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公开(公告)号:US20240139683A1
公开(公告)日:2024-05-02
申请号:US18411415
申请日:2024-01-12
发明人: John L. BURBA
IPC分类号: B01D61/04 , B01D15/00 , B01D15/10 , B01D61/02 , B01D61/24 , B01D61/58 , B01J20/02 , B01J20/08 , B01J20/10 , B01J20/16 , B01J20/26 , C01D15/02 , C01D15/08 , C02F1/00 , C02F1/28 , C02F1/42 , C02F1/44 , C22B3/02 , C22B3/24 , C22B3/42 , C22B26/12 , C25B1/14
CPC分类号: B01D61/04 , B01D15/00 , B01D15/10 , B01D61/025 , B01D61/246 , B01D61/58 , B01J20/0281 , B01J20/0292 , B01J20/08 , B01J20/10 , B01J20/16 , B01J20/262 , C01D15/02 , C01D15/08 , C02F1/008 , C02F1/281 , C02F1/42 , C02F1/441 , C22B3/02 , C22B3/24 , C22B3/42 , C22B26/12 , C25B1/14 , B01D2311/04 , B01D2311/2626 , B01D2313/54 , C22B7/006
摘要: Apparatuses and methods for extracting desired chemical species including, without limitation, lithium, specific lithium species, and/or other chemical compounds from input flows in a modular unit. The input flows may be raw materials in which lithium metal and/or lithium species are dissolved and/or extracted. The apparatuses and methods may include daisy chain flow through separate tanks, a column array, and/or combinations thereof.
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公开(公告)号:US20240043296A1
公开(公告)日:2024-02-08
申请号:US18491445
申请日:2023-10-20
申请人: TECHWIN CO., LTD.
发明人: Jung Sik KIM , Hyun Su SHIN , Tae Woo KIM
CPC分类号: C02F1/50 , C25B1/14 , C02F2103/008
摘要: The present disclosure relates to a treatment system for ship ballast water, which comprises at least: a water supply device for supplying a water stream to a first tank storing solid raw material, and a first raw material supply device for mixing the solid raw material and the water stream to form a raw material aqueous solution; a first electrolysis unit that includes a first anode chamber for obtaining a first anode product by reacting the raw material aqueous solution, a first cathode chamber for obtaining a first cathode product by reacting water and cations provided from the first anode chamber, and a first diaphragm that separates the first anode chamber and the first cathode chamber; a reaction unit for obtaining a treatment agent by reacting the first anode product and the first cathode product; and an injection unit for providing the treatment agent to the ballast water.
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公开(公告)号:US11649170B2
公开(公告)日:2023-05-16
申请号:US16988054
申请日:2020-08-07
申请人: TERRALITHIUM LLC
发明人: Stephen Harrison
IPC分类号: C01D15/08 , C01D9/04 , C01B9/02 , C01D7/07 , C22B26/12 , C25B1/14 , C01D15/02 , C25C1/02 , C25C7/04
CPC分类号: C01D15/08 , C01B9/02 , C01D7/07 , C01D9/04 , C01D15/02 , C22B26/12 , C25B1/14 , C25C1/02 , C25C7/04 , C01P2006/80
摘要: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
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公开(公告)号:US11555251B2
公开(公告)日:2023-01-17
申请号:US17416413
申请日:2019-12-19
发明人: Saad Dara , Benjamin Zahiri
IPC分类号: C01D7/00 , C25B1/14 , C25B9/23 , C25B11/032 , C25B11/052 , C25B9/21 , B01D61/46 , B01D69/02 , C01D15/02 , C01D15/04 , C01D15/08 , C01F5/24 , C01F11/18 , C02F1/461 , C02F1/469 , C25B1/16 , C25C1/02 , C25C7/02 , C25C7/04 , C02F101/10 , C02F103/08 , C02F103/10
摘要: In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.
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公开(公告)号:US20220219119A1
公开(公告)日:2022-07-14
申请号:US17582391
申请日:2022-01-24
发明人: John Burba
IPC分类号: B01D61/04 , B01D61/58 , C25B1/14 , B01D15/10 , B01D61/24 , B01J20/02 , B01J20/08 , B01J20/10 , B01J20/26 , C22B3/02 , C22B3/24 , C22B26/12 , B01D15/00 , B01D61/02 , B01J20/16 , C01D15/02 , C01D15/08 , C02F1/00 , C02F1/42 , C02F1/28 , C02F1/44
摘要: Apparatuses and methods for extracting desired chemical species from input flows in a modular unit.
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公开(公告)号:US20220170171A1
公开(公告)日:2022-06-02
申请号:US17541172
申请日:2021-12-02
IPC分类号: C25B15/08 , C25B1/14 , C25B9/19 , C25B15/031 , C25B15/029 , C25B15/023 , B01D53/32
摘要: The present invention describes ways of increasing the production efficiency of a saline water electrolysis cell and of consuming CO2 gas and sequestering it from the atmosphere. This is achieved by the introduction of CO2 gas into the catholyte of the electrolysis, where reaction of the CO2 with the hydroxide ions present in the catholyte reduces the pH of the catholyte, thereby increasing production efficiency of the electrolysis cell. The preceding reaction forms bicarbonate and/or carbonate, thus sequestering the reactant CO2 gas from the atmosphere. The CO2 gas may be introduced either directly into the cathode area of the electrolysis cell, or into the electrolyte prior to its introduction into the electrolysis cell. Corresponding apparatus is also provided.
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公开(公告)号:US10815423B2
公开(公告)日:2020-10-27
申请号:US15555719
申请日:2016-03-02
IPC分类号: C09K11/57 , C09K11/61 , C01G23/00 , C01B33/10 , C25B15/08 , C25B1/00 , C01G25/00 , C01G29/00 , C01G35/00 , C01G33/00 , C01G19/00 , C01G17/00 , C01G45/00 , C25B1/14
摘要: A process for synthesizing a Mn4+ doped phosphor of formula I by electrolysis is presented. The process includes electrolyzing a reaction solution comprising a source of manganese, a source of M and a source of A. One aspect relates to a phosphor composition produced by the process. A lighting apparatus including the phosphor composition is also provided. Ax[MFy]:Mn4+ (I) where, A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
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公开(公告)号:US10759671B2
公开(公告)日:2020-09-01
申请号:US15570400
申请日:2016-04-29
发明人: Sung Kook Park , Kwang Seok Park , Sang Gil Lee , Woo Chul Jung , Ki Young Kim , Hyun Woo Lee
摘要: The present invention relates to a method for manufacturing lithium hydroxide and lithium carbonate, and a device therefor. The present invention provides a method for manufacturing lithium hydroxide, comprising: a step of dissolving lithium phosphate in an acid; a step of preparing a monovalent ion selective-type electrodialysis device disposed in the order of a cathode cell containing a cathode separator, a monovalent anion selective-type dialysis membrane for selectively permeating a monovalent anion, a monovalent cation selective-type dialysis membrane for selectively permeating a monovalent cation, and an anode cell containing an anode separator, injecting the lithium phosphate dissolved in the acid between the anode separator of the anode cell and the monovalent cation selective-type dialysis membrane, and between the cathode separator of the cathode cell and the monovalent anion selective-type dialysis membrane, respectively, and injecting water between the monovalent cation selective-type dialysis membrane and the monovalent anion selective-type dialysis membrane; a step of obtaining an aqueous lithium chloride solution, and at the same time, obtaining a phosphoric acid aqueous solution formed as a byproduct, by applying an electric current to the monovalent ion selective-type electrodialysis device; and a step of converting the obtained aqueous lithium chloride solution into an aqueous lithium hydroxide solution.
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公开(公告)号:US10508049B2
公开(公告)日:2019-12-17
申请号:US15976702
申请日:2018-05-10
申请人: Tesla, Inc.
IPC分类号: C02F1/469 , C02F1/461 , C02F1/44 , B01D61/44 , B01D61/46 , B01D61/54 , B01D61/58 , C02F101/10 , B01D61/02 , B01D61/14 , C25B1/14 , C25B1/22
摘要: A waste water treatment system including an electrolysis treatment system and three membrane concentration systems. The electrolysis treatment system includes a first chamber that receives waste water and produces treated waste water, a second chamber that receives first recycled water and produces dilute acid discharge, and a third chamber that receives second recycled water and produces dilute caustic discharge. An anion exchange membrane separates the first chamber from the second chamber. A cation exchange membrane separates the first chamber from the third chamber. The membrane concentration system receives the treated waste water and produces a concentrated aqueous sodium sulfate product and a pure water product. A first thermal concentration system receives the dilute acid discharge and produces first recycled water and a concentrated acid product. The second thermal concentration system receives the dilute caustic discharge and produces second recycled water and a concentrated aqueous sodium sulfate product.
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公开(公告)号:US10400349B2
公开(公告)日:2019-09-03
申请号:US15064385
申请日:2016-03-08
发明人: William J. Stewart , Matthew R. Santillanes , Kevin Schwarz , Justin Sanchez , Geofrey C. Showalter , Kyle Lee
IPC分类号: C25F1/00 , C02F1/467 , C25B15/02 , C25B15/08 , C25B9/18 , C25B1/14 , C25B1/26 , C25B9/06 , C02F1/461 , C02F1/00
摘要: Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean. For high current density cells, cleaning is preferably performed by reversing the polarity of the electrodes and applying a lower current density to the electrodes, preferably by adjusting the salinity or brine concentration of the electrolyte while keeping the voltage constant. Electrolyte flow preferably comprises water and brine flows which are preferably separately monitored and automatically adjusted. For bipolar cells, flow between modules arranged in parallel is preferably approximately equally distributed between modules and between intermediate electrodes within each module.
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