公开(公告)号：US20050258042A1

公开(公告)日：2005-11-24

申请号：US11100036

申请日：2005-04-06

申请人： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

发明人： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC分类号： H01G9/00 ,  H01G9/04 ,  H01G9/058 ,  H01M4/137 ,  H01M4/60 ,  H01M4/66 ,  H01M4/04

CPC分类号： H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

摘要： Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

摘要翻译： 公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。 所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。 在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。

公开(公告)号：US20050217998A1

公开(公告)日：2005-10-06

申请号：US11088509

申请日：2005-03-24

申请人： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

发明人： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC分类号： H01G9/04 ,  H01G9/155 ,  H01M4/137 ,  H01M4/60 ,  H01M4/04

CPC分类号： H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

摘要： Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5·10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

摘要翻译： 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不低于5.10〜5mol / l，（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是 双（水杨醛） - 乙二胺在希夫碱。

公开(公告)号：US20050225928A1

公开(公告)日：2005-10-13

申请号：US11098698

申请日：2005-04-04

申请人： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

发明人： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC分类号： H01G9/00 ,  H01G9/022 ,  H01G9/04 ,  H01G9/042 ,  H01G9/22 ,  H01M4/04 ,  H01M4/60

CPC分类号： H01M4/602 ,  H01G9/042 ,  H01G9/22 ,  H01G11/02 ,  H01G11/26 ,  H01G11/32 ,  H01G11/48 ,  Y02E60/13 ,  Y10T29/417

摘要： The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.

摘要翻译： 本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。 电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并​​且在电位从-3.0V到+ 1.5V（例如四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。 使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。