公开(公告)号：US4731423A

公开(公告)日：1988-03-15

申请号：US896480

申请日：1986-08-13

申请人： Abel Mendoza ,  Chun S. Wang ,  Eric E. Bancroft ,  David B. Fritz

发明人： Abel Mendoza ,  Chun S. Wang ,  Eric E. Bancroft ,  David B. Fritz

IPC分类号： C07D215/16 ,  C07C39/367 ,  C07C39/38 ,  C07C39/42 ,  C07C211/52 ,  C07C235/16 ,  C07C235/88 ,  C07C271/28 ,  C07C271/30 ,  C07D217/02 ,  C07D237/28 ,  C08F8/20 ,  C08G8/28 ,  C08G59/02 ,  C08G59/08 ,  C08G59/30 ,  C08G59/36 ,  C08G64/42 ,  C08G59/06 ,  C07C39/12

CPC分类号： C07C39/42 ,  C07C39/367 ,  C08G59/08 ,  C08G59/30

摘要： Titled materials and their preparation. The materials contain a moiety such as, for example, 4-oxy-3,5-dimethyl-2,6-dibromobenzyl which can impart a high degree of thermal and hydrolytic stability to the materials, for example, epoxy thermosets such as in electronic encapsulations. For example, when used in electronic encapsulation formulations, these materials can provide a substantial increase in electronic device reliability. Their preparation involves an alkylation of an aromatic ring, for example, such as a Friedel-Crafts alkylation with 4-bromomethyl-3,5-dibromo-2,6-dimethylphenol or with 4-hydroxymethyl-3,5-dibromo-2,6-dimethylphenol.

公开(公告)号：US4892925A

公开(公告)日：1990-01-09

申请号：US300460

申请日：1989-01-23

申请人： Chun S. Wang ,  Abel Mendoza ,  David B. Fritz

发明人： Chun S. Wang ,  Abel Mendoza ,  David B. Fritz

IPC分类号： C07D303/22 ,  C07C43/23 ,  C07D303/27 ,  C08G59/06 ,  C08G59/14 ,  C08G59/30 ,  C08G59/40 ,  C08K7/04 ,  C08L63/00

CPC分类号： C07C43/23 ,  C08G59/066 ,  C08G59/30

摘要： 2,6-dibromo-3,5-dialkyl-4-hydroxybenzyl ethers, glycidyl ethers thereof and reaction products with phenolic hydroxyl-containing compounds, and glycidyl ethers of the resulting new phenolic hydroxyl-containing compounds.

公开(公告)号：US5028668A

公开(公告)日：1991-07-02

申请号：US549177

申请日：1990-07-06

申请人： Chun S. Wang ,  Abel Mendoza

发明人： Chun S. Wang ,  Abel Mendoza

IPC分类号： C07D303/24 ,  C08G59/14 ,  C08G59/36 ,  H01B3/40 ,  H01L23/29

CPC分类号： C07D303/24 ,  C08G59/1444 ,  C08G59/145 ,  C08G59/36 ,  H01B3/40 ,  H01L23/293 ,  H01L2924/0002

摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

摘要翻译： 公开了代谢溴化单酚如3,5-二溴-2,4,6-三甲基苯酚和多官能环氧化物如甲酚 - 甲醛环氧酚醛清漆树脂的加合物，用于封装电子部件的制剂中。

公开(公告)号：US4895755A

公开(公告)日：1990-01-23

申请号：US259449

申请日：1988-10-14

申请人： Jody R. Berman ,  Chun S. Wang ,  Louis L. Walker ,  Abel Mendoza

发明人： Jody R. Berman ,  Chun S. Wang ,  Louis L. Walker ,  Abel Mendoza

IPC分类号： C07C37/62 ,  C07D303/24 ,  C08G59/06 ,  C08G59/30 ,  C08G59/32 ,  H05K1/03

CPC分类号： C08G59/30 ,  C07C37/62 ,  C07D303/24 ,  C08G59/066 ,  C08G59/3218 ,  H05K1/0326 ,  Y10T428/31522 ,  Y10T428/31529 ,  Y10T442/2434 ,  Y10T442/2992

摘要： Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.

摘要翻译： 公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子 到一个芳香环。 这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比， 在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。

公开(公告)号：US4975500A

公开(公告)日：1990-12-04

申请号：US440149

申请日：1989-11-22

申请人： Chun S. Wang ,  Abel Mendoza

发明人： Chun S. Wang ,  Abel Mendoza

IPC分类号： C07D303/24 ,  C08G59/14 ,  C08G59/36 ,  H01B3/40 ,  H01L23/29

CPC分类号： H01B3/40 ,  C07D303/24 ,  C08G59/1444 ,  C08G59/145 ,  C08G59/36 ,  H01L23/293 ,  H01L2924/0002

摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

公开(公告)号：US4914185A

公开(公告)日：1990-04-03

申请号：US851996

申请日：1986-04-14

申请人： Chun S. Wang ,  Abel Mendoza

发明人： Chun S. Wang ,  Abel Mendoza

IPC分类号： C07D303/24 ,  C08G59/00 ,  C08G59/04 ,  C08G59/14 ,  C08G59/18 ,  C08G59/20 ,  C08G59/36 ,  C08K5/13 ,  C08L63/00 ,  H01B3/40 ,  H01L23/29 ,  H01L23/31

CPC分类号： C08G59/145 ,  C07D303/24 ,  C08G59/1444 ,  C08G59/36 ,  H01B3/40 ,  H01L23/293 ,  H01L2924/0002

摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

公开(公告)号：US5098963A

公开(公告)日：1992-03-24

申请号：US652845

申请日：1991-02-08

申请人： Chun S. Wang ,  Abel Mendoza

发明人： Chun S. Wang ,  Abel Mendoza

IPC分类号： C07D303/24 ,  C08G59/14 ,  C08G59/36 ,  H01B3/40 ,  H01L23/29

CPC分类号： C08G59/145 ,  C07D303/24 ,  C08G59/1444 ,  C08G59/36 ,  H01B3/40 ,  H01L23/293 ,  H01L2924/0002

摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

摘要翻译： 公开了代谢溴化单酚如3,5-二溴-2,4,6-三甲基苯酚和多官能环氧化物如甲酚 - 甲醛环氧酚醛清漆树脂的加合物，用于封装电子部件的制剂中。

公开(公告)号：US4727119A

公开(公告)日：1988-02-23

申请号：US907706

申请日：1986-09-15

申请人： Jody R. Berman ,  Chun S. Wang ,  Louis L. Walker ,  Abel Mendoza

发明人： Jody R. Berman ,  Chun S. Wang ,  Louis L. Walker ,  Abel Mendoza

IPC分类号： C08G59/14 ,  C07C37/62 ,  C07D303/24 ,  C08G59/06 ,  C08G59/30 ,  C08G59/32 ,  C08L63/00 ,  H05K1/03

CPC分类号： C07D303/24 ,  C07C37/62 ,  C08G59/066 ,  C08G59/30 ,  C08G59/3218 ,  H05K1/0326

摘要： Halogenated aromatic epoxy resins are disclosed wherein the halogen atoms are in the meta position with respect to a glycidyl ether group attached to an aromatic ring.Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.

摘要翻译： 公开了卤化芳族环氧树脂，其中卤素原子相对于连接到芳族环上的缩水甘油醚基团处于间位。 公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子 到一个芳香环。 这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比， 在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。

公开(公告)号：US4778863A

公开(公告)日：1988-10-18

申请号：US85035

申请日：1987-08-13

申请人： Chun S. Wang ,  Zeng-kun Liao

发明人： Chun S. Wang ,  Zeng-kun Liao

IPC分类号： C08G59/00 ,  C07D301/27 ,  C08G59/02 ,  C08G59/04 ,  C08G59/18 ,  C08G59/68 ,  C08G59/06 ,  C08G59/08

CPC分类号： C08G59/02

摘要： Glycidyl derivatives of compounds containing --OH, --NH.sub.2 and/or --COOH groups are prepared by reacting in the presence of a mixture of solvents, at least one of which is a polar aprotic solvent, an excess of an epihalohydrin with a compound containing --OH, --NH.sub.2 and/or --COOH groups while continuously or incrementally adding an alkali metal hydroxide to the mixture and removing water from the reaction by codistillation with epihalohydrin and the solvents.

公开(公告)号：US4499255A

公开(公告)日：1985-02-12

申请号：US523910

申请日：1983-08-16

申请人： Chun S. Wang ,  Ha Q. Pham ,  James L. Bertram

发明人： Chun S. Wang ,  Ha Q. Pham ,  James L. Bertram

IPC分类号： C08G59/06 ,  C08G59/10

CPC分类号： C08G59/10 ,  C08G59/063

摘要： Epoxy resins are prepared by reacting an excess of an epihalohydrin with a phenolic hydroxyl-containing compound in the presence of the incremental addition of a basic catalyst while removing water by codistilling with a solvent and epihalohydrin.

摘要翻译： 环氧树脂通过使过量的表卤代醇与含酚羟基的化合物在增量添加碱性催化剂的存在下反应制备，同时通过用溶剂和表卤代醇进行分馏除去水。