公开(公告)号：US20050196670A1

公开(公告)日：2005-09-08

申请号：US11049432

申请日：2005-02-01

申请人： Akira Yamaguchi ,  Kaoru Nakajima ,  Yusuke Fujishige ,  Yuzuru Fukushima ,  Masayuki Nagamine

发明人： Akira Yamaguchi ,  Kaoru Nakajima ,  Yusuke Fujishige ,  Yuzuru Fukushima ,  Masayuki Nagamine

IPC分类号： H01M10/05 ,  H01M4/134 ,  H01M4/38 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/40 ,  H01M4/58

CPC分类号： H01M10/0568 ,  H01M4/134 ,  H01M4/386 ,  H01M4/387 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0085

摘要： An electrolyte solution and a battery which are capable of improving cycle characteristics are provided. An anode includes a simple substance, an alloy or a compound of a metal element or a metalloid element capable of forming an alloy with lithium as an anode active material. A separator is impregnated with an electrolyte solution formed through dissolving an electrolyte salt in a solvent. The electrolyte salt includes a first electrolyte salt including LiB(C2O4)2 and a second electrolyte salt including at least one kind selected from the group consisting of LiPF6, LiBF4, LiN(CF3SO2)2, LiN(C2F5SO2)2, LiClO4, LiAsF6 and LiC(CF3SO2)3. In the solvent, 4-fluoroethylene carbonate is included. A coating is formed on the anode by the first electrolyte salt, and high ionic conductivity can be obtained by the second electrolyte salt. Further an oxidation-decomposition reaction of the electrolyte solution which occurs in a cathode can be prevented by 4-fluoroethylene carbonate.

摘要翻译： 提供能够改善循环特性的电解液和电池。 阳极包括能够形成与锂作为阳极活性材料的合金的金属元素或准金属元素的单质，合金或化合物。 用通过将电解质盐溶解在溶剂中形成的电解质溶液浸渍隔板。 所述电解质盐包括第一电解质盐，其包含LiB（C 2 O 4 O）2 N 2，和包含选自以下的至少一种的第二电解质盐： 由LiPF 6，LiBF 4，LiN（CF 3 SO 2）2组成的组， LiN（C 2 H 5 SO 2）2，LiClO 4， 3，LiAsF 6和LiC（CF 3 SO 2）3。 在溶剂中，包括4-氟乙烯碳酸酯。 通过第一电解质盐在阳极上形成涂层，并且可以通过第二电解质盐获得高离子电导率。 此外，通过4-氟乙烯碳酸酯可以防止在阴极中发生的电解质溶液的氧化分解反应。

公开(公告)号：US09219257B2

公开(公告)日：2015-12-22

申请号：US10758764

申请日：2004-01-16

申请人： Akira Yamaguchi ,  Yusuke Fujishige

发明人： Akira Yamaguchi ,  Yusuke Fujishige

IPC分类号： H01M10/52 ,  H01M2/02 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0565 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/60 ,  H01M4/02

CPC分类号： H01M10/52 ,  H01M2/0275 ,  H01M2/0287 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/60 ,  H01M4/623 ,  H01M4/625 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122

摘要： Disclosed is a non-aqueous electrolyte battery for suppressing the swell of a film-shaped exterior material. A gas adsorbing carbon material added to an anode mixture layer 9 of an anode 4 and/or to a cathode mixture layer 13 of a cathode 5 adsorbs a gas generated in the battery to suppress the gas storage in the battery, so that it is possible to suppress the swell of a film-shaped exterior material 3 caused by the storage of the gas generated within the battery.

摘要翻译： 公开了一种用于抑制膜状外部材料的膨胀的非水电解质电池。 添加到阴极5的阳极混合物层9和/或阴极混合物层13的阳极混合物层9中的气体吸附碳材料吸收电池中产生的气体，以抑制电池中的气体储存，从而可能 以抑制由电池内产生的气体的储存引起的膜状外部材料3的膨胀。

公开(公告)号：US07754389B2

公开(公告)日：2010-07-13

申请号：US11049432

申请日：2005-02-01

申请人： Akira Yamaguchi ,  Kaoru Nakajima ,  Yusuke Fujishige ,  Yuzuru Fukushima ,  Masayuki Nagamine

发明人： Akira Yamaguchi ,  Kaoru Nakajima ,  Yusuke Fujishige ,  Yuzuru Fukushima ,  Masayuki Nagamine

IPC分类号： H01M6/16 ,  H01M4/00

CPC分类号： H01M10/0568 ,  H01M4/134 ,  H01M4/386 ,  H01M4/387 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0085

摘要： An electrolyte solution and a battery which are capable of improving cycle characteristics are provided. An anode includes a simple substance, an alloy or a compound of a metal element or a metalloid element capable of forming an alloy with lithium as an anode active material. A separator is impregnated with an electrolyte solution formed through dissolving an electrolyte salt in a solvent. The electrolyte salt includes a first electrolyte salt including LiB(C2O4)2 and a second electrolyte salt including at least one kind selected from the group consisting of LiPF6, LiBF4, LiN(CF3SO2)2, LiN(C2F5SO2)2, LiClO4, LiAsF6 and LiC(CF3SO2)3. In the solvent, 4-fluoroethylene carbonate is included. A coating is formed on the anode by the first electrolyte salt, and high ionic conductivity can be obtained by the second electrolyte salt. Further an oxidation-decomposition reaction of the electrolyte solution which occurs in a cathode can be prevented by 4-fluoroethylene carbonate.

摘要翻译： 提供能够改善循环特性的电解液和电池。 阳极包括能够形成与锂作为阳极活性材料的合金的金属元素或准金属元素的单质，合金或化合物。 用通过将电解质盐溶解在溶剂中形成的电解质溶液浸渍隔板。 电解质盐包括包含LiB（C 2 O 4）2的第一电解质盐和包括选自LiPF 6，LiBF 4，LiN（CF 3 SO 2）2，LiN（C 2 F 5 SO 2）2，LiClO 4，LiAsF 6和 LiC（CF3SO2）3。 在溶剂中，包括4-氟乙烯碳酸酯。 通过第一电解质盐在阳极上形成涂层，并且可以通过第二电解质盐获得高离子电导率。 此外，通过4-氟乙烯碳酸酯可以防止在阴极中发生的电解质溶液的氧化分解反应。

公开(公告)号：US07749659B2

公开(公告)日：2010-07-06

申请号：US10474941

申请日：2003-02-18

申请人： Mashio Shibuya ,  Kenichi Kawase ,  Fumiko Hara ,  Yusuke Fujishige

发明人： Mashio Shibuya ,  Kenichi Kawase ,  Fumiko Hara ,  Yusuke Fujishige

IPC分类号： H01M4/58 ,  H01M4/02 ,  H01M10/40

CPC分类号： H01M4/587 ,  H01M2/0212 ,  H01M2/027 ,  H01M2/0275 ,  H01M2/0287 ,  H01M2/06 ,  H01M4/133 ,  H01M4/364 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2006/106 ,  H01M2300/0085

摘要： The present invention uses a mixture of spherical carbonaceous materials having different average particle sizes as an anode active material in an anode composite mixture layer of an anode. The spherical carbonaceous material of large particle size decreases the reaction with non-aqueous electrolyte solution to suppress the decrease in battery capacity, form clearances having suitable sizes in the anode composite mixture layer, and retain the non-aqueous electrolyte solution. The clearances in the anode composite mixture layer are efficiently filled with the carbonaceous material of small particle size while spaces capable of suitably retaining the non-aqueous electrolyte solution are left unfilled. Thus, the volume density of the anode composite mixture layer is improved and the battery capacity is increased. Accordingly, energy density can be increased without deteriorating battery characteristics.

摘要翻译： 本发明在阳极的阳极复合混合物层中使用具有不同平均粒径的球形碳质材料作为负极活性物质的混合物。 大粒径的球形碳质材料与非水电解质溶液反应减少，以抑制电池容量的降低，在阳极复合材料层中形成具有合适尺寸的间隙，并保持非水电解质溶液。 阳极复合混合物层中的间隙有效地填充小粒径的碳质材料，同时保持非水电解质溶液的空间不被填充。 因此，阳极复合混合物层的体积密度提高，电池容量增加。 因此，可以提高能量密度而不劣化电池特性。

公开(公告)号：US20050014069A1

公开(公告)日：2005-01-20

申请号：US10791401

申请日：2004-03-02

申请人： Yuzuru Fukushima ,  Yusuke Fujishige ,  Fumiko Kimura ,  Takuya Endo

发明人： Yuzuru Fukushima ,  Yusuke Fujishige ,  Fumiko Kimura ,  Takuya Endo

IPC分类号： H01M10/05 ,  H01M2/16 ,  H01M4/40 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/40

CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0085

摘要： The invention provides an electrolyte whose battery capacity, cycle characteristics, load characteristics, and low temperature characteristics are all excellent, and a battery using it. A cathode and an anode are layered and wound with a separator and electrolyte layer in between. The electrolyte layer contains a high molecular weight compound and an electrolytic solution containing at least one from the group consisting of vinylethylene carbonate and its derivatives in the range of 0.05 wt % to 5 wt % in total. Therefore, chemical stability of the electrolyte layer is improved. It is preferable that the electrolytic solution further contains ethylene carbonate and propylene carbonate by a mass ratio of ethylene carbonate:propylene carbonate=15-75:85-25.

摘要翻译： 本发明提供电池容量，循环特性，负载特性和低温特性均优异的电解质，以及使用它的电池。 阴极和阳极层叠并缠绕有隔膜和电解质层。 电解质层含有高分子量化合物和含有至少一种由碳酸乙烯基碳酸亚乙酯及其衍生物组成的组的电解质，其总量为0.05重量％〜5重量％。 因此，电解质层的化学稳定性提高。 优选电解液还含有碳酸亚乙酯和碳酸亚丙酯，碳酸亚乙酯：碳酸亚丙酯= 15-75:85-25的质量比。

公开(公告)号：US07632606B2

公开(公告)日：2009-12-15

申请号：US10791401

申请日：2004-03-02

申请人： Yuzuru Fukushima ,  Yusuke Fujishige ,  Fumiko Kimura ,  Takuya Endo

发明人： Yuzuru Fukushima ,  Yusuke Fujishige ,  Fumiko Kimura ,  Takuya Endo

IPC分类号： H01M6/14

CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525 ,  H01M10/0565 ,  H01M2300/0082 ,  H01M2300/0085

摘要： An electrolyte whose battery capacity, cycle characteristics, load characteristics, and low temperature characteristics are all excellent, and a battery using it. A cathode and an anode are layered and wound with a separator and electrolyte layer in between. The electrolyte layer contains an electrolytic solution containing at least one from the group consisting of vinylethylene carbonate and its derivatives in the range of 0.05 wt % to 5 wt % in total and a polymer. Therefore, chemical stability of the electrolyte layer is improved. It is preferable that the electrolytic solution further contains ethylene carbonate and propylene carbonate with a mass ratio of ethylene carbonate to propylene carbonate ranging from about 15/85 to about 75/25.

摘要翻译： 其电池容量，循环特性，负载特性和低温特性均优异的电解液以及使用它的电池。 阴极和阳极层叠并缠绕有隔膜和电解质层。 电解质层含有含有碳酸乙烯亚乙酯及其衍生物中的至少一种的电解溶液，其总量为0.05重量％〜5重量％，聚合物为一种。 因此，电解质层的化学稳定性提高。 优选电解液还含有碳酸亚乙酯和碳酸亚丙酯，其碳酸亚乙酯与碳酸亚丙酯的质量比为约15/85至约75/25。