C09D201/10 ,  C09K3/18 ,  C23C14/06 ,  C23C14/12 ,  Y10T428/31663

摘要： To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid, whereby it is possible to form a surface-treated layer which has high initial water/oil repellency and which is excellent in abrasion resistance and fingerprint stain removability, and a substrate having a surface-treated layer and a method for its production.A fluorinated ether compound which has a poly(oxyperfluoroalkylene) chain ((αβ)n) made of at least two units (αβ) linked to one another, and which has a hydrolysable silyl group on at least one terminal of the chain ((αβ)n) via a linking group, wherein each unit (αβ) is a poly(oxyperfluoroalkylene) group comprising one to three groups (α) made of at least one type of a C1-2 oxyperfluoroalkylene group and one to three groups (β) made of at least one type of a C3-6 oxyperfluoroalkylene group.

摘要翻译： 为了提供氟化醚化合物，氟化醚组合物和涂布液，由此可以形成具有高的初始拒水拒油性并且耐磨性和指纹污渍除去性优异的表面处理层，以及基材 具有表面处理层及其制造方法。 具有由至少两个相互连接的单元（α和bgr）构成的聚（全氟全氟亚烷基）链（（α，bgr））n）的氟化醚化合物，并且在链的至少一个末端具有可水解的甲硅烷基（ （α＆bgr;）n），其中每个单元（α＆bgr）是由至少一种类型的C1-2氧全氟亚烷基和一至三个所组成的一至三个基团（α）的聚（氧全氟亚烷基） 由至少一种C3-6氧全氟亚烷基组成的组（＆bgr）。

公开(公告)号：US20150344703A1

公开(公告)日：2015-12-03

申请号：US14821941

申请日：2015-08-10

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Kiyotaka TAKAO ,  Nobuyuki Otozawa ,  Daisuke Jomuta ,  Kuniko Okano ,  Taiki Hoshino

IPC分类号： C09D5/16 ,  C07C43/12 ,  C07C271/22 ,  C09D133/14 ,  C07C69/63

CPC分类号： C09D5/16 ,  C07C43/126 ,  C07C69/63 ,  C07C271/22 ,  C08G65/007 ,  C08G65/329 ,  C08G65/33348 ,  C08G2650/48 ,  C09D4/00 ,  C09D133/14 ,  C09D171/00 ,  G02B1/14 ,  Y10T428/3154

摘要： To provide a fluorinated ether compound capable of imparting excellent antifouling properties (oil-based ink repellency, fingerprint stain removability) to a hard coating layer, etc., a composition for forming a hard coating layer, containing such a compound, and an article having an antifouling hard coating layer formed from such a composition.A fluorinated ether compound which has either a poly(oxyperfluoroalkylene) chain having a unit repeated that comprises a group constituted by one to three of at least one type of a C1-2 oxyperfluoroalkylene group and a group constituted by one to three of at least one type of a C3-6 oxyperfluoroalkylene group, bonded to each other, or a poly(oxyperfluoroalkylene) chain having a unit repeated that comprises a C4 oxyperfluoroalkylene group and an oxyperfluoroalkylene group other than such a group, bonded to each other, a linking group bonded to a first terminal of the above poly(oxyperfluoroalkylene) chain, and at least one (meth)acryloyl group bonded to the above linking group; a composition for forming a hard coating layer containing such a compound; and an article having such a hard coating layer.

摘要翻译： 为了提供能够赋予硬涂层等优异的防污性（油基拒油性，指纹色斑去除性）的含氟醚化合物，含有这种化合物的硬质涂层形成用组合物和具有 由这种组合物形成的防污硬涂层。 具有重复单元的聚（全氟全氟亚烷基）链的氟化醚化合物，其包含由至少一种类型的C1-2氧全氟亚烷基中的一至三个构成的基团和由至少一个 或相互键合的C3-6氧全氟亚烷基的类型或重复单元的聚（全氟亚烷基）链，其包含除了这些基团之外的C4全氟代亚烷基和氧全氟亚烷基，彼此键合， 到上述聚（全氟亚烷基）链的第一末端，和至少一个与上述连接基团键合的（甲基）丙烯酰基; 用于形成含有这种化合物的硬质涂层的组合物; 以及具有这样的硬涂层的制品。

公开(公告)号：US09637650B2

公开(公告)日：2017-05-02

申请号：US14298267

申请日：2014-06-06

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Eisuke Murotani ,  Taiki Hoshino ,  Akira Isobe ,  Daisuke Shirakawa ,  Daisuke Jomuta ,  Nobuyuki Otozawa

IPC分类号： C09D7/12 ,  C23C14/12 ,  B05D1/02 ,  B05D1/28 ,  B05D1/18 ,  C07C43/12 ,  B05D1/00 ,  C09D171/00 ,  C08G65/336 ,  C07F7/18 ,  C09D5/16 ,  C08G65/00

CPC分类号： C09D7/63 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B05D1/28 ,  C07C43/126 ,  C07F7/1804 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D5/1637 ,  C09D171/00 ,  C23C14/12 ,  Y10T428/31504

摘要： To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid, whereby it is possible to form a surface-treated layer which has high initial water/oil repellency and which is excellent in abrasion resistance and fingerprint stain removability, and a substrate having a surface-treated layer and a method for its production.A fluorinated ether compound which has a poly(oxyperfluoroalkylene) chain (αβ) having a C4 oxyperfluoroalkylene unit (α) and an oxyperfluoroalkylene unit (β) other than the unit (α) and which has a hydrolysable silyl group on at least one terminal of the poly(oxyperfluoroalkylene) chain (αβ) via a linking group.

公开(公告)号：US09598345B2

公开(公告)日：2017-03-21

申请号：US14991393

申请日：2016-01-08

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Tomoyuki Fujita ,  Koichi Murata ,  Naoko Shirota ,  Yusuke Suzuki ,  Daisuke Jomuta

IPC分类号： C07C67/10 ,  C07C67/00 ,  C07C51/093

CPC分类号： C07C67/10 ,  C07C51/093 ,  C07C67/00 ,  Y02P20/582 ,  C07C69/54 ,  C07C57/04

摘要： The present invention relates to a method for producing an unsaturated-acid ester or an unsaturated acid, containing a step of reacting a compound (1) represented by the following formula (1) with a compound represented by the following formula (2) (excluding the compound (1)) in the presence of a Lewis acid catalyst at a temperature of the boiling point of the compound (1) or higher and 350° C. or lower, thereby obtaining products including a compound represented by the following formula (3): (in formula (1) and formula (3), R1, R2 and R4 each independently may be hydrogen atom or an alkyl group, R3 and R5 each independently are hydrogen atom or a deuterium atom, and X is a halogen atom; in formula (2) and formula (3), R6 may be hydrogen atom, an alkyl group or an aryl group, and R7 is hydrogen atom or a deuterium atom).

公开(公告)号：US09540404B2

公开(公告)日：2017-01-10

申请号：US14311948

申请日：2014-06-23

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Eisuke Murotani ,  Taiki Hoshino ,  Akinobu Kunimoto ,  Daisuke Jomuta ,  Nobuyuki Otozawa

IPC分类号： B05D1/02 ,  B05D1/18 ,  B05D1/28 ,  B05D1/30 ,  C03C17/30 ,  C07F7/18 ,  C08G65/00 ,  C08G65/336 ,  C09D201/10 ,  C23C14/12 ,  C09K3/18 ,  B05D1/00 ,  B05D1/20 ,  C09D7/12 ,  C23C14/06 ,  C09D171/00 ,  C03C17/32

CPC分类号： C07F7/1804 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B05D1/204 ,  B05D1/28 ,  B05D1/30 ,  C03C17/30 ,  C03C17/328 ,  C03C2217/76 ,  C07F7/18 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C09D7/63 ,  C09D171/00 ,  C09D201/10 ,  C09K3/18 ,  C23C14/06 ,  C23C14/12 ,  Y10T428/31663

摘要： To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid, whereby it is possible to form a surface-treated layer which has high initial water/oil repellency and which is excellent in abrasion resistance and fingerprint stain removability, and a substrate having a surface-treated layer and a method for its production.A fluorinated ether compound which has a poly(oxyperfluoroalkylene) chain ((αβ)n) made of at least two units (αβ) linked to one another, and which has a hydrolysable silyl group on at least one terminal of the chain ((αβ)n) via a linking group, wherein each unit (αβ) is a poly(oxyperfluoroalkylene) group comprising one to three groups (α) made of at least one type of a C1-2 oxyperfluoroalkylene group and one to three groups (β) made of at least one type of a C3-6 oxyperfluoroalkylene group.

摘要翻译： 具有由至少两个单元（αβ）构成的聚（全氟亚烷基）链（（αβ）n）的氟化醚化合物彼此连接，并且在至少一个末端具有可水解的甲硅烷基（（αβ ）n），其中每个单元（αβ）是由至少一种类型的C1-2氧全氟亚烷基和一至三个基团（β）制成的一至三个基团（α）的聚（全氟亚烷基） 由至少一种类型的C3-6氧全氟亚烷基组成。