摘要:
Isoprene is recovered from a C.sub.5 -hydrocarbon mixture containing isoprene, penta-1,3-diene and cyclopentadiene by separating the said mixture by liquid-liquid extraction or extractive distillation with the aid of a selective solvent, in combination with a distillation upstream or downstream from the liquid-liquid extraction or extractive distillation, by a method in which a stream containing penta-1,3-diene and cyclopentadiene is separated off in the upstream or downstream distillation and is catalytically hydrogenated, and the hydrogenated stream is fed to the upper part of the liquid-liquid extraction or extractive distillation.
摘要:
A process for isolating a conjugated diolefin from a C.sub.4 - or C.sub.5 -hydrocarbon mixture containing the diolefin, by single-stage or multi-stage extractive distillation using a selective solvent, wherein the selective solvent is a solvent mixture which comprises(a) from 1 to 99 percent by weight of an N-alkyl-substituted lower aliphatic acid amide or of an N-alkyl-substituted alicyclic acid amide having 5 ring members and(b) from 1 to 99 percent by weight of an lower aliphatic carboxylic acid ester or carbonic acid ester boiling at from 30.degree. C. to 200.degree. C.
摘要:
A process for isolating 1,3-butadiene by means of a selective solvent from a C.sub.4 -hydrocarbon mixture which contains 1,3-butadiene, propyne, hydrocarbons which are more soluble than 1,3-butadiene in the selective solvent and hydrocarbons which are less soluble than 1,3-butadiene in the selective solvent, wherein the C.sub.4 -hydrocarbon mixture is separated, using one or more extractive distillation zones, into a distillate containing the less soluble hydrocarbons, a stream of 1,3-butadiene and a stream containing the more soluble hydrocarbons, and the propyne is separated off either by distillation of the C.sub.4 -hydrocarbon mixture in a distillation zone upstream of the extractive distillation zone or zones or by distillation of the stream of 1,3-butadiene, obtained from the extractive distillation zone or zones, in a downstream distillation zone, giving a stream of hydrocarbons containing propyne and 1,3-butadiene, which stream is fed to an additional distillation zone, while at the same time a second stream of liquid or gaseous hydrocarbons is fed to the additional distillation zone, and the bottom product from the additional distillation zone is recycled to the extractive distillation.
摘要:
A process for isolating a conjugated diolefin from a C.sub.4 - or C.sub.5 -hydrocarbon mixture containing the diolefin, by single-stage or multi-stage extractive distillation using a selective solvent, wherein the selective solvent is a solvent mixture which comprises(a) from 50 to 99 percent by weight of a selective solvent boiling at from 140.degree. C. to 260.degree. C. and(b) from 1 to 50 percent by weight of an organic solvent boiling at from 45.degree. C. to 125.degree. C.
摘要:
A process for isolating isobutene from C.sub.4 -hydrocarbon mixtures containing isobutene by reacting the mixture with a primary alcohol in the presence of an acid condensing agent, to form the tertiary ether, separating off the unconverted hydrocarbons and decomposing the tertiary ether in the presence of an acid catalyst at an elevated temperature, wherein a primary C.sub.3 - or C.sub.4 -alcohol is used and the temperature at which the reaction mixture leaves the etherification stage, in which the tertiary ether is formed, is lower than the mean temperature in the etherification stage.
摘要:
A process for isolating butadiene, with the aid of a selective solvent, from a C.sub.4 -hydrocarbon mixture which contains butadiene and small amounts of styrene and may contain oxygen, hydrocarbons more soluble than butadiene in the selective solvent and hydrocarbons less soluble than butadiene in the selective solvent, in which process the C.sub.4 -hydrocarbon mixture is separated by extractive distillation into a distillate which contains the less soluble hydrocarbons, a stream of butadiene and a stream containing the more soluble hydrocarbons, and in which a mixture of styrene and C.sub.4 -hydrocarbons is removed from the C.sub.4 -hydrocarbon mixture in a distillation zone upstream of the extractive distillation, the top product of the said distillation zone being fed to the extractive distillation.
摘要:
A process for isolating a conjugated diolefin from a C.sub.4 - or C.sub.5 -hydrocarbon mixture containing the diolefin, by single-stage or multi-stage extractive distillation using a selective solvent, wherein the selective solvent is a solvent mixture which comprises(a) from 1 to 99 percent by weight of an N-alkyl-substituted lower aliphatic acid amide or of an N-alkyl-substituted alicyclic acid amide having 5 ring members and(b) from 1 to 99 percent by weight of an aliphatic or alicyclic ether boiling at from 30.degree. C. to 200.degree. C.
摘要:
A process for conjointly preparing methyl tert.-butyl ether and obtaining isobutene from an isobutene-containing C.sub.4 -hydrocarbon mixture. In the process the C.sub.4 -hydrocarbon mixture is reacted, in one or more etherification stages, with methanol and a primary C.sub.3 - or C.sub.4 -alcohol in the presence of an acid condensing agent, the resulting reaction mixture or mixtures are then separated into a fraction containing the unconverted hydrocarbons, the methyl tert.-butyl ether and a fraction containing the C.sub.3 - or C.sub.4 -alkyl tert.-butyl ether. Thereafter, the C.sub.3 - or C.sub.4 -alkyl tert.-butyl ether is decomposed at an elevated temperature, in the presence of an acid catalyst, into isobutene and primary C.sub.3 - or C.sub.4 -alcohol.
摘要:
A process for isolating butadiene by means of a selective solvent from a C.sub.4 -hydrocarbon mixture which contains butadiene, small amounts of oxygen, hydrocarbons which are more soluble than butadiene in the selective solvent and hydrocarbons which are less soluble than butadiene in the selective solvent, wherein the C.sub.4 -hydrocarbon mixture is separated, by extractive distillation, into a distillate containing the less soluble hydrocarbons, a stream of butadiene and a stream containing the more soluble hydrocarbons, a mixture of oxygen and C.sub.4 -hydrocarbons is separated out of the C.sub.4 -hydrocarbon mixture in a distillation zone upstream of the extractive distillation, and the bottom product is fed to the extractive distillation.
摘要:
A process for removing condensable aliphatic hydrocarbons and acidic gases such as H.sub.2 S, CO.sub.2 and COS from natural gas containing these, wherein the natural gas is initially treated with polyethylene glycol dialkyl ethers, as the solvent, in a first absorption stage to effect absorption of the condensable aliphatic hydrocarbons; the natural gas drawn off from the first absorption stage is then treated with polyethylene glycol dialkyl ethers, as the solvent, under superatmospheric pressure in a second absorption stage, the acidic gases being completely or partly absorbed; the solvent charged with the condensable aliphatic hydrocarbons which is obtained from the first absorption stage is treated with water in an extraction stage, to form a hydrocarbon phase containing the condensable aliphatic hydrocarbons and an aqueous dialkyl ether phase, and the hydrocarbon phase is separated from the aqueous dialkyl ether phase. The solvent charged with acid gases which is obtained from the second absorption stage is regenerated by expansion and/or stripping in a regeneration stage and the regenerated solvent is recycled to the absorption.