摘要:
Continuous process for preparation of polyalkylene arylates A) comprising highly branched or hyperbranched polymers B) and, if appropriate, comprising lubricants C), by esterifying or transesterifying an aromatic dicarboxylic acid or its ester or ester-forming derivatives, with a molar excess of an aliphatic dihydroxy compound, and polycondensing the resultant transesterification or esterification product, which comprises, on achievement of at least 80% of the desired viscosity number, adding component B) and also, if appropriate, C) to the polymer melt, and, if appropriate, post-condensing the melt and then discharging, cooling, and pelletizing it, and also using, as component B), at least one highly branched or hyperbranched polycarbonate B1) with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or at least one highly branched or hyperbranched polyester B2) of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these.
摘要:
Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester B) from 0.01 to 50% by weight of a highly branched or hyperbranched polyester of AxBy type where x is at least 1.1 and y is at least 2.1 C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 60% by weight of at least one graft polymer, composed of c1) from 20 to 80% by weight of a graft base composed of an elastomeric polymer based on alkyl acrylates having from 1 to 8 carbon atoms in the alkyl moiety and having a glass transition temperature below 10° C. c2) from 20 to 80% by weight of a graft composed of c21) from 60 to 95% by weight of styrene or of substituted styrenes of the general formula I where R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom, and R1 is an alkyl radical having from 1 to 8 carbon atoms, and n is 1, 2, or 3, and c22) from 5 to 40% by weight of at least one unsaturated nitrile, D) from 0 to 60% by weight of a copolymer composed of d1) from 60 to 95% by weight of styrene or of substituted styrenes of the general formula 1, or a mixture of these, d2) from 5 to 40% by weight of at least one unsaturated nitrile, E) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.
摘要翻译:热塑性成型组合物,其包含A)10至98.99重量%的至少一种热塑性聚酯,B)0.01至50重量%的B1)至少一种高度支化或超支化的聚碳酸酯,其OH值为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1,y为至少2.1,或这些的混合物,C)1至60重量%的至少一种接枝聚合物,由C 1 O 3组成),20至80%由 接枝基质的重量由基于丙烯酸烷基酯的烷基部分中具有1至8个碳原子并具有低于10℃的玻璃化转变温度的丙烯酸烷基酯的弹性体聚合物组成。c 20 C 20 重量%的由c 21 C 21组成的接枝物),60至95重量%的苯乙烯或通式I的取代苯乙烯,其中R是具有1至8个碳原子的烷基或 一个 氢原子,R 1是具有1至8个碳原子的烷基,n是1,2或3,c 22)5至40 重量%的至少一种不饱和腈,D)0至60重量%的由d-1组成的共聚物),60至95重量%的苯乙烯或一般的取代苯乙烯 式1或这些的混合物,d 2/2)5至40重量%的至少一种不饱和腈,E)0至60重量%的其它添加剂,其中总计 组分A)至E)的重量百分比为100%。
摘要:
A thermoplastic molding composition comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a mixture composed of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), and B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要翻译:一种热塑性模塑组合物,其包含A)10至99.99重量%的至少一种热塑性聚酯,B)0.01至50重量%的由B1组成的混合物,至少一种高度支化或超支化的聚碳酸酯,其具有OH数为 1至600mg KOH / g聚碳酸酯(根据DIN 53240,第2部分)和B2)至少一种高度支化或超支化的A x B B y y型聚酯 ,其中x为至少1.1,y为至少2.1,C为0至60重量%的其它添加剂,其中组分A)至C)的重量百分比的总和为100%。
摘要:
Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester B) from 0.01 to 50% by weight of a highly branched or hyperbranched polyester of AxBy type where x is at least 1.1 and y is at least 2.1 C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要翻译:热塑性模塑组合物,其包含A)10至99.99重量%的至少一种热塑性聚酯B)0.01至50重量%的A支链或超支化聚酯A B 其中x为至少1.1,y为至少2.1C)0至60重量%的其它添加剂,其中组分A)至C)的重量百分比的合计为100%。
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译:热塑性模塑组合物,其包含A)10至98重量%的至少一种热塑性聚合物,B)0.01至50重量%的B1)至少一种高度支化或超支化聚碳酸酯,其OH值为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1和y为至少2.1,或这些的混合物,C)1至40重量%的无卤阻燃剂,选自含磷或含氮化合物,或 PN缩合物,或它们的混合物,D)0至60重量%的其它添加剂,其中组分A)至D)的重量百分比的总和为100%。
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of an impact-modifying polymer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译:热塑性成型组合物,其包含A)10至98重量%的至少一种热塑性聚酯,B)0.01至50重量%的B1)至少一种高度支化或超支化聚碳酸酯,其OH数为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1和y为至少2.1,或这些的混合物,C)1至40重量%的冲击改性聚合物,D)0至60重量%的其它添加剂,其中 组分A)至D)的重量百分比为100%。
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1 or a mixture of these C) from 0.1 to 10% by weight of at least one epoxidized naturally occurring oil or fatty acid ester, or a mixture of these, and D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1 or a mixture of these C) from 0.1 to 10% by weight of at least one epoxidized naturally occurring oil or fatty acid ester, or a mixture of these, and D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.