公开(公告)号：US20010034458A1

公开(公告)日：2001-10-25

申请号：US09854244

申请日：2001-05-11

Applicant: AlliedSignal Inc.

Inventor： Russell F. Anderson ,  David E. Bradley ,  David Nalewajek ,  Haridasan K. Nair ,  Mariola J. Proszowski ,  Eugene V. Sitzmann ,  Ellen L. Swan

IPC: C07C069/734 ,  C07C043/16

CPC classification number: C07C43/17 ,  C07C43/172 ,  C07C43/176 ,  C07C69/63 ,  C07C309/73 ,  C07C2601/14 ,  C08F8/18 ,  C08F16/26 ,  C09D11/101 ,  C09D129/10 ,  C09J4/00 ,  C09J129/10 ,  G02B6/1221 ,  G02B6/13 ,  G11B7/2531 ,  G11B7/2532 ,  G11B7/2533 ,  G11B7/2542 ,  G11B7/2545 ,  G11B7/256 ,  G11B7/2572 ,  C08F216/125

Abstract: Vinyl ether compounds having the formula:R-O-X-OnullCHnullCH2wherein R is a radical selected from R1-CnHm-, R1-CnHmnullC(nullO)null, R1-CnHmnullCHnullnullO-X-OnullCHnullCH2nullnull, R1-CnHmnullCHnull'O-X-OnullCHnullCH2nullnullC(nullO)null, R1-CnHmnullCHnullnullC(nullO)nullO-X-OnullCHnullCH2nullnull, R1-CnHmnullCHnullnullC(nullO)nullO-X-OnullCHnullCH2nullnullC(nullO)null, R1-nullCFClnullCF2nullnullpCH2null and HCFClnullCF2null, wherein R1 is hydrogen, an unsubstituted or substituted fluorinated aliphatic radical, an unsubstituted or substituted fluorinated cyclic aliphatic radical, an unsubstituted or substituted fluorinated aromatic radical, an unsubstituted or substituted fluorinated araliphatic radical, or an unsubstituted or substituted fluorinated heterocyclic radical; n is an integer between 1 and 6, inclusive; nnullmnull2n; p is an integer between 1 and 20, inclusive and X is an unsubstituted or substituted aliphatic radical, an unsubstituted or substituted cyclic aliphatic radical, an unsubstituted or substituted aromatic radical, an unsubstituted or substituted araliphatic radical, or an unsubstituted or substituted heterocyclic radical; provided that when R1 of R1-CnHmnull is an otherwise unsubstituted fluorinated aliphatic group, X is not ethylene or propylene. Curable compositions containing the vinyl ether compounds are also disclosed, as well as polymers polymerized from the vinyl ether compounds.

Abstract translation: 具有下式的乙烯基醚化合物：其中R是选自R 1 -C n H m - ，R 1 -C n H m的基团 -C（= O） - ，R1-CnHm-CH [-OXO-CH = CH2-]，R1-CnHm-CH ['OXO-CH = CH2-] C（= O） - ，R1-CnHm-CH [ -C（= O）-OXO-CH = CH 2 - ]，R 1 -C n H m -CH（-C（= O）-OXO-CH = CH 2 - ] C（= O） - ，R 1 - [CFCl-CF 2 - pCH 2 - 和HCFCl-CF 2 - ，其中R 1是氢，未取代或取代的氟化脂族基团，未取代或取代的氟代环状脂肪族基团，未取代或取代的氟化芳族基团，未取代或取代的氟化芳脂族基团， 取代的氟化杂环基; n是1和6之间的整数，包括1和6; n <= m <= 2n; p是1至20的整数，包括1和20，X是未取代或取代的脂族基团，未取代或取代的环状脂族基团，未取代或取代的芳族基团，未取代或取代的芳脂族基团，或未取代或取代的杂环基团; 条件是当R1-CnHm-的R1是另外未被取代的氟代脂族基团时，X不是乙烯或丙烯。 还公开了含有乙烯基醚化合物的可固化组合物，以及由乙烯基醚化合物聚合的聚合物。