公开(公告)号：US20110275766A1

公开(公告)日：2011-11-10

申请号：US13083696

申请日：2011-04-11

申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

IPC分类号： C08G65/46 ,  C08G65/38

CPC分类号： C08G65/46

摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

公开(公告)号：US08017716B2

公开(公告)日：2011-09-13

申请号：US12495980

申请日：2009-07-01

申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

IPC分类号： C08G65/38 ,  C08G63/02

CPC分类号： C08G65/46

摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

摘要翻译： 使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚） 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。

公开(公告)号：US20110003962A1

公开(公告)日：2011-01-06

申请号：US12495980

申请日：2009-07-01

申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

IPC分类号： C08G65/00

CPC分类号： C08G65/46

摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

摘要翻译： 使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚） 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。

公开(公告)号：US08124717B2

公开(公告)日：2012-02-28

申请号：US13083696

申请日：2011-04-11

申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

IPC分类号： C08G65/38 ,  C08G2/00

CPC分类号： C08G65/46

摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

摘要翻译： 使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚） 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。

公开(公告)号：US08722837B2

公开(公告)日：2014-05-13

申请号：US13362426

申请日：2012-01-31

申请人： Alvaro Carrillo ,  Hua Guo ,  Scott Fisher

发明人： Alvaro Carrillo ,  Hua Guo ,  Scott Fisher

IPC分类号： C08G65/38 ,  C08G77/46

CPC分类号： C08L83/12 ,  C08G65/44 ,  C08G77/46 ,  C08K5/34924 ,  C08L25/00 ,  C08L27/00 ,  C08L71/12 ,  C08L71/123 ,  C08L71/126

摘要： A composition is prepared by oxidative copolymerization of specific amounts of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and a hydroxyaryl-terminated polysiloxane. The composition exhibits an increased heat resistance relative to a corresponding composition prepared by copolymerizing 2,6-dimethylphenol and hydroxyaryl-terminated polysiloxane, without 2,3,6-trimethylphenol. The composition is useful as a flame-retardant additive in polymer compositions that require high heat resistance.

摘要翻译： 通过特定量的2,6-二甲基苯酚，2,3,6-三甲基苯酚和羟基芳基封端的聚硅氧烷的氧化共聚制备组合物。 该组合物相对于不含2,3,6-三甲基苯酚共聚2,6-二甲基苯酚和羟基芳基封端的聚硅氧烷制备的相应组合物，具有增加的耐热性。 该组合物可用作需要高耐热性的聚合物组合物中的阻燃添加剂。

公开(公告)号：US08669332B2

公开(公告)日：2014-03-11

申请号：US13169137

申请日：2011-06-27

申请人： Alvaro Carrillo ,  Hua Guo

发明人： Alvaro Carrillo ,  Hua Guo

IPC分类号： C08L71/12 ,  C08G77/46

CPC分类号： C08G77/46 ,  C08G77/16 ,  C08G77/80 ,  C08G81/00 ,  C08G2261/126 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/04

摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

摘要翻译： 包括聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

公开(公告)号：US20120329961A1

公开(公告)日：2012-12-27

申请号：US13169137

申请日：2011-06-27

申请人： Alvaro Carrillo ,  Hua Guo

发明人： Alvaro Carrillo ,  Hua Guo

IPC分类号： C08L83/12 ,  C08L71/12 ,  C08L25/06 ,  C08L77/00 ,  C08L23/02 ,  C08G77/46 ,  C08L67/00

CPC分类号： C08G77/46 ,  C08G77/16 ,  C08G77/80 ,  C08G81/00 ,  C08G2261/126 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/04

摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

摘要翻译： 包含聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

公开(公告)号：US20110190454A1

公开(公告)日：2011-08-04

申请号：US13043506

申请日：2011-03-09

申请人： Alvaro Carrillo ,  Stephen Farnell ,  Hua Guo ,  Gerardo Rocha-Galicia ,  Farah Jean-Jacques Toublan

发明人： Alvaro Carrillo ,  Stephen Farnell ,  Hua Guo ,  Gerardo Rocha-Galicia ,  Farah Jean-Jacques Toublan

IPC分类号： C08G77/46

CPC分类号： C08L71/126 ,  C08G77/46 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/00 ,  C08L2666/22

摘要： A thermoplastic composition includes a poly(arylene ether) and a poly(arylene ether)-polysiloxane block copolymer. The thermoplastic composition is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The method is simpler than prior methods of preparing poly(arylene ether)-polysiloxane block copolymers by linking pre-formed poly(arylene ether) and polysiloxane blocks. The method is also produces greater incorporation of polysiloxane into the poly(arylene ether)-polysiloxane block copolymer than prior methods of copolymerizing monohydric phenols and hydroxyaryl-terminated polysiloxane.

公开(公告)号：US20110190453A1

公开(公告)日：2011-08-04

申请号：US13043502

申请日：2011-03-09

申请人： Alvaro Carrillo ,  Stephen Farnell ,  Hua Guo ,  Gerardo Rocha-Galicia ,  Farah Jean-Jacques Toublan

发明人： Alvaro Carrillo ,  Stephen Farnell ,  Hua Guo ,  Gerardo Rocha-Galicia ,  Farah Jean-Jacques Toublan

IPC分类号： C08L83/12

CPC分类号： C08L71/126 ,  C08G77/46 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/00 ,  C08L2666/22

摘要： A thermoplastic composition includes a poly(arylene ether) and a poly(arylene ether)-polysiloxane block copolymer. The thermoplastic composition is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The method is simpler than prior methods of preparing poly(arylene ether)-polysiloxane block copolymers by linking pre-formed poly(arylene ether) and polysiloxane blocks. The method is also produces greater incorporation of polysiloxane into the poly(arylene ether)-polysiloxane block copolymer than prior methods of copolymerizing monohydric phenols and hydroxyaryl-terminated polysiloxane.

摘要翻译： 热塑性组合物包括聚（亚芳基醚）和聚（亚芳基醚） - 聚硅氧烷嵌段共聚物。 热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 该方法比通过连接预形成的聚（亚芳基醚）和聚硅氧烷嵌段制备聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的现有方法更简单。 与先前的一元酚和羟基芳基封端的聚硅氧烷的共聚方法相比，该方法还可以使聚硅氧烷更好地引入聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中。

公开(公告)号：US07541421B2

公开(公告)日：2009-06-02

申请号：US11298182

申请日：2005-12-08

申请人： Alvaro Carrillo ,  Erik René Delsman ,  Hua Guo ,  Alexey Kruglov ,  Edward N. Peters

发明人： Alvaro Carrillo ,  Erik René Delsman ,  Hua Guo ,  Alexey Kruglov ,  Edward N. Peters

IPC分类号： C08G61/02 ,  C08G65/38

CPC分类号： C08G65/44 ,  H05K1/0326

摘要： A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.

摘要翻译： 聚（亚芳基醚）共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克，平均每分子约1.8至约2个羟基。 聚（亚芳基醚）共聚物富含低分子量共聚物链和共聚物链，其包括源自二元酚的末端单元。