Urea cosolvents for organic carbonate process
    2.
    发明授权
    Urea cosolvents for organic carbonate process 失效
    尿素共溶剂用于有机碳酸盐工艺

    公开(公告)号:US5001252A

    公开(公告)日:1991-03-19

    申请号:US132229

    申请日:1987-12-11

    CPC classification number: C07C68/005

    Abstract: An organic carbonate such as dimethyl carbonate is prepared by reacting an alcohol such as methanol with carbon monoxide and oxygen in the presence of a catalyst system containing Cu(OMe)Cl as catalyst and a urea or a mixture of ureas as a cosolvent for the catalyst system.

    Abstract translation: 有机碳酸酯如碳酸二甲酯通过在含有Cu(OMe)Cl作为催化剂的催化剂体系和脲或作为催化剂的共溶剂的脲的混合物存在下,使甲醇等醇与一氧化碳和氧反应来制备, 系统。

    Base-modified zeolite-containing catalysts for the conversion of
synthesis gas to alcohols
    4.
    发明授权
    Base-modified zeolite-containing catalysts for the conversion of synthesis gas to alcohols 失效
    用于将合成气转化为醇的碱改性沸石催化剂

    公开(公告)号:US4822825A

    公开(公告)日:1989-04-18

    申请号:US185575

    申请日:1988-04-25

    CPC classification number: C07C29/156 C07C29/153

    Abstract: A method for preparing a mixture of lower aliphatic alcohols from the reaction of carbon monoxide and hydrogen in the presence of a zeolite-containing heavy metal catalyst under carbon monoxide-hydrogenation conditions in which said catalysts comprises a zeolite support, at least one heavy metal oxide selected from the group of oxides consisting of molybdenum, tungsten, rhenium, optionally, a heavy metal oxide from the group of elements consisting of cobalt, iron and nickel and an alkali or alkaline earth promoter which has been treated with a nitrogen-containing compound, or a thermally stable derivative thereof is provided. A method for preparing zeolite-containing catalysts by treating with volatile metal complexes at high pressure is also provided.

    Abstract translation: 一种一氧化碳氢化条件下,在含有沸石的重金属催化剂存在下,由一氧化碳和氢气反应制备低级脂族醇的混合物的方法,其中所述催化剂包括沸石载体,至少一种重金属氧化物 选自由钼,钨,铼组成的氧化物组,任选地,由钴,铁和镍组成的元素组的重金属氧化物和已经用含氮化合物处理的碱或碱土助催化剂, 或其热稳定衍生物。 还提供了通过用高压挥发性金属络合物处理来制备含沸石催化剂的方法。

    Catalyst treatment process
    6.
    发明授权
    Catalyst treatment process 失效
    催化剂处理工艺

    公开(公告)号:US4886772A

    公开(公告)日:1989-12-12

    申请号:US208709

    申请日:1988-06-20

    CPC classification number: C07C29/156 Y02P20/52

    Abstract: A method for preparing a mixture of lower aliphatic alcohols from the reaction of carbon monoxide and hydrogen in the presence of a sulfide-containing heavy metal catalyst under carbon-monoxide-hydrogenation conditions in which said catalyst comprises at least one sulfided heavy metal element selected from the group consisting of molybdenum, tungsten, rhenium, and an alkali or alkaline earth promoter which has been treated with a nitrogen-containing compound, or a theramlly stable derivative thereof is provided.

    Abstract translation: 在一氧化碳 - 氢化条件下,在含硫化物的重金属催化剂的存在下,从一氧化碳和氢气的反应制备低级脂族醇的混合物的方法,其中所述催化剂包含至少一种选自以下的硫化重金属元素: 提供了已经用含氮化合物处理的钼,钨,铼以及碱土或碱土助催化剂或其热稳定的衍生物。

    Phosphoramide additives for preparation of organic carbonates
    7.
    发明授权
    Phosphoramide additives for preparation of organic carbonates 失效
    用于制备有机碳酸酯的磷酰胺添加剂

    公开(公告)号:US4638076A

    公开(公告)日:1987-01-20

    申请号:US766325

    申请日:1985-08-16

    CPC classification number: C07C68/005

    Abstract: An organic carbonate such as dimethyl carbonate is prepared by reacting an alcohol such as methanol with carbon monoxide oxygen in the presence of a catalyst system containing Cu(OMe)Cl as a catalyst and a phosphoramide as an additive for the catalyst system.

    Abstract translation: 在含有Cu(OMe)Cl作为催化剂的催化剂体系和作为催化剂体系的添加剂的磷酰胺的存在下,使诸如甲醇的醇与一氧化碳氧反应制备有机碳酸酯。

    Catalyst for preparation of dimethyl carbonate
    9.
    发明授权
    Catalyst for preparation of dimethyl carbonate 失效
    用于制备碳酸二甲酯的催化剂

    公开(公告)号:US4879266A

    公开(公告)日:1989-11-07

    申请号:US218766

    申请日:1988-07-14

    CPC classification number: C07C68/005

    Abstract: An organic carbonate such as dimethyl carbonate is prepared by reacting an alcohol such as methanol, oxygen, and carbon monoxide in the presence of a catalyst system containing Cu(OMe)Cl as catalyst and boron trifluoride, calcium chloride, benzyltriethylammonium chloride, etc. as promoters.

    Abstract translation: 在含有Cu(OMe)Cl作为催化剂的催化剂体系和三氟化硼,氯化钙,苄基三乙基氯化铵等的催化剂体系存在下,通过使甲醇,氧气和一氧化碳等醇类反应来制备碳酸二甲酯,作为 发起人。

    Base-modified metal oxide catalysts for the conversion of synthesis gas
to alcohols
    10.
    发明授权
    Base-modified metal oxide catalysts for the conversion of synthesis gas to alcohols 失效
    用于将合成气转化为醇的碱改性金属氧化物催化剂

    公开(公告)号:US4824869A

    公开(公告)日:1989-04-25

    申请号:US158474

    申请日:1988-02-22

    CPC classification number: B01J23/8872 C07C29/156 C07C29/157

    Abstract: A method for preparing a mixture of lower aliphatic alcohols from the reaction of carbon monoxide and hydrogen in the presence of an oxide-containing heavy metal catalyst under carbon monoxide-hydrogenation conditions in which said catalyst comprises an alumina support, at least one heavy metal oxide selected from the group of oxides consisting of molybdenum, tungsten, rhenium, optionally, a heavy metal oxide from the group of elements consisting of cobalt, iron and nickel, and an alkali or alkaline earth promotor which has been treated with a nitrogen-containing compound, or a thermally stable derivative thereof is provided.

    Abstract translation: 一种在一氧化碳 - 氢化条件下,在含氧化物的重金属催化剂存在下由一氧化碳和氢气反应制备低级脂族醇的混合物的方法,其中所述催化剂包含氧化铝载体,至少一种重金属氧化物 选自由钼,钨,铼组成的氧化物组,任选地,由钴,铁和镍组成的元素组中的重金属氧化物,以及已经用含氮化合物处理的碱金属或碱土金属的促进剂 ,或其热稳定衍生物。

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