公开(公告)号：US20050065364A1

公开(公告)日：2005-03-24

申请号：US10897769

申请日：2004-07-22

申请人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers ,  Michael Muskett

发明人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers ,  Michael Muskett

IPC分类号： C07C51/56 ,  C07C67/08 ,  C07C309/00 ,  C07C381/00 ,  C07C67/24 ,  C07C51/54

CPC分类号： C07C309/00 ,  C07C51/56 ,  C07C67/08 ,  C07C381/00 ,  C07C53/18 ,  C07C69/14

摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid. Optionally, water in stoichiometric amounts or less, with respect to the acetic anhydride, may be fed to a continuous process of this type to produce some acetic acid in situ.

公开(公告)号：US20050020856A1

公开(公告)日：2005-01-27

申请号：US10627254

申请日：2003-07-24

申请人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers

发明人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers

IPC分类号： C07C51/56 ,  C07C67/08 ,  C07C309/00 ,  C07C381/00 ,  C07C69/02

CPC分类号： C07C309/00 ,  C07C51/56 ,  C07C67/08 ,  C07C381/00 ,  C07C53/18 ,  C07C69/14

摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid.

摘要翻译： 通过包括在有效量的过渡金属催化剂和反应促进剂以及酸酐化合物和任选的酸的存在下，在无水环境中使甲烷和二氧化碳接触的方法制备乙酰基酸酐。 乙酸酐可以与水接触以产生乙酸或与醇反应生成包含乙酸酯并且也可以包含乙酸的产物。

公开(公告)号：US20060025628A1

公开(公告)日：2006-02-02

申请号：US10901643

申请日：2004-07-28

申请人： Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis Bell ,  John Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Lucy

发明人： Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis Bell ,  John Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Lucy

IPC分类号： C07C51/16

CPC分类号： C07C51/305 ,  C07C53/08

摘要： Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O2 to a system that includes a palladium-containing catalyst such as PdCl2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.

摘要翻译： 在选自浓硫酸和发烟硫酸的酸，含钯催化剂和促进剂，优选铜或铁盐的存在下，用含氧气体氧化甲酸来生产乙酸。 将促进剂和O 2加入到包含含钯催化剂如PdCl 2 N的体系中增加了甲烷形成乙酸的速率超过一个量级 与现有技术相比，并且还抑制了Pd黑的沉淀。

公开(公告)号：US07009074B2

公开(公告)日：2006-03-07

申请号：US10901643

申请日：2004-07-28

申请人： Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis T. Bell ,  John Glenn Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Richard Lucy

发明人： Mark Zerella ,  Sudip Mukhopadhyay ,  Alexis T. Bell ,  John Glenn Sunley ,  Sander Gaemers ,  Philip Howard ,  Brian Ellis ,  Andrew Richard Lucy

IPC分类号： C07C51/14

CPC分类号： C07C51/305 ,  C07C53/08

摘要： Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O2 to a system that includes a palladium-containing catalyst such as PdCl2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.

摘要翻译： 在选自浓硫酸和发烟硫酸的酸，含钯催化剂和促进剂，优选铜或铁盐的存在下，用含氧气体氧化甲酸来生产乙酸。 将促进剂和O 2加入到包含含钯催化剂如PdCl 2 N的体系中增加了甲烷形成乙酸的速率超过一个量级 与现有技术相比，并且还抑制了Pd黑的沉淀。

公开(公告)号：US06960682B2

公开(公告)日：2005-11-01

申请号：US10897769

申请日：2004-07-22

申请人： Alexis T. Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Glenn Sunley ,  Sander Gaemers ,  Michael James Muskett

发明人： Alexis T. Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Glenn Sunley ,  Sander Gaemers ,  Michael James Muskett

IPC分类号： C07C51/56 ,  C07C67/08 ,  C07C309/00 ,  C07C381/00 ,  C07C67/36 ,  C07C51/15

CPC分类号： C07C309/00 ,  C07C51/56 ,  C07C67/08 ,  C07C381/00 ,  C07C53/18 ,  C07C69/14

摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid. Optionally, water in stoichiometric amounts or less, with respect to the acetic anhydride, may be fed to a continuous process of this type to produce some acetic acid in situ.

摘要翻译： 通过包括在有效量的过渡金属催化剂和反应促进剂以及酸酐化合物和任选的酸的存在下，在无水环境中使甲烷和二氧化碳接触的方法制备乙酰基酸酐。 乙酸酐可以与水接触以产生乙酸或与醇反应生成包含乙酸酯并且也可以包含乙酸的产物。 任选地，相对于乙酸酐的化学计量或更少的水可以进料到这种类型的连续方法中以原位产生一些乙酸。

公开(公告)号：US20070078280A1

公开(公告)日：2007-04-05

申请号：US11242716

申请日：2005-10-03

申请人： Alexis Bell ,  Mark Zerella ,  Argyris Kahros

发明人： Alexis Bell ,  Mark Zerella ,  Argyris Kahros

IPC分类号： C07C51/16

CPC分类号： C07C51/215 ,  C07C51/305 ,  C07C53/08

摘要： Acetic acid or derivatives such as methyl acetate and acetyl sulfate, are produced from methane by contacting a methane-containing feed with an oxygen-containing gas in the presence of a palladium-containing catalyst and an acid selected from concentrated sulfuric acid and fuming sulfuric acid. The process is carried out using an oxygen partial pressure of from about 30 to about 300 psi and most preferably from about 60 to about 200 psi, a methane partial pressure of from about 100 to about 1000 psi, and most preferably from about 100 to about 400 psi, and a total pressure of oxygen and methane of from about 130 to about 1300 psi, preferably from about 200 to about 600 psi. The process is carried out in the absence of a catalyst promoter.

摘要翻译： 在含钯催化剂和选自浓硫酸和发烟硫酸的酸的存在下，使含甲烷的进料与含氧气体接触，由甲烷生产乙酸或乙酸硫酸乙酯等衍生物 。 该方法使用约30至约300psi，最优选约60至约200psi的氧分压，约100至约1000psi的甲烷分压，最优选约100至约100psi 400psi，氧气和甲烷的总压力为约130至约1300psi，优选约200至约600psi。 该方法在不存在催化剂促进剂的情况下进行。

公开(公告)号：US20110060442A1

公开(公告)日：2011-03-10

申请号：US12557381

申请日：2009-09-10

申请人： John C. Valcore, JR. ,  Mark Zerella

发明人： John C. Valcore, JR. ,  Mark Zerella

IPC分类号： G06F19/00

CPC分类号： H01L21/67253 ,  H01L21/67069 ,  H01L21/6831

摘要： A method for identifying an optimal time for mechanically removing a substrate from a lower electrode in a processing chamber of a plasma processing system is provided. The method includes employing a set of sensors to monitor a set of electrical characteristics of a plasma, wherein the plasma is formed over the substrate during a dechuck event. The method also includes sending processing data about the set of electrical characteristics to a data collection device. The method further includes comparing the processing data against a set of threshold values. The method yet also includes, if the processing data traverses the threshold values, removing the substrate from the lower electrode since a substrate-released event has occurred.

摘要翻译： 提供了一种用于识别在等离子体处理系统的处理室中从下电极机械地去除衬底的最佳时间的方法。 该方法包括采用一组传感器来监测等离子体的一组电特性，其中在脱帽事件期间在衬底上形成等离子体。 该方法还包括将关于一组电特性的处理数据发送到数据收集装置。 该方法还包括将处理数据与一组阈值进行比较。 该方法还包括，如果处理数据穿过阈值，则由于发生了衬底释放事件而从底部电极去除衬底。