摘要:
The present invention describes an electrochemical cell, comprising at least an anode half-cell with an anode, a cathode half-cell with a cathode, and an ion exchange membrane arranged between the anode half-cell and the cathode half-cell, the anode and/or the cathode is a gas diffusion electrode. And a gap is provided between the gas diffusion electrode and the ion exchange membrane, and the half-cell with the gas diffusion electrode has an electrolyte feed and an electrolyte discharge as well as a gas inlet and a gas outlet. The electrochemical cell preferably has an electrolyte feed that is hermetically connected to the gap.
摘要:
The present invention describes an electrochemical cell, comprising at least an anode half-cell with an anode, a cathode half-cell with a cathode, and an ion exchange membrane arranged between the anode half-cell and the cathode half-cell, the anode and/or the cathode is a gas diffusion electrode. And a gap is provided between the gas diffusion electrode and the ion exchange membrane, and the half-cell with the gas diffusion electrode has an electrolyte feed and an electrolyte discharge as well as a gas inlet and a gas outlet. The electrochemical cell preferably has an electrolyte feed that is hermetically connected to the gap.
摘要:
The present invention provides a process for quenching a gaseous reaction mixture during the phosgenation of diamines in the gas phase to produce diisocyanates. The gaseous reaction mixture contains at least a diisocyanate, phosgene and hydrogen chloride. The quenching liquid is injected into the gas mixture continuously flowing out of a cylindrical reaction zone into the downstream cylindrical quenching zone with the aid of at least two spray nozzles which are arranged at the entrance to the quenching zone at equal distances along the circumference of the quenching zone.
摘要:
In a method for improving heat transfer in a heat exchanger, in which a heating medium passes through heat exchange elements 1,8 which transfer their heat to a liquid with which they are in contact and which is located in the jacket region 3 of the heat exchanger, the liquid between the heat exchange elements in the jacket region 3 is heated locally to such a high temperature by means of additional heating elements 2,9 that nucleate boiling occurs in the liquid on the surface of these additional heating elements 2,9 and the resulting vapour bubbles ascend between the normal heating exchange elements 1,8 in the jacket region 3. For this purpose an evaporative condenser containing vertically superimposed heat exchange elements 1,8 extending in a horizontal direction and a shell enclosing the jacket region 3 of the heat exchange elements 1,8 is provided, in which additional heating elements 2,9 connected to a heating medium circuit which is separate from the heat exchange elements 1,8 are arranged beneath the heat exchange elements 1,8, preferably in the bottom third of the vertical arrangement.