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    Nonaqueous electrolyte battery
    1.
    发明授权
    Nonaqueous electrolyte battery 有权
    非水电解液电池

    公开(公告)号：US07749659B2

    公开(公告)日：2010-07-06

    申请号：US10474941

    申请日：2003-02-18

    申请人： Mashio Shibuya ,  Kenichi Kawase ,  Fumiko Hara ,  Yusuke Fujishige

    发明人： Mashio Shibuya ,  Kenichi Kawase ,  Fumiko Hara ,  Yusuke Fujishige

    IPC分类号： H01M4/58 ,  H01M4/02 ,  H01M10/40

    CPC分类号： H01M4/587 ,  H01M2/0212 ,  H01M2/027 ,  H01M2/0275 ,  H01M2/0287 ,  H01M2/06 ,  H01M4/133 ,  H01M4/364 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2006/106 ,  H01M2300/0085

    摘要： The present invention uses a mixture of spherical carbonaceous materials having different average particle sizes as an anode active material in an anode composite mixture layer of an anode. The spherical carbonaceous material of large particle size decreases the reaction with non-aqueous electrolyte solution to suppress the decrease in battery capacity, form clearances having suitable sizes in the anode composite mixture layer, and retain the non-aqueous electrolyte solution. The clearances in the anode composite mixture layer are efficiently filled with the carbonaceous material of small particle size while spaces capable of suitably retaining the non-aqueous electrolyte solution are left unfilled. Thus, the volume density of the anode composite mixture layer is improved and the battery capacity is increased. Accordingly, energy density can be increased without deteriorating battery characteristics.

    摘要翻译： 本发明在阳极的阳极复合混合物层中使用具有不同平均粒径的球形碳质材料作为负极活性物质的混合物。 大粒径的球形碳质材料与非水电解质溶液反应减少，以抑制电池容量的降低，在阳极复合材料层中形成具有合适尺寸的间隙，并保持非水电解质溶液。 阳极复合混合物层中的间隙有效地填充小粒径的碳质材料，同时保持非水电解质溶液的空间不被填充。 因此，阳极复合混合物层的体积密度提高，电池容量增加。 因此，可以提高能量密度而不劣化电池特性。

    Negative electrode comprising vapor grown carbon fiber and polymer materials and nonaqueous electrolyte secondary battery
    3.
    发明授权
    Negative electrode comprising vapor grown carbon fiber and polymer materials and nonaqueous electrolyte secondary battery 有权
    包含气相生长碳纤维和聚合物材料和非水电解质二次电池的负电极

    公开(公告)号：US08603673B2

    公开(公告)日：2013-12-10

    申请号：US12753237

    申请日：2010-04-02

    申请人： Mashio Shibuya

    发明人： Mashio Shibuya

    IPC分类号： H01M4/13 ,  H01M4/62

    CPC分类号： H01M10/0525 ,  H01M4/133 ,  H01M4/621 ,  H01M4/622 ,  H01M4/625 ,  H01M10/0565

    摘要： A nonaqueous electrolyte secondary battery includes a positive electrode; a negative electrode; and a nonaqueous electrolyte, wherein the negative electrode has a negative electrode mixture layer including a negative electrode active material; a polymer containing vinylidene fluoride as a repeating unit; a polymer containing acrylonitrile as a repeating unit; and a vapor-grown carbon fiber; and the nonaqueous electrolyte contains a fluorocarbon based polymer compound.

    摘要翻译： 非水电解质二次电池包括正极; 负极; 和非水电解质，其中所述负极具有包含负极活性物质的负极合剂层; 含有偏二氟乙烯作为重复单元的聚合物; 含有丙烯腈作为重复单元的聚合物; 和气相生长碳纤维; 非水电解质含有碳氟化合物系高分子化合物。

    NEGATIVE ELECTRODE, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY USING THE SAME
    4.
    发明申请
    NEGATIVE ELECTRODE, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY USING THE SAME 有权
    负极和非水电解质二次电池

    公开(公告)号：US20080057401A1

    公开(公告)日：2008-03-06

    申请号：US11844634

    申请日：2007-08-24

    申请人： Tamami Mori ,  Mashio Shibuya

    发明人： Tamami Mori ,  Mashio Shibuya

    IPC分类号： H01M4/38 ,  H01M10/40

    CPC分类号： H01M4/133 ,  H01M4/366 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0569

    摘要： A negative electrode for a non-aqueous electrolyte secondary battery is provided. The negative electrode includes: an electro-conductive base; a first layer provided on the electro-conductive base; and a second layer provided on the first layer. The first layer includes at least a graphitic material as a negative active material. The second layer includes at least a non-graphitizable carbonaceous material as a negative active material.

    摘要翻译： 提供了一种非水电解质二次电池用负极。 负极包括：导电性基体; 设置在所述导电性基材上的第一层; 以及设置在第一层上的第二层。 第一层至少包含作为负极活性物质的石墨材料。 第二层包括至少一种不可石墨化的含碳材料作为负极活性物质。

    SECONDARY BATTERY
    6.
    发明申请
    SECONDARY BATTERY 审中-公开
    二次电池

    公开(公告)号：US20090111012A1

    公开(公告)日：2009-04-30

    申请号：US12243630

    申请日：2008-10-01

    申请人： Mashio Shibuya ,  Masaki Machida

    发明人： Mashio Shibuya ,  Masaki Machida

    IPC分类号： H01M2/02

    CPC分类号： H01M10/0569 ,  H01M4/131 ,  H01M4/133 ,  H01M4/137 ,  H01M4/405 ,  H01M4/483 ,  H01M10/0565 ,  H01M10/0568

    摘要： A secondary battery incoludes a positive electrode, a negative electrode including an anode active material layer formed on at least one side of a negative electrode current collector, an electrolyte, and a laminate-film casing member containing therein the positive electrode, the negative electrode, and the electrolyte. The electrolyte contains a non-aqueous solvent which includes a cyclic carbonic ester in an amount of 80 to 100%, based on a total weight of the non-aqueous solvent. The also contains an electrolyte salt in a concentration of 0.8 to 1.8 mol/kg. The anode active material layer contains a polymer which includes repeating units derived from vinylidene fluoride. A peel strength between the anode active material layer and negative electrode current collector is 4 mN/mm or more as measured after immersing the anode active material layer into a solvent.

    摘要翻译： 二次电池包括正电极，负极包括在负极集电体的至少一个侧面上形成的负极活性物质层，电解质和含有正极，负极等的层叠膜壳体构件， 和电解质。 该电解质含有非水溶剂，其包含基于非水溶剂的总重量为80-100％的环状碳酸酯。 还含有浓度为0.8〜1.8mol / kg的电解质盐。 负极活性物质层含有包含衍生自偏二氟乙烯的重复单元的聚合物。 阳极活性物质层和负极集电体之间的剥离强度在将阳极活性物质层浸渍在溶剂中后测定为4mN / mm以上。

    Gel electrolyte and gel electrolyte cell
    7.
    发明授权
    Gel electrolyte and gel electrolyte cell 有权
    凝胶电解质和凝胶电解质电池

    公开(公告)号：US06509123B1

    公开(公告)日：2003-01-21

    申请号：US09672881

    申请日：2000-09-28

    申请人： Mashio Shibuya ,  Tsuyonobu Hatazawa ,  Tomitaro Hara ,  Goro Shibamoto ,  Shuji Goto

    发明人： Mashio Shibuya ,  Tsuyonobu Hatazawa ,  Tomitaro Hara ,  Goro Shibamoto ,  Shuji Goto

    IPC分类号： H01M618

    CPC分类号： H01M10/0565 ,  H01M6/164 ,  H01M6/168 ,  H01M6/181 ,  H01M10/052 ,  H01M2300/0085

    摘要： The present invention provides a gel electrolyte cell including a non-aqueous electrolytic solution containing lithium-containing electrolyte salt solved in a non-aqueous solvent and made into a gel state by a matrix polymer, and the gel electrolyte contains vinylene carbonate or derivative thereof in the amount not less than 0.05 wt % and not greater than 5 wt %. This gel electrolyte exhibits an excellent chemical stability with the negative electrode, strength, and liquid-retention characteristic. This gel electrolyte enables to obtain a gel electrolyte cell satisfying the cell capacity, cycle characteristic, load characteristic, and low-temperature characteristic.

    摘要翻译： 本发明提供一种凝胶电解质电池，其包含溶解在非水溶剂中的含锂电解质盐的非水电解液，并由基质聚合物形成凝胶态，凝胶电解质含有碳酸亚乙烯酯或其衍生物 该量不小于0.05wt％且不大于5wt％。 该凝胶电解质具有优异的化学稳定性与负极，强度和保液性。 该凝胶电解质能够得到满足电池容量，循环特性，负载特性和低温特性的凝胶电解质电池。

    Battery
    8.
    发明授权
    Battery 有权
    电池

    公开(公告)号：US08133610B2

    公开(公告)日：2012-03-13

    申请号：US11865612

    申请日：2007-10-01

    申请人： Mashio Shibuya

    发明人： Mashio Shibuya

    IPC分类号： H01M6/04 ,  H01M4/02 ,  H01M4/60 ,  H01M4/62

    CPC分类号： H01M10/0525 ,  H01M4/621 ,  H01M4/623 ,  H01M10/0565 ,  H01M10/0587

    摘要： A battery capable of obtaining the superior battery performance is provided. An electrolyte is a gel electrolyte containing an electrolytic solution and a polymer compound. The polymer compound contains a ternary system copolymer containing vinylidene fluoride, hexafluoropropylene, and monomethylmaleic acid ester as a component. The copolymerization amounts of hexafluoropropylene and monomethylmaleic acid ester in the ternary system copolymer are respectively in the range from 4 wt % to 7.5 wt %, and in the range from 0.3 wt % to 2 wt %. Further, the weight average molecular weight of the ternary system copolymer is in the range from 0.6 million to 1.5 million. The liquid retaining characteristics of the electrolyte are improved. Therefore, the contact characteristics of the electrolyte to a cathode, an anode, and a separator are improved.

    摘要翻译： 提供能够获得优异的电池性能的电池。 电解质是含有电解液和高分子化合物的凝胶电解质。 高分子化合物含有含有偏二氟乙烯，六氟丙烯和单甲基马来酸酯作为组分的三元体系共聚物。 三元系共聚物中的六氟丙烯和单甲基马来酸酯的共聚量分别在4重量％〜7.5重量％的范围内，在0.3重量％〜2重量％的范围内。 此外，三元体系共聚物的重均分子量在60万至150万的范围内。 改善了电解液的液体保持特性。 因此，电解质与阴极，阳极和隔膜的接触特性得到改善。

    Nonaqueous electrolyte and nonaqueous electrolyte battery
    9.
    发明授权
    Nonaqueous electrolyte and nonaqueous electrolyte battery 有权
    非水电解液和非水电解质电池

    公开(公告)号：US06984471B2

    公开(公告)日：2006-01-10

    申请号：US10194722

    申请日：2002-07-12

    申请人： Yusuke Suzuki ,  Mashio Shibuya

    发明人： Yusuke Suzuki ,  Mashio Shibuya

    IPC分类号： H01M6/16

    CPC分类号： H01M10/0525 ,  H01M6/10 ,  H01M6/164 ,  H01M10/0565 ,  H01M10/0569 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/0085

    摘要： A nonaqueous electrolyte has electrolyte salt dissolved in a nonaqueous solvent, wherein the ratio of the nonaqueous solvent having a ring structure is 50 wt % or more in all nonaqueous electrolyte solution components and the nonaqueous solvent includes at least one or more kinds of halogenated solvents expressed by a below-described general formula (1). (Here, at least one of R1 and R2 designates an alkyl group having the number of carbons of 4 or larger and at least one of them is a halogenated alkyl group). Thus, the decomposition of the halogenated solvent is suppressed.

    摘要翻译： 非水电解液具有溶解在非水溶剂中的电解质盐，其中，在所有非水电解液成分中，具有环结构的非水溶剂的比例为50重量％以上，非水溶剂包含至少一种以上表示的卤化溶剂 通过下述通式（1）。 （这里，R 1和R 2中的至少一个表示碳原子数为4以上的烷基，其中至少一个为卤代烷基 ）。 因此，可以抑制卤化溶剂的分解。

    Solid electrolyte cell
    10.
    发明授权
    Solid electrolyte cell 失效
    固体电解质电池

    公开(公告)号：US06753113B2

    公开(公告)日：2004-06-22

    申请号：US09803561

    申请日：2001-03-09

    申请人： Tomitaro Hara ,  Mashio Shibuya ,  Yusuke Suzuki

    发明人： Tomitaro Hara ,  Mashio Shibuya ,  Yusuke Suzuki

    IPC分类号： H01M618

    CPC分类号： H01M10/4235 ,  H01M4/13 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565

    摘要： A solid electrolyte cell in which oxidative decomposition of electrolyte components is suppressed to maintain the superior cell performance. The solid electrolyte includes a negative electrode 9 having a negative electrode current collector 7 and a negative electrode active material 8, a positive electrode 12 having a positive electrode current collector 10 and a positive electrode active material 11 and a solid electrolyte 13 arranged between the negative electrode 9 and the positive electrode 12 and which is comprised of an electrolyte salt dispersed in a matrix polymer. A diene compound is contained in at least one of the positive electrode 12 and the solid electrolyte 13.

    摘要翻译： 其中抑制了电解质成分的氧化分解以维持优异的电池性能的固体电解质电池。 固体电解质包括具有负极集电体7和负极活性物质8的负极9，具有正极集电体10的正极12和正极活性物质11以及负极活性物质13之间的固体电解质13 电极9和正电极12，其由分散在基质聚合物中的电解质盐组成。 二烯化合物包含在正极12和固体电解质13中的至少一个中。