摘要:
REACTING 3,4-EPOXYBUTENE-1 WITH HYDROCHLORIC ACID AND CUPROUS CHLORIDE TO PRODUCE 1,4-DICHLOROBUTENE-2. IN ANOTHER EMBODIMENT THE 3,4-EPOXYBUTENE-1 IS FIRST HYDROLYZED TO A MIXTURE OF THE 2 - BUTENE - 1,4 - DIOL AND ERYTHROL (1-BUTENE-3,4-DIOL). THESE COMPOUNDS CAN BE REACTED WITH THE HYDROCHLORIC ACID AND CUPROUS CHLORIDE TO PRODUCE THE 1,4-DICHLOROBUTENE-2. THE 1,4-DICHLOROBUTENE-2 IS A USEFUL INTERMEDIATE IN THE PRODUCTION OF VARIOUS MONOMERS.
摘要:
Novel compositions of matter comprising polymers of adamantyl epoxides and adamantyl epoxides useful as intermediates in the preparation of said polymers. The polymers are useful in making wax additives, gaskets and rubber-like compositions. A process for the preparation of adamantyl epoxides comprising contacting an alkenyl adamantane with an oxidizing agent selected from the group consisting of organic peracids and their derivatives, inorganic peracids, halogenhydrins and their derivatives, hydrogen peroxide, and organic hydroperoxides.