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1.发明授权公开(公告)号：US07550132B2
公开(公告)日：2009-06-23
申请号：US10594759
申请日：2005-03-09
CPC分类号： C01B17/05 , B01D2257/304
摘要： Process for the production of sulfur, obtained in pure form, and possibly easily disposable even at ambient temperature, starting from hydrogen sulphide contained in natural gas, which includes: a) oxidizing a portion of hydrogen sulphide to sulfur dioxide; b) dissolving in water the sulfur dioxide obtained in step (a); c) carrying out the reaction (I): 2H2S+SO2→3S+2H2O (I) making the remaining hydrogen sulphide to react with the solution prepared in step (b); and d) using the thus obtained sulfur suspension for the production sulfur or, alternatively, to use it for the disposal of the sulfur itself in a site reserved for such purpose.
摘要翻译： 即使在环境温度下也可以容易地一次性地获得硫的方法，其从天然气中所含的硫化氢开始，其包括：a）将一部分硫化氢氧化成二氧化硫; b）将在步骤（a）中获得的二氧化硫溶于水; c）进行反应（I）：2H 2 S + SO 2→3S + 2H 2 O（I），使剩余的硫化氢与步骤（b）中制备的溶液反应; 和d）使用由此获得的硫悬浮液来生产硫磺，或者用于将硫自身处置在为此目的而保留的场所中。
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2.发明申请公开(公告)号：US20070160523A1
公开(公告)日：2007-07-12
申请号：US10594759
申请日：2005-03-09
IPC分类号： C01B17/04
CPC分类号： C01B17/05 , B01D2257/304
摘要： Process for the production of sulfur, obtained in pure form, and possibly easily disposable even at ambient tem-perature, starting from hydrogen sulphide contained in natural gas, which includes: a) oxidizing a portion of hydrogen sulphide to sulfur dioxide; b) dissolving in water the sulfur dioxide obtained in step (a); c) carrying out the reaction (I): 2H2S+SO2→3S+2H20 (I) making the remaining hydrogen sulphide to react with the solution prepared in step (b); and d) using the thus obtained sulfur suspension for the production sulfur or, alternatively, to use it for the disposal of the sulfur itself in a site reserved for such purpose.
摘要翻译： 即使在环境温度下也可以容易地一次性地获得硫的方法，从天然气中所含的硫化氢开始，其包括：a）将一部分硫化氢氧化成二氧化硫; b）将在步骤（a）中获得的二氧化硫溶于水; c）进行反应（I）：2H 2 S + SO 2 - （3S）+ 2H 2 O（I）使剩余的 硫化氢与步骤（b）中制备的溶液反应; 和d）使用由此获得的硫悬浮液来生产硫磺，或者用于将硫自身处置在为此目的而保留的场所中。
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3.发明授权Process for the disposal of sulfur in the form of compounds liquid at room temperature 失效在室温下以化合物液体形式处置硫的方法公开(公告)号：US07588527B2
公开(公告)日：2009-09-15
申请号：US10562674
申请日：2004-07-06
CPC分类号： E21B41/0057 , B09B1/008 , B65G5/00
摘要： Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H2Sn+1, wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150° C.
摘要翻译： 用于处理液态硫的方法，其包括：a）将元素硫转化为具有通式H 2 Sn + 1的硫烷，其中n为1至7的数; b）任选地将粉末形式的元素硫与液体硫烷混合，直至其浓度保证混合物的可泵送性; c）将室温下的硫烷液体注入温度低于150℃的地质构造中。
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4.发明申请公开(公告)号：US20070178033A1
公开(公告)日：2007-08-02
申请号：US10588215
申请日：2005-01-20
IPC分类号： B01D53/14
CPC分类号： B01D53/52 , B01D2257/304 , C01B17/05
摘要： Hydrogen sulfide is oxidized to sulfur by means of treatment with an aqueous acid solution containing trivalent iron and a hetero polyacid having formula (I): HnXVyM(12-y)O40; or a sole hetero polyacid having formula (II): HnMeM12O40; wherein the symbols X, M Me n and y are specified in the text. At the end of the oxidation, the solution is treated with gas containing oxygen to re-oxidize the reduced metal.
摘要翻译： 通过用含有三价铁的含水酸溶液和具有式（I）的杂多酸处理将硫化氢氧化成硫：H 1 H （12-y）O 40; 或具有式（II）的单独的多元酸：H n MeM 12 O 40; 其中符号X，M Me n和y在文中指定。 在氧化结束时，用含氧的气体处理溶液以再还原还原的金属。
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5.发明申请Process for the Removal By Oxidation, of Mercaptans Contained in Hydrocarbons 有权通过氧化除去含有碳氢化合物的硫醇的方法公开(公告)号：US20080207951A1
公开(公告)日：2008-08-28
申请号：US11816755
申请日：2006-02-15
申请人： Alberto De Angelis , Paolo Pollesel
发明人： Alberto De Angelis , Paolo Pollesel
IPC分类号： C07C319/14
CPC分类号： C07C319/14 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C319/24 , C10G27/00 , C10L3/10 , C10L3/102 , C07C321/14 , B01J2523/51 , B01J2523/55 , B01J2523/68
摘要： The mercaptans R—SH contained in a hydrocarbon stream are oxidized to the corresponding (di)sulfides by means of a redox system which comprises trivalent iron and a heteropolyacid which allows the complete reoxidation of the reduced iron also with air.
摘要翻译： 通过包含三价铁和杂多酸的氧化还原体系将包含在烃流中的硫醇R-SH氧化成相应的（二）硫化物，其允许还用空气完全还原还原铁。
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6.发明申请Process for the disposal of sulfur in the form of compounds liquid at room temperature 失效在室温下以化合物液体形式处置硫的方法公开(公告)号：US20070048087A1
公开(公告)日：2007-03-01
申请号：US10562674
申请日：2004-07-06
IPC分类号： B09B3/00
CPC分类号： E21B41/0057 , B09B1/008 , B65G5/00
摘要： Process for the disposal of sulfur in the liquid state which comprises: a) transforming elemental sulfur into sulfanes having the general formula H2Sn+1, wherein n is a number from 1 to 7; b) optionally mixing elemental sulfur in powder form with the liquid sulfanes, up to such a concentration as to guarantee the pumpability of the mixture; c) injecting the sulfanes liquid at room temperature into geological formations having a temperature lower than 150° C.
摘要翻译： 处理液态硫的方法，其包括：a）将元素硫转化成具有通式H 2 S n + 1的硫烷，其中n是数 从1到7; b）任选地将粉末形式的元素硫与液体硫烷混合，直至其浓度保证混合物的可泵送性; c）将室温下的硫烷液体注入温度低于150℃的地质构造中。
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7.发明授权公开(公告)号：US07906683B2
公开(公告)日：2011-03-15
申请号：US11816755
申请日：2006-02-15
申请人： Alberto De Angelis , Paolo Pollesel
发明人： Alberto De Angelis , Paolo Pollesel
IPC分类号： C07C321/00
CPC分类号： C07C319/14 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C319/24 , C10G27/00 , C10L3/10 , C10L3/102 , C07C321/14 , B01J2523/51 , B01J2523/55 , B01J2523/68
摘要： The mercaptans R—SH contained in a hydrocarbon stream are oxidized to the corresponding (di)sulfides by means of a redox system which comprises trivalent iron and a heteropolyacid which allows the complete reoxidation of the reduced iron also with air.
摘要翻译： 通过包含三价铁和杂多酸的氧化还原体系将包含在烃流中的硫醇R-SH氧化成相应的（二）硫化物，其允许还用空气完全还原还原铁。
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8.发明授权公开(公告)号：US07553473B2
公开(公告)日：2009-06-30
申请号：US10588215
申请日：2005-01-20
CPC分类号： B01D53/52 , B01D2257/304 , C01B17/05
摘要： Hydrogen sulfide is oxidized to sulfur by means of treatment with an aqueous acid solution containing trivalent iron and a hetero polyacid having formula (I): HnXVyM(12-y)O40; or a sole hetero polyacid having formula (II): HnMeM12O40; wherein the symbols X, M Me n and y are specified in the text. At the end of the oxidation, the solution is treated with gas containing oxygen to re-oxidize the reduced metal.
摘要翻译： 通过用含有三价铁的含水酸溶液和式（I）的杂多酸（HnXVyM（12-y）O40）处理将硫化氢氧化成硫。 或具有式（II）的唯一的杂多酸：HnMeM12O40; 其中符号X，M Me n和y在文中指定。 在氧化结束时，用含氧的气体处理溶液以再还原还原的金属。
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9.发明申请PROCESS FOR THE PRODUCTION OF STABLE AQUEOUS SUSPENSIONS OF SULPHUR STARTING FROM HYDROGEN SULPHIDE AND POSSIBLE DISPOSAL OF THE SUSPENSIONS THUS OBTAINED 审中-公开从硫化氢生产硫磺起始稳定的水性悬浮液的生产工艺和可能的废弃物处理公开(公告)号：US20100210890A1
公开(公告)日：2010-08-19
申请号：US12160939
申请日：2007-03-21
IPC分类号： A62D3/30
CPC分类号： B01D53/523 , C01B17/05
摘要： Process for the production of stable sulphur suspensions starting from hydrogen sulphide contained in fossil fuels comprising: a. oxidizing an aliquot of hydrogen sulphide to sulphur dioxide; b. dissolving the sulphur dioxide thus produced in brackish water or sea water; c. effecting the reaction (I): 2H2S+SO2→→3S+2H2O by putting the remaining hydrogen sulphide in contact with the solution prepared in step (b); and d. removing the suspension thus obtained.
摘要翻译： 从化石燃料中所含的硫化氢开始生产稳定的硫悬浮液的方法，包括：a。 将硫化氢等分试样氧化成二氧化硫; b。 将由此产生的二氧化硫溶解在咸水或海水中; C。 通过将剩余的硫化氢与步骤（b）中制备的溶液接触来进行反应（I）：2H 2 S + SO 2→3S 3 + 2H 2 O; 和d。 除去由此获得的悬浮液。
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10.发明授权公开(公告)号：US07608231B2
公开(公告)日：2009-10-27
申请号：US12065909
申请日：2006-08-31
CPC分类号： B01D53/14 , B01D53/1418 , B01D53/1425 , B01D53/1468 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.
摘要翻译： 用于从含有它的气流中连续除去硫化氢的方法，包括：a）将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原性质的杂多酸; b）过滤和分离由氧化还原反应产生的硫; c）用空气将硝酸亚铁氧化成硝酸铁; d）将含有硝酸铁和杂多酸的溶液循环到氧化步骤（a）中; e）使离开氧化反应器（c）的气流经还原溶液洗涤; 和f）排出气流。
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