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    Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound
    4.
    发明申请
    Processes for producing a fluorosulfonyl group-containing compound and a compound led from the fluorosulfonyl group-containing compound 有权
    用于制备含氟磺酰基化合物和由含氟磺酰基化合物引发的化合物的方法

    公开(公告)号：US20040230018A1

    公开(公告)日：2004-11-18

    申请号：US10830140

    申请日：2004-04-23

    申请人： ASAHI GLASS COMPANY LIMITED

    发明人： Takashi Okazoe ,  Atsushi Watakabe ,  Masahiro Ito ,  Kunio Watanabe ,  Takeshi Eriguchi ,  Kimiaki Kashiwagi ,  Shu-zhong Wang

    IPC分类号： C08F012/20 ,  C07D317/08

    CPC分类号： C08F24/00 ,  C07D317/18 ,  C07D317/24 ,  C07D317/42

    摘要： A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided. A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. 1 wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.

    摘要翻译： 提供具有高聚合反应性的含氟磺酰基的化合物，其制备方法，由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物 。 化合物（3）被氟化以形成化合物（4），然后使化合物（4）进行分解反应以制备化合物（5）。 将化合物（5）的优选化合物（5-1）热分解，得到聚合反应性高的化合物（7-1）。 其中R A是二价有机基团，例如氟代亚烷基基团，R AF是​​具有R A氟化的基团，或与R aA相同的基团，R B至R D各自 各自独立地为氢原子等，R 〜R DF中的每一个为氟原子等，R E为一价有机基团，R EF为 与R E相同的基团，或与R E相同的基团，E为二价连接基团，E F为与E相同的基团，或具有E氟化基团，E F1为 通过E 的断裂形成的基团，X 1〜X 3各自为氢原子等，X 1〜X 3F各自为氟原子等。

    Fluorinated diene compound and fluoropolymer, and methods for their production
    5.
    发明申请
    Fluorinated diene compound and fluoropolymer, and methods for their production 失效
    氟化二烯化合物和含氟聚合物及其制备方法

    公开(公告)号：US20040204615A1

    公开(公告)日：2004-10-14

    申请号：US10834076

    申请日：2004-04-29

    申请人： ASAHI GLASS COMPANY LIMITED

    发明人： Kimiaki Kashiwagi ,  Gen Ogawa ,  Takashi Okazoe ,  Kunio Watanabe ,  Eisuke Murotani ,  Kazuya Oharu

    IPC分类号： C08F216/12 ,  C07C043/12

    CPC分类号： G02B6/02038 ,  C07C43/17 ,  C08F16/32 ,  C08F214/18 ,  G02B1/046 ,  G02B6/02033 ,  C08L29/10

    摘要： A novel fluoropolymer which can be an optical resin material having a low refractive index and excellent heat resistance, and a novel fluorinated diene compound having two unsaturated bonds, capable of presenting such a fluoropolymer, are presented. Further, by virtue of the low refractive index and excellent heat resistance, the polymer presents a high performance optical transmitter and a plastic optical fiber. A fluorinated diene compound represented by CF2nullCFCF(ORf)CF2OCFnullCF2 (wherein Rf is a perfluoroalkyl group such as a trifluoromethyl group), and a fluoropolymer thereof. Further, an optical transmitter made by using such a fluoropolymer, and a plastic optical fiber having a core comprising such a fluoropolymer and a fluorinated low molecular compound contained therein as a refractive index-increasing agent.

    摘要翻译： 本发明提供一种可以是具有低折射率和优异的耐热性的光学树脂材料的新型含氟聚合物，以及具有两个不饱和键的氟化二烯化合物，能够呈现这种含氟聚合物。 此外，由于低折射率和优异的耐热性，聚合物呈现高性能的光发射机和塑料光纤。 由CF 2 = CFCF（OR f）CF 2 OCF = CF 2（其中R f是全氟烷基如三氟甲基）表示的氟化二烯化合物及其含氟聚合物。 此外，通过使用这种含氟聚合物制成的光发送器，以及包含其中包含这种含氟聚合物的核心和其中包含的氟化低分子化合物的塑料光纤作为折射增加剂。