Process for producing block copolymers
    1.
    发明授权
    Process for producing block copolymers 失效
    制备嵌段共聚物的方法

    公开(公告)号:US4057600A

    公开(公告)日:1977-11-08

    申请号:US747937

    申请日:1976-12-06

    CPC分类号: C08F295/00

    摘要: Block copolymers are produced by (i) polymerizing ethylene or propylene, or copolymerizing the same with another .alpha.-olefin of 2 to 7 carbon atoms in the presence of a Ziegler-type catalyst, and (ii) copolymerizing the resulting polymer or copolymer with a radical-polymerizable vinyl compound (e.g., methyl methacrylate) in the presence of an organic sulfoxide.

    摘要翻译: 嵌段共聚物是通过在齐格勒型催化剂存在下,通过(ⅰ)聚合乙烯或丙烯或将其与另外的2-7个碳原子的α-烯烃进行聚合制备的,和(ⅱ)将所得聚合物或共聚物与 可自由基聚合的乙烯基化合物(如甲基丙烯酸甲酯)在有机亚砜存在下。

    Organic electroluminescence device
    2.
    发明授权
    Organic electroluminescence device 失效
    有机电致发光器件

    公开(公告)号:US06489046B1

    公开(公告)日:2002-12-03

    申请号:US09675200

    申请日:2000-09-29

    IPC分类号: H05B3312

    摘要: An organic electroluminescence device which exhibits an excellent purity of color and a high efficiency of light emission, has a long life and emits reddish light and a novel compound having these characteristics. The organic electroluminescence device comprises an organic layer disposed between at least one pair of electrodes, wherein the organic layer comprises a compound represented by general formula [1]: wherein R1 to R14 each independently represent hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an arylalkyl group having 6 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylamino group having 6 to 30 carbon atoms, an alkylamino group having 2 to 20 carbon atoms or an arylalkylamino group having 6 to 30 carbon atoms, the groups being substituted or unsubstituted; and at least one pair of R among R1 to R14 which are adjacent to each other do not represent hydrogen atom but represent groups which form a cyclic structure in combination.

    摘要翻译: 具有优异的颜色纯度和高发光效率的有机电致发光元件具有使用寿命长,发出红色光的特性,具有这些特性的新型化合物。 有机电致发光器件包括设置在至少一对电极之间的有机层,其中有机层包含由通式[1]表示的化合物:其中R 1至R 14各自独立地表示氢原子,具有1至10个碳原子的烷基 原子,碳原子数6〜20的芳氧基,碳原子数6〜20的芳烷基,碳原子数6〜30的芳基,碳原子数6〜30的芳基氨基,碳原子数2〜20的烷基氨基 原子或碳原子数为6〜30的芳烷基氨基,取代或未取代的基团; 并且彼此相邻的R 1〜R 14中的至少一对R不表示氢原子,而是表示组合形成环状结构的基团。

    Process for the preparation of polycarbonate with weatherproof property
    6.
    发明授权
    Process for the preparation of polycarbonate with weatherproof property 失效
    具有耐候性的聚碳酸酯的制备方法

    公开(公告)号:US4153780A

    公开(公告)日:1979-05-08

    申请号:US436333

    申请日:1974-01-14

    CPC分类号: C08G64/14 C08G64/24

    摘要: A process is provided for preparing a polycarbonate composition with excellent weatherproof properties. The process comprises adding an ultraviolet absorbing compound having a hydroxy group which contributes at least partially to the molecular weight modifier to an oligomeric polycarbonate which is obtained by the reaction of a dioxy compound with phosgene, and then condensing said oligomeric polycarbonate to polymerize the same. The invention also concerns a process for preparing a polycarbonate with excellent weatherproof properties which process comprises introducing a dioxy compound in alkaline solution and an organic solvent for the polycarbonate into a tubular reactor continuously to form a turbulent flow, feeding phosgene concurrently to the reactor with cooling outside of the reactor to produce an oligomeric polycarbonate as the solution of organic solvent, adding an aqueous alkaline solution of dioxy compound, molecular weight modifier, which is contained at least in part ultraviolet absorbing compound having an hydroxy group, and catalyst selected from the group consisting of tertiary amine and quaternary ammonium salt and, if desired, antioxidant to said oligomeric polycarbonate solution and condensing said oligomeric polycarbonate to polymerize the same.

    摘要翻译: 提供了制备具有优异耐候性的聚碳酸酯组合物的方法。 该方法包括将具有至少部分贡献于分子量调节剂的羟基的紫外线吸收化合物加入通过二氧化合物与光气反应获得的低聚聚碳酸酯,然后使所述低聚物聚碳酸酯聚合。 本发明还涉及一种制备具有优良耐候性的聚碳酸酯的方法,该方法包括将二氧化合物在碱性溶液中引入,并将聚碳酸酯的有机溶剂连续引入管状反应器中以形成湍流,同时将光气同时送入反应器 在反应器外部产生低聚聚碳酸酯作为有机溶剂的溶液,加入至少部分含有羟基的紫外线吸收化合物的二氧基化合物的分子量调节剂的碱性水溶液和选自以下的催化剂: 由叔胺和季铵盐组成,如果需要,将抗氧化剂包含在所述低聚聚碳酸酯溶液中,并冷凝所述低聚物聚碳酸酯以使其聚合。