Novel enol esters
    2.
    发明授权
    Novel enol esters 失效
    新型烯醇酯

    公开(公告)号:US4048201A

    公开(公告)日:1977-09-13

    申请号:US723536

    申请日:1976-09-15

    摘要: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma and perfume aroma augmenting, modifying, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product tobacco, perfume and perfumed article aroma imparting materials of one or more alkyl side chain methyl substituted or unsubstituted 2,2,6-trimethyl-1-cyclohexen-1-vinyl alkanoates (hereinafter referred to as "enol esters") having the generic structure: ##STR1## (which structure is intended to cover both the "cis" and the "trans" isomers thereof) wherein R.sub.1 is C.sub.1 -C.sub.11 alkyl and R.sub.4 is hydrogen or methyl.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用香料,香料,烟草香料和芳香和香料增香,改性,增强和赋予组合物以及作为食品,口香糖,牙膏,药用产品烟草的方法和组合物, 具有一般结构的一种或多种烷基侧链甲基取代或未取代的2,2,6-三甲基-1-环己烯-1-乙烯基链烷酸酯(以下称为“烯醇酯”)的香料和香料制品香气赋予材料: IMAGE>(其结构旨在涵盖“顺式”和“反式”异构体),其中R 1是C 1 -C 11烷基,R 4是氢或甲基。

    Uses in tobacco and as a tobacco flavor additive of enol esters
    6.
    发明授权
    Uses in tobacco and as a tobacco flavor additive of enol esters 失效
    用于烟草和作为烯醇酯的烟草香料添加剂

    公开(公告)号:US4086927A

    公开(公告)日:1978-05-02

    申请号:US723537

    申请日:1976-09-15

    IPC分类号: A24B15/34 C11B9/00 A24B3/12

    CPC分类号: C11B9/0034 A24B15/34 C11B9/00

    摘要: Processes and compositions are described for the use in tobacco flavor and aroma augmenting and enhancing compositions and as tobacco aroma and flavor augmenting, imparting and enhancing materials of one or more alkyl side chain methyl unsubstituted 2,2,6-trimethyl-1-cyclohexen-1-vinyl alkanoates (hereinafter referred to as "enol esters") having the generic structure: ##STR1## (which structure is intended to cover both the "cis" and the "trans" isomers thereof) wherein R.sub.1 is straight chain alkyl having 1, 3, 7 or 11 carbon atoms.

    摘要翻译: 描述了用于烟草香料和香气增强和增强组合物的方法和组合物,并且作为烟草香气和风味增加,赋予和增强一种或多种烷基侧链甲基未取代的2,2,6-三甲基-1-环己烯 - 具有一般结构的1-乙烯基链烷酸酯(以下称为“烯醇酯”):其中R1是具有1个直链烷基的直链烷基(其结构旨在涵盖“顺式”和“反式”异构体) 3,7或11个碳原子。

    Novel fragrance compositions and perfumed articles containing
alpha-substituted acetaldehyde
    7.
    发明授权
    Novel fragrance compositions and perfumed articles containing alpha-substituted acetaldehyde 失效
    新颖的香料组合物和含有α-取代乙醛的香料制品

    公开(公告)号:US4055506A

    公开(公告)日:1977-10-25

    申请号:US740949

    申请日:1976-11-11

    摘要: Processes and compositions are described for the use in perfume aroma imparting, augmenting, modifying, altering or enhancing compositions and as perfume and perfumed article aroma imparting, modifying, altering and enhancing materials of 2,2,6-trimethyl-1-cyclohexene-1-ylacetaldehyde (hereinafter referred to as "beta-cyclohomocitral") produced by a process which either (A) comprises the steps of:I. Oxidizing beta-ionone having the formula: ##STR1## with a peralkanoic acid having the formula: ##STR2## (wherein R is H, methyl or ethyl) in the presence of buffer and in the absence of dimethyl formamide, to form 2,2,6-trimethyl-1-cyclohexene-1-ylvinylacetate (hereinafter referred to as "beta-ionone enol ester") having the formula: ##STR3## and II. Hydrolyzing said beta-ionone enol ester using a basic hydrolysis agent to form beta-cyclo-homocitral having the structure: ##STR4## or (B) oxidizing beta-ionone with hydrogen peroxide in the presence of inorganic base to form beta-cyclohomocitral, directly. Addition of beta-cyclohomocitral is indicated to produce in perfumes, woody, camphoraceous, green, earthy and rosey notes, or enhance in perfume compositions and perfumed articles, floral (especially rosey) notes.

    摘要翻译: 描述了用于香料香气赋予,增加,改性,改变或增强组合物的方法和组合物,以及香料和香料制品香气赋予,改性,改性和增强2,2,6-三甲基-1-环己烯-1 (A)包括以下步骤制备的 - 乙酰基乙醛(以下称为“β-环戊氧基)”:

    Enol esters of an alpha substituted acetaldehyde fragrance compositions
    8.
    发明授权
    Enol esters of an alpha substituted acetaldehyde fragrance compositions 失效
    ALPHA替代乙酰胆碱成分组合物

    公开(公告)号:US4000090A

    公开(公告)日:1976-12-28

    申请号:US620355

    申请日:1975-10-07

    IPC分类号: A24B15/34 C11B9/00

    摘要: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma and perfume aroma augmenting, modifying, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more 2,2,6-trimethyl-1-cyclohexen-1-ylacetaldehyde enol esters (hereinafter referred to as "beta-cyclohomocitral enol esters") having the generic structure: ##STR1## (which structure is intended to cover both the "cis" and the "trans" isomers thereof) wherein R.sub.1 is C.sub.1 -C.sub.5 lower alkyl.Addition of the one or more beta-cyclohomocitral enol esters to consumable materials is indicated to produce:A. In foodstuff food flavorings, chewing gums, toothpastes and medicinal products, sweet, fruity, sweet carrot juice, ionone-like, rosey, raspberry, raspberry seed, grape and/or floral aromas with fermented tea and tobacco nuances and sweet vegetable, sweet carrot juice, sweet, fruity, raspberry, ionone-like, woody and/or raspberry kernel tastes with a sweet aftertaste;B. In tobacco, a sweet, floral, fruity, slightly fatty, aromatic tobacco aroma prior to smoking and a sweet, tobacco-like smoke aroma characteristic in the mainstream on smoking; andC. In perfumes, sweet, fruity, floral, "beta-ionone"-like notes with fermented tea and tobacco aftertastes.

    Flavoring compositions containing mixture of
2,2,6-trimethyl-1-cyclohexen-1-ylacetaldehyde and
2,6,6-trimethyl-1-crotonyl-1,3-cyclohexadiene
    9.
    发明授权
    Flavoring compositions containing mixture of 2,2,6-trimethyl-1-cyclohexen-1-ylacetaldehyde and 2,6,6-trimethyl-1-crotonyl-1,3-cyclohexadiene 失效
    含有2,2,6-三甲基-1-环己烯-1-基乙醛和2,6,6-三甲基-1-丁烯基-1,3-环己二烯的混合物的调味组合物

    公开(公告)号:US3959508A

    公开(公告)日:1976-05-25

    申请号:US598654

    申请日:1975-07-24

    摘要: Processes and compositions are described for the use in foodstuff flavor and aroma, tobacco flavor and aroma and perfume aroma augmenting, modifying, altering and enhancing compositions and as foodstuff, chewing gum, toothpaste, medicinal products, tobacco, perfume and perfumed article aroma imparting materials of mixtures of (i) 2,2,6-trimethyl-1-cyclohexen-1-ylacetaldehyde (hereinafter referred to as "beta-cyclohomocitral") and (ii) 2,6,6-trimethyl-crotonyl-1,3-cyclohexadiene having the structure: ##SPC1##Hereinafter referred to as "damascenone". Addition of mixtures beta-cyclohomocitral and damascenone is indicated to produce:A. In food flavorings, a fruity, rosey, woody, tea aroma and a woody-tea, fruity-tobacco flavor;B. In tobacco, a sweet, floral, fruity, earthy, green aroma prior to smoking and a sweet, rich, tobacco-like smoke aroma augmenting effect with woody flavoring characteristics in the mainstream on smoking; andC. In perfumes, rosey, woody, camphoraceous, green and earthy notes.

    摘要翻译: 描述了用于食品风味和香气,烟草风味和芳香和香料香气增加,改变,改变和增强组合物以及作为食品,口香糖,牙膏,药用产品,烟草,香料和香料的香气赋予材料的方法和组合物 (i)2,2,6-三甲基-1-环己烯-1-基乙醛(以下称为“β-环己基)”和(ii)2,6,6-三甲基 - 巴豆酰基-1,3- 具有以下结构的环己二烯:

    2,6,6-Trimethyl-1-cyclohexen-1-ylacetaldehyde fragrance composition
    10.
    发明授权
    2,6,6-Trimethyl-1-cyclohexen-1-ylacetaldehyde fragrance composition 失效
    2,6,6-三甲基-1-环己烯-1-基乙醛香料组合物

    公开(公告)号:US4026824A

    公开(公告)日:1977-05-31

    申请号:US598805

    申请日:1975-07-24

    摘要: Processes and compositions are described for the use in perfume aroma imparting, augmenting, modifying, altering or enhancing compositions and as perfume and perfumed article aroma imparting, modifying, altering and enhancing materials of 2,2,6-trimethyl-1-cyclohexene-1-ylacetaldehyde (hereinafter referred to as "beta-cyclohomocitral") produced by a process which either (A) comprises the steps of:I. Oxidizing beta-ionone having the formula: ##STR1## with a peralkanoic acid having the formula: ##STR2## (wherein R is H, methyl or ethyl) in the presence of buffer and in the absence of dimethyl formamide, to form 2,2,6-trimethyl-1-cyclohexene-1-ylvinylacetate (hereinafter referred to as "beta-ionone enol ester") having the formula: ##STR3## II. Hydrolyzing said beta-ionone enol ester using a basic hydrolysis agent to form beta-cyclo-homocitral having the structure: ##STR4## or (B) oxidizing beta-ionone with hydrogen peroxide in the presence of inorganic base to form beta-cyclohomocitral, directly. Addition of beta-cyclohomocitral is indicated to produce in perfumes, woody, camphoraceous, green, earthy and rosey notes, or enhance in perfume compositions and perfumed articles, floral (especially rosey) notes.

    摘要翻译: 描述了用于香料香气赋予,增加,改性,改变或增强组合物的方法和组合物,以及香料和香料制品香气赋予,改性,改性和增强2,2,6-三甲基-1-环己烯-1 (A)包括以下步骤制备的 - 乙酰基乙醛(以下称为“β-环戊氧基)”: