公开(公告)号：US20170309889A1

公开(公告)日：2017-10-26

申请号：US15523484

申请日：2015-10-23

申请人： ZEON CORPORATION

发明人： Azusa MASUDA ,  Hiroki OGURO ,  Kouichirou MAEDA

IPC分类号： H01M4/04 ,  C08F2/22 ,  C08F10/00 ,  H01M10/0525

CPC分类号： H01M4/0466 ,  C08F2/22 ,  C08F2/44 ,  C08F10/00 ,  C08F287/00 ,  H01M4/62 ,  H01M10/0525 ,  C08F212/08 ,  C08F220/18 ,  C08F220/14 ,  C08F2220/1825

摘要： The present invention relates to a binder composition for lithium-ion secondary battery electrodes. Recently, there is a need for a lithium-ion secondary battery which has the excellent property of accommodating an abnormal situation so that in cases when the battery has heated up abnormally or is in an abnormally high-temperature environment, the battery can lower the charge/discharge performance thereof. The present invention solves the above-mentioned problem by using, as a binder for electrodes, composite polymer particles obtained by polymerizing, in an aqueous medium, a monomer solution containing a polymer.

公开(公告)号：US07563354B2

公开(公告)日：2009-07-21

申请号：US11088509

申请日：2005-03-24

申请人： Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

发明人： Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC分类号： C25D9/00

CPC分类号： H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

摘要： Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5-10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

摘要翻译： 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不小于5-10-5mol / l（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双 - （水杨醛）的残基， 乙二胺在希夫的基地。

公开(公告)号：US20080061693A1

公开(公告)日：2008-03-13

申请号：US11634840

申请日：2006-12-07

申请人： Keun Soo Lee ,  Seok Hyun Jung ,  Gyung Soo Kim ,  Jong Hyung Choi ,  Jeong Seob Shim

发明人： Keun Soo Lee ,  Seok Hyun Jung ,  Gyung Soo Kim ,  Jong Hyung Choi ,  Jeong Seob Shim

IPC分类号： H01J17/49

CPC分类号： H01B1/22 ,  H01J9/02 ,  H01J11/12 ,  H01J11/22 ,  H01J11/24 ,  H01J11/44 ,  H01J2211/225 ,  H01J2211/444 ,  H01M4/0466 ,  H01M4/48 ,  H01M4/54 ,  H01M4/621

摘要： The present invention relates to an electrode paste composition, a front plate of plasma display panel, and a manufacturing method manufactured using the same. The front plate of plasma display panel comprises a front substrate, a bus electrode disposed on a predetermined position of the front substrate and a black matrix disposed in each discharge cell. The paste composition for a bus electrode comprises about 5 to 20 parts by weight of a binder, about 2 to 15 parts by weight of a photopolymerization monomer, about 1 to 8 parts by weight of a photopolymerization initiator, about 5 to 20 parts by weight of a solvent, about 1 to 10 parts by weight of a glass powder, about 50 to 80 parts by weight of a metal powder and about 0.1 to 5 parts by weight of a boron oxide (B2O3). In the paste composition and the front plate of the plasma display panel using the same according to the present invention, it can be formed a bus electrode on a substrate directly using a paste composition for electrode which is mixed a boron oxide in a silver.

摘要翻译： 电极糊组合物，等离子体显示面板的前板及其制造方法技术领域本发明涉及电极糊组合物，等离子体显示面板的前板以及使用其制造的制造方法。 等离子体显示面板的前板包括前基板，设置在前基板的预定位置的总线电极和布置在每个放电单元中的黑矩阵。 用于总线电极的糊剂组合物包含约5至20重量份的粘合剂，约2至15重量份的光聚合单体，约1至8重量份的光聚合引发剂，约5至20重量份 的溶剂，约1至10重量份的玻璃粉末，约50至80重量份的金属粉末和约0.1至5重量份的氧化硼（B 2 O 2 3 ）。 在根据本发明的使用其的等离子体显示面板的糊组合物和前板中，可以直接使用将氧化硼混合在银中的电极用糊剂组合物在基板上形成总线电极。

公开(公告)号：US07081320B2

公开(公告)日：2006-07-25

申请号：US09879227

申请日：2001-06-13

申请人： Soichiro Kawakami ,  Shinya Mishina ,  Naoya Kobayashi

发明人： Soichiro Kawakami ,  Shinya Mishina ,  Naoya Kobayashi

IPC分类号： H01M2/14 ,  H01M2/16 ,  H01M4/02 ,  H01M4/04 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/24 ,  H01M4/36 ,  H01M4/40 ,  H01M4/42 ,  H01M4/48 ,  H01M4/485 ,  H01M4/50 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/58 ,  H01M4/62 ,  H01M4/74 ,  H01M4/80 ,  H01M10/05 ,  H01M10/052 ,  H01M10/056 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/0587 ,  H01M10/24 ,  H01M10/36

CPC分类号： H01M10/05 ,  H01M2/14 ,  H01M2/1673 ,  H01M4/02 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0414 ,  H01M4/0416 ,  H01M4/0419 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/0428 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0438 ,  H01M4/045 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/24 ,  H01M4/244 ,  H01M4/36 ,  H01M4/366 ,  H01M4/38 ,  H01M4/40 ,  H01M4/42 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/581 ,  H01M4/582 ,  H01M4/62 ,  H01M4/621 ,  H01M4/622 ,  H01M4/623 ,  H01M4/625 ,  H01M4/74 ,  H01M4/742 ,  H01M4/808 ,  H01M10/052 ,  H01M10/056 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/0587 ,  H01M10/24 ,  H01M10/30 ,  H01M12/08 ,  H01M2004/027 ,  Y02E60/128 ,  Y10T29/49108

摘要： A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrites of lithium or zinc at the time of charge can be prevented, short circuiting between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of long cycle life can be manufactured.

摘要翻译： 提供具有长循环寿命且包含由锂或锌制成的负极活化材料的二次电池，该电池至少具有由用作负极活化材料的锂或锌制成的负极，电解质（电解液） 分离器，由正极活化材料制成的正极，集电电极和电池壳体，其中至少负极的表面被具有允许与电池反应相关的离子通过的结构的膜覆盖 通过。 由于可以防止在充电时锂或锌的枝晶生长，所以可以防止负极和正极之间的短路。 因此，充放电循环寿命可以显着延长。 结果，可以制造循环寿命长的锂二次电池，镍 - 锌二次电池，空气 - 锌二次电池，溴 - 锌二次电池和氧化银 - 锌二次电池。

公开(公告)号：US20050258042A1

公开(公告)日：2005-11-24

申请号：US11100036

申请日：2005-04-06

申请人： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

发明人： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC分类号： H01G9/00 ,  H01G9/04 ,  H01G9/058 ,  H01M4/137 ,  H01M4/60 ,  H01M4/66 ,  H01M4/04

CPC分类号： H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

摘要： Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

摘要翻译： 公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。 所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。 在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。

公开(公告)号：US06641759B1

公开(公告)日：2003-11-04

申请号：US09668944

申请日：2000-09-22

申请人： Gaku Harada ,  Toshihiko Nishiyama ,  Masaki Fujiwara ,  Shinako Kaneko ,  Masato Kurosaki ,  Yuuji Nakagawa

发明人： Gaku Harada ,  Toshihiko Nishiyama ,  Masaki Fujiwara ,  Shinako Kaneko ,  Masato Kurosaki ,  Yuuji Nakagawa

IPC分类号： B29C7060

CPC分类号： H01M4/0416 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/043 ,  H01M4/0433 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/624

摘要： Powder of a polymer active material 1 exhibiting an electro-chemical oxidation-reduction reaction is mixed with powder of a conductivity assisting agent 2 to obtain a mixture. The mixture is molded by a thermal press into a unitary block. Thus, a cell electrode having a large film thickness is produced without causing cracks or breakage. The electrode having a large film thickness improves the energy density of the polymer secondary cell.

摘要翻译： 将表现出电化学氧化 - 还原反应的聚合物活性材料1的粉末与导电助剂2的粉末混合，得到混合物。 混合物通过热压成型成整体块。 因此，制造具有大膜厚度的电池电极而不引起裂纹或断裂。 具有大膜厚度的电极提高了聚合物二次电池的能量密度。

公开(公告)号：US06391492B1

公开(公告)日：2002-05-21

申请号：US08482569

申请日：1995-06-07

申请人： Soichiro Kawakami ,  Shinya Mishina ,  Naoya Kobayashi

发明人： Soichiro Kawakami ,  Shinya Mishina ,  Naoya Kobayashi

IPC分类号： H01M402

CPC分类号： H01M10/05 ,  H01M2/14 ,  H01M2/1673 ,  H01M4/02 ,  H01M4/04 ,  H01M4/0402 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0414 ,  H01M4/0416 ,  H01M4/0419 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/0428 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/0438 ,  H01M4/045 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/0471 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/24 ,  H01M4/244 ,  H01M4/36 ,  H01M4/366 ,  H01M4/38 ,  H01M4/40 ,  H01M4/42 ,  H01M4/48 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/581 ,  H01M4/582 ,  H01M4/62 ,  H01M4/621 ,  H01M4/622 ,  H01M4/623 ,  H01M4/625 ,  H01M4/74 ,  H01M4/742 ,  H01M4/808 ,  H01M10/052 ,  H01M10/056 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/0587 ,  H01M10/24 ,  H01M10/30 ,  H01M12/08 ,  H01M2004/027 ,  Y02E60/128 ,  Y10T29/49108

摘要： A secondary battery exhibiting a long cycle life and comprising a negative pole activating material made of lithium or zinc is provided, the battery at least having a negative pole made of lithium or zinc serving as the negative pole activating material, an electrolyte (electrolytic solution), a separator, a positive pole made of a positive pole activating material, a collecting electrode and a battery case, wherein at least the surface of the negative pole is covered with a film having a structure which allows ions relating to the battery reactions to pass through. Since growth of dendrites of lithium or zinc at the time of charge can be prevented, short circuiting between the negative pole and the positive pole can be prevented. Therefore, the charge/discharge cycle life can significantly be lengthened. As a result, a lithium secondary battery, a nickel-zinc secondary battery, an air-zinc secondary battery, a bromine-zinc secondary battery and a silver oxide-zinc secondary battery of long cycle life can be manufactured.

摘要翻译： 提供具有长循环寿命且包含由锂或锌制成的负极活化材料的二次电池，该电池至少具有由用作负极活化材料的锂或锌制成的负极，电解质（电解液） 分离器，由正极活化材料制成的正极，集电电极和电池壳体，其中至少负极的表面被具有允许与电池反应相关的离子通过的结构的膜覆盖 通过。 由于可以防止在充电时锂或锌的枝晶生长，所以可以防止负极和正极之间的短路。 因此，充放电循环寿命可以显着延长。 结果，可以制造循环寿命长的锂二次电池，镍 - 锌二次电池，空气 - 锌二次电池，溴 - 锌二次电池和氧化银 - 锌二次电池。

公开(公告)号：US6120940A

公开(公告)日：2000-09-19

申请号：US961100

申请日：1997-10-30

申请人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer

发明人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer

IPC分类号： C08G61/12 ,  H01B1/12 ,  H01M4/04 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/14

CPC分类号： H01M4/137 ,  C08G61/126 ,  H01B1/127 ,  H01M10/052 ,  H01M10/0565 ,  H01M4/0466 ,  H01M4/1399 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  Y10T29/49108

摘要： An electrochemical storage cell or battery including as at least one electrode at least one electrically conductive polymer, the polymer being poly(1,4-bis(2-thienyl)-3-fluorophenylene), poly(1,4-bis(2-thienyl)-2,5-difluorophenylene), poly(1,4-bis(2-thienyl)-2,3,5,6-tetrafluorophenylene), or poly(1,4-bis(2-thienyl)-benzene). These polymeric electrodes have remarkably high charge capacities, and excellent cycling efficiency. The provision of these polymeric electrodes further permits the electrochemical storage cell to be substantially free of metal components, thereby improving handling of the storage cell and obviating safety and environmental concerns associated with alternative secondary battery technology.

摘要翻译： 一种电化学存储单元或电池，其包括作为至少一个电极的至少一种导电聚合物，所述聚合物是聚（1,4-双（2-噻吩基）-3-氟亚苯基），聚（1,4-双（2- 噻吩基）-2,5-二氟亚苯基），聚（1,4-双（2-噻吩基）-2,3,5,6-四氟亚苯基）或聚（1,4-双（2-噻吩基） - 苯） 。 这些聚合物电极具有非常高的充电容量，并具有优异的循环效率。 提供这些聚合物电极进一步允许电化学存储电池基本上不含金属组分，从而改善存储电池的处理并避免与替代二次电池技术相关的安全和环境问题。

公开(公告)号：US5961810A

公开(公告)日：1999-10-05

申请号：US964618

申请日：1997-11-05

申请人： Changming Li ,  Ke Keryn Lian ,  Han Wu

发明人： Changming Li ,  Ke Keryn Lian ,  Han Wu

IPC分类号： C09D5/44 ,  H01B1/12 ,  H01G9/02 ,  H01G9/025 ,  H01M4/04 ,  H01M4/66 ,  H01M4/74 ,  C23C22/78 ,  C25D5/34

CPC分类号： H01G9/025 ,  C09D5/4476 ,  H01B1/127 ,  H01B1/128 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/662 ,  H01M4/661 ,  H01M4/74

摘要： A method for making high power electrochemical charge storage devices, provides for depositing an electrically conducting polymer (16), (18), onto a non-noble metal substrate (10), which has been prepared by treatment with a surfactant. Using this method, high power, high energy electrochemical charge storage devices may be fabricated with highly reproducible low cost.

摘要翻译： 一种用于制造高功率电化学电荷存储装置的方法，提供将导电聚合物（16）（18）沉积到已经通过用表面活性剂处理制备的非贵金属基底（10）上。 使用该方法，可以以高度可重现的低成本制造高功率，高能量的电化学电荷存储装置。

公开(公告)号：US4904553A

公开(公告)日：1990-02-27

申请号：US211059

申请日：1988-06-24

申请人： Tadashi Nakajima ,  Shinichi Toyosawa ,  Shigeru Kijima ,  Katsuhiko Arai ,  Yuko Maeda ,  Masao Ogawa ,  Takahiro Kawagoe ,  Yasuhiro Iino ,  Ryuzo Osawa ,  Yuichi Ishino

发明人： Tadashi Nakajima ,  Shinichi Toyosawa ,  Shigeru Kijima ,  Katsuhiko Arai ,  Yuko Maeda ,  Masao Ogawa ,  Takahiro Kawagoe ,  Yasuhiro Iino ,  Ryuzo Osawa ,  Yuichi Ishino

IPC分类号： C08G73/02 ,  H01B1/12 ,  H01M4/60 ,  H01M4/66 ,  H01M4/74 ,  H01M10/05

CPC分类号： H01M10/05 ,  C08G73/0266 ,  H01B1/128 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/602 ,  H01M4/742 ,  H01M2004/028 ,  H01M2300/0025 ,  H01M4/661 ,  H01M4/663 ,  H01M4/669

摘要： A polyaniline is highly conductive and less corrosive when it contains up to 7 mol % of benzenoid-ammonium salt state and up to 25 mol % of quinoid-diimine state, based on the total molar amount of the polyaniline.

摘要翻译： 基于聚苯胺的总摩尔量，当其含有高达7mol％的苯甲基铵盐状态和高达25mol％的醌型二亚胺状态时，聚苯胺是高导电性和较少腐蚀性的。