Corrosion inhibitor for heavy brines
    1.
    发明授权
    Corrosion inhibitor for heavy brines 失效
    重盐水腐蚀抑制剂

    公开(公告)号:US4539122A

    公开(公告)日:1985-09-03

    申请号:US581932

    申请日:1984-02-21

    摘要: The present invention provides a method for reducing the corrosive effects of a heavy brine upon a metal by admixing a quantity of a selected corrosion inhibitor with the brine solution. The corrosion inhibitor can comprise at least one member selected from the group consisting of a monovalent or divalent salt of erythorbic acid, a molybdate salt, ferrous gluconate and sodium gluconate. The brine solution can contain potassium, sodium, calcium or zinc halide salts. The corrosion inhibitor can be used in drilling, completion, packer and workover fluids.

    摘要翻译: 本发明提供一种通过将一定数量的选择的腐蚀抑制剂与盐水溶液混合来降低重盐水对金属的腐蚀作用的方法。 腐蚀抑制剂可包括选自异抗坏血酸的单价或二价盐,钼酸盐,葡萄糖酸亚铁和葡糖酸钠中的至少一种。 盐水溶液可以含有卤化钾,钠,钙或锌。 腐蚀抑制剂可用于钻井,完井,封隔器和修井液。

    Method of preventing loss of an oil-base drilling fluid during the
drilling of an oil or gas well into a subterranean formation
    2.
    发明授权
    Method of preventing loss of an oil-base drilling fluid during the drilling of an oil or gas well into a subterranean formation 失效
    在将油井或气井钻入地下地层期间防止油基钻井液损失的方法

    公开(公告)号:US4525285A

    公开(公告)日:1985-06-25

    申请号:US528326

    申请日:1983-08-31

    IPC分类号: C09K8/32 E21B21/00 C09K7/06

    摘要: A method of drilling a well bore into a subterranean formation containing water with monovalent and polyvalent cations and preventing leak-off into the formation of an oil-base drilling fluid used in the drilling. The method is carried out by adding to an oil-base fluid comprising an oil, water, a weighting agent and an emulsifying agent, a powdered seepage loss reducer selected from the group consisting of an amorphous silicate having a molecular ratio of silicon dioxide to alkali metal oxide in the range of from about 1.5:1 to about 3.3:1 wherein the alkali metal is selected from the group consisting of sodium, potassium, and mixtures thereof, an ammonium soap of a fatty acid having from about 12 to about 22 carbon atoms and mixtures thereof to form the drilling fluid and circulating the drilling fluid containing the powdered seepage loss reducer in the well bore. When the circulation of the drilling fluid containing the seepage loss reducer takes place, the compound reacts with the monovalent and polyvalent cations contained in the formation to form a seal in the formation adjacent to the well bore.

    摘要翻译: 一种将含有一价和多价阳离子的含水井的井眼钻入井眼的方法,并防止泄漏到钻井中使用的油基钻井液的形成。 该方法通过向包含油,水,加重剂和乳化剂的油基流体中加入选自二氧化硅与碱的分子量的无定形硅酸盐的粉末状渗漏减少剂 金属氧化物的范围为约1.5:1至约3.3:1,其中所述碱金属选自钠,钾及其混合物,具有约12至约22个碳原子的脂肪酸的铵皂 原子及其混合物,以形成钻井液,并将含有粉状渗漏损失减少剂的钻井液循环到井眼中。 当含有渗流损失减少剂的钻井液的循环发生时,化合物与包含在地层中的单价和多价阳离子反应,在与井眼相邻的地层中形成密封。

    Cationic amide/ester compositions as demulsifiers
    3.
    发明授权
    Cationic amide/ester compositions as demulsifiers 失效
    阳离子酰胺/酯组合物作为破乳剂

    公开(公告)号:US5117058A

    公开(公告)日:1992-05-26

    申请号:US612659

    申请日:1990-11-09

    摘要: Novel cationic amide compositions having the structure ##STR1## where R.sup.1 represents an alkylene group of the formula C.sub.n H.sub.2n, and alkenyl group of the formula C.sub.n H.sub.n, or a phenyl group, or mixtures thereof, where n equals 0 to 10; R.sup.2 represents C.sub.m H.sub.2m, where m equals 1 to 4; R.sup.3 independently represents methyl, ethyl or propyl; and the combination of R.sup.4 and X.sup.- represents the remnant from a quaternizing agent have been discovered and have been found useful as demulsifiers in breaking petroleum emulsions as might be produced during fireflooding petroleum recovery procedures. In one embodiment, the cationic amide/ester compositions are made by reacting (1) a dicarboxylic acid of the formula: ##STR2## where R.sup.1 represents C.sub.n H.sub.2n, where n equals 0 to 10, or an ester or an acid halide thereof; (2) and aminoalkylamine selected from the group consisting of dimethylaminopropylamine, dimethylaminoethylamine, diethylaminopropylamine, diethylaminoethylamine and mixtures thereof; (3) a quaternizing agent is selected from the group consisting of epichlorohydrin, dimethyl sulfate, alkyl halides and benzyl chloride; and (4) from about 0 to about 40 wt. % of at least one oxyalkylated surface active agent having HLB between about 7 and about 16.

    摘要翻译: 其中R1表示式CnH2n的亚烷基,式CnHn的烯基或苯基或其混合物的新型阳离子酰胺组合物,其中n等于0至10; R2表示CmH2m,其中m等于1至4; 乙烯基或丙基; 并且已经发现来自季铵化剂的残余物的R4和X的组合已经被发现,并且已经被发现可用作破坏石油乳液中的破乳剂,如可能在消防石油采收程序期间产生的那样。 在一个实施方案中,阳离子酰胺/酯组合物通过使(1)下式的二羧酸:其中R 1表示C n H 2n,其中n等于0至10,或其酯或其酰卤; (2)和选自二甲基氨基丙胺,二甲基氨基乙胺,二乙基氨基丙胺,二乙基氨基乙胺及其混合物的氨基烷基胺; (3)季铵化剂选自表氯醇,硫酸二甲酯,烷基卤和苄基氯; 和(4)约0至约40wt。 至少一种HLB约为7至约16的烷氧基化表面活性剂的%。

    Well drilling and completion fluid composition
    4.
    发明授权
    Well drilling and completion fluid composition 失效
    钻井和完井液组成

    公开(公告)号:US4536297A

    公开(公告)日:1985-08-20

    申请号:US572103

    申请日:1984-01-19

    IPC分类号: C09K8/14 C09K8/24 C09K7/02

    摘要: An improved well drilling and completion fluid composition which has excellent stability over a broad temperature range, has a low tubular goods corrosion rate, prevents the sloughing of clay-containing materials and is environmentally acceptable. The composition is comprised of water, a viscosity increasing agent, a fluid loss reducer and rheology stabilizer and one or more water-soluble clay-stabilizing organic salts.

    摘要翻译: 在宽温度范围内具有优异的稳定性的改进的钻井和完井液组合物具有低的管状物料腐蚀速率,防止含粘土材料的脱落并且是环境可接受的。 该组合物由水,增粘剂,失水减少剂和流变稳定剂以及一种或多种水溶性粘土稳定的有机盐组成。

    Method for effecting electric well logging with introduction of a fluid
composition to minimize the effect of interfering ions
    5.
    发明授权
    Method for effecting electric well logging with introduction of a fluid composition to minimize the effect of interfering ions 失效
    通过引入流体组合物来实现电测井的方法,以最小化干扰离子的影响

    公开(公告)号:US4647859A

    公开(公告)日:1987-03-03

    申请号:US749916

    申请日:1985-06-27

    摘要: A method of effecting an improved electric log of a subterranean clay-containing formation ion which a chloride-containing fluid is present which comprises introducing a fluid composition comprising a selected potassium salt of a water-soluble organic acid which stabilizes said clay-containing formation and reduces the chloride-induced interference with the electric log into said formation prior to effecting the electric well log.

    摘要翻译: 一种实现含有含氯化物的地层离子的改进的电气记录的方法,其包含含氯化物的流体,其包括将包含稳定所述含粘土的地层的水溶性有机酸的选定的钾盐的流体组合物和 在进行电气井记录之前,将氯离子对电记录的干扰减少到所述地层中。

    Shale and salt stabilizing drilling fluid
    6.
    发明授权
    Shale and salt stabilizing drilling fluid 失效
    页岩和盐稳定钻井液

    公开(公告)号:US4526693A

    公开(公告)日:1985-07-02

    申请号:US495011

    申请日:1983-05-16

    IPC分类号: C09K8/16 C09K7/02 C09K7/04

    CPC分类号: C09K8/16 Y10S507/904

    摘要: The invention relates to a clay based aqueous drilling fluid containing dissolved inorganic salts for use in drilling through either or both shale and salt formations. The fluid is prepared by dissolving designated quantities of ammonium chloride and sodium chloride in the aqueous fluid prior to admixing of the clay and other additives.

    摘要翻译: 本发明涉及含有溶解的无机盐的粘土基含水钻井液,用于通过页岩和盐岩中的任一个或两者钻井。 在混合粘土和其它添加剂之前,通过将指定量的氯化铵和氯化钠溶解在含水流体中来制备流体。

    Well drilling and completion fluid composition
    7.
    发明授权
    Well drilling and completion fluid composition 失效
    钻井和完井液组成

    公开(公告)号:US4440649A

    公开(公告)日:1984-04-03

    申请号:US343620

    申请日:1982-01-28

    IPC分类号: C09K8/14 C09K8/24 C09K7/02

    摘要: An improved well drilling and completion fluid composition which has excellent stability over a broad temperature range, has a low tubular goods corrosion rate, prevents the sloughing of clay-containing materials and is environmentally acceptable. The composition is comprised of water, a viscosity increasing agent, a fluid loss reducer and rheology stabilizer and one or more water-soluble clay-stabilizing organic salts.

    摘要翻译: 在宽温度范围内具有优异的稳定性的改进的钻井和完井液组合物具有低的管状物料腐蚀速率,防止含粘土材料的脱落并且是环境可接受的。 该组合物由水,增粘剂,失水减少剂和流变稳定剂以及一种或多种水溶性粘土稳定的有机盐组成。