公开(公告)号：US20080211135A1

公开(公告)日：2008-09-04

申请号：US11917487

申请日：2006-06-13

申请人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Volkel ,  Bernhard Rosenau ,  Christophe Ginss ,  Kurt Hofli

发明人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Volkel ,  Bernhard Rosenau ,  Christophe Ginss ,  Kurt Hofli

IPC分类号： B29C33/40 ,  B29C47/06

CPC分类号： B32B27/36 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  H05K1/0353 ,  Y10T428/31507 ,  Y10T428/31786 ,  C08L2666/18

摘要： Process for production of multicomponent moldings, which comprises producing a molding of which at least one layer is composed of a thermoplastic molding composition composed of A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.

摘要翻译： 制造多组分成型制品的方法，其包括制备至少一层由以下组成的热塑性模塑组合物的模制品：A）10至99.99重量％的至少一种热塑性聚酯，B）0.01至50重量％ 至少一种高度支化或超支化的聚碳酸酯，其具有OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240，Part 2）或B2）至少一种高支化或超支化聚酯A 其中x为至少1.1，y为至少2.1，或这些的混合物，C）0至60重量％的其它物质 添加剂，其中组分A）至C）的重量百分比的总和为100％。

公开(公告)号：US08445107B2

公开(公告)日：2013-05-21

申请号：US11917487

申请日：2006-06-13

申请人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Voelkel ,  Bernhard Rosenau ,  Christophe Ginss ,  Kurt Hofli

发明人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Voelkel ,  Bernhard Rosenau ,  Christophe Ginss ,  Kurt Hofli

IPC分类号： B32B27/36

CPC分类号： B32B27/36 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  H05K1/0353 ,  Y10T428/31507 ,  Y10T428/31786 ,  C08L2666/18

摘要： Process for production of multicomponent moldings, which comprises producing a molding of which at least one layer is composed of a thermoplastic molding composition composed of A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.

摘要翻译： 制造多组分成型制品的方法，其包括制备至少一层由以下组成的热塑性模塑组合物的模制品：A）10至99.99重量％的至少一种热塑性聚酯，B）0.01至50重量％ 重量比为B1）至少一种具有OH值为1至600mg KOH / g聚碳酸酯（根据DIN 53240第2部分）或B2的至少一种高度支化或超支化的聚碳酸酯，至少一种高度支化或超支化的AxBy聚酯 类型，其中x为至少1.1，y为至少2.1，或其混合物，C）0至60重量％的其它添加剂，其中组分A）至C）的重量百分比的总和） 是100％。

公开(公告)号：US20080167419A1

公开(公告)日：2008-07-10

申请号：US11996489

申请日：2006-07-13

申请人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Volkel ,  Kurt Hofli ,  Christophe Ginss

发明人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiss ,  Mark Volkel ,  Kurt Hofli ,  Christophe Ginss

IPC分类号： C08L67/00

CPC分类号： C08L67/02 ,  C08L67/00 ,  C08L67/025 ,  C08L69/00 ,  C08L101/02 ,  C08L2666/02 ,  C08L2666/18

摘要： Thermoplastic molding compositions comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 0.1 to 40% by weight of a thermoplastic polyester elastomer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.

摘要翻译： 热塑性成型组合物，其包含A）10至98.9重量％的至少一种热塑性聚酯，B）0.01至50重量％的B1）至少一种高度支化或超支化聚碳酸酯，其OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240，第2部分）或B2）至少一种高度支化或超支化的A x B B y y y型聚酯，其中x在 至少1.1和y为至少2.1，或这些的混合物，C）0.1至40重量％的热塑性聚酯弹性体，D）0至60重量％的其它添加剂，其中通过 组分A）至D）的重量为100％。

公开(公告)号：US20080292864A1

公开(公告)日：2008-11-27

申请号：US11753324

申请日：2007-05-24

申请人： Mark Volkel ,  Carsten Weiss ,  Andreas Eipper ,  Christophe Ginss ,  Gianluca Pizzati ,  Vittorio Bortolon

发明人： Mark Volkel ,  Carsten Weiss ,  Andreas Eipper ,  Christophe Ginss ,  Gianluca Pizzati ,  Vittorio Bortolon

IPC分类号： B32B3/26

CPC分类号： B32B5/18 ,  B29C44/086 ,  B29C45/0001 ,  B29C45/1676 ,  B32B27/36 ,  Y10T428/249954

摘要： An injection moulding process for making a completely recyclable, multilayered article which contains: i) a rigid layer formed of a thermoplastic polymer and ii) a foamed skin layer formed of a thermoplastic polymer compatible with the material of the rigid layer, by injection moulding of the rigid layer into a mould composed of two sides, lifting one side of the mould, or change one side of the mould to obtain a small gap of between 3 to 4 mm between the rigid layer and the side of the mould lifted or changed and injecting the foamed skin layer into the gap formed in step b).

摘要翻译： 一种用于制造完全可再循环的多层制品的注射成型方法，其包含：i）由热塑性聚合物形成的刚性层，以及ii）由与所述刚性层的材料相容的热塑性聚合物形成的泡沫表皮层， 将刚性层分成由两侧组成的模具，提升模具的一侧，或者改变模具的一侧，以在刚性层和模具的侧面提升或改变之间获得3至4mm之间的小间隙，并且 将泡沫表皮层注入步骤b）中形成的间隙中。

公开(公告)号：US20120202943A1

公开(公告)日：2012-08-09

申请号：US13446332

申请日：2012-04-13

申请人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiß ,  Mark Völkel ,  Kurt Höfli ,  Christophe Ginss

发明人： Andreas Eipper ,  Bernd Bruchmann ,  Carsten Weiß ,  Mark Völkel ,  Kurt Höfli ,  Christophe Ginss

IPC分类号： C08L67/03

CPC分类号： C08L67/02 ,  C08L67/00 ,  C08L67/025 ,  C08L69/00 ,  C08L101/02 ,  C08L2666/02 ,  C08L2666/18

摘要： Thermoplastic molding compositions comprising A) from 10 to 98.9% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 0.1 to 40% by weight of a thermoplastic polyester elastomer, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.

摘要翻译： 热塑性成型组合物，其包含A）10至98.9重量％的至少一种热塑性聚酯，B）0.01至50重量％的B1）至少一种高度支化或超支化聚碳酸酯，其OH数为1至600mg KOH / g聚碳酸酯（根据DIN 53240第2部分）或B2）至少一种AxBy型的高支化或超支化聚酯，其中x为至少1.1且y为至少2.1，或其混合物，C） 0.1至40重量％的热塑性聚酯弹性体，D）0至60重量％的其它添加剂，其中组分A）至D）的重量百分比的总和为100％。

公开(公告)号：US07976749B2

公开(公告)日：2011-07-12

申请号：US11753324

申请日：2007-05-24

申请人： Mark Völkel ,  Carsten Weiβ ,  Andreas Eipper ,  Christophe Ginss ,  Gianluca Pizzati ,  Vittorio Bortolon

发明人： Mark Völkel ,  Carsten Weiβ ,  Andreas Eipper ,  Christophe Ginss ,  Gianluca Pizzati ,  Vittorio Bortolon

IPC分类号： B32B37/00

CPC分类号： B32B5/18 ,  B29C44/086 ,  B29C45/0001 ,  B29C45/1676 ,  B32B27/36 ,  Y10T428/249954

摘要： An injection moulding process for making a completely recyclable, multilayered article which contains: i) a rigid layer formed of a thermoplastic polymer and ii) a foamed skin layer formed of a thermoplastic polymer compatible with the material of the rigid layer, by injection moulding of the rigid layer into a mould composed of two sides, lifting one side of the mould, or change one side of the mould to obtain a small gap of between 3 to 4 mm between the rigid layer and the side of the mould lifted or changed and injecting the foamed skin layer into the gap formed in step b).

摘要翻译： 一种用于制造完全可再循环的多层制品的注射成型方法，其包含：i）由热塑性聚合物形成的刚性层，以及ii）由与所述刚性层的材料相容的热塑性聚合物形成的泡沫表皮层， 将刚性层分成由两侧组成的模具，提升模具的一侧，或者改变模具的一侧，以在刚性层和模具的侧面提升或改变之间获得3至4mm之间的小间隙，并且 将泡沫表皮层注入步骤b）中形成的间隙中。

公开(公告)号：US06380306B1

公开(公告)日：2002-04-30

申请号：US09269338

申请日：1999-03-25

申请人： Peter Ittemann ,  Rainer Neumann ,  Joachim Seibring ,  Bernhard Rosenau ,  Manfred Kötting ,  Christophe Ginss ,  Norbert Güntherberg ,  Christian Meyer

发明人： Peter Ittemann ,  Rainer Neumann ,  Joachim Seibring ,  Bernhard Rosenau ,  Manfred Kötting ,  Christophe Ginss ,  Norbert Güntherberg ,  Christian Meyer

IPC分类号： C08L900

CPC分类号： C08L51/04 ,  C08L2666/02

摘要： Thermoplastic molding materials of A) from 72 to 88.5% by weight of a thermoplastic styrene or &agr;-methylstyrene polymer or copolymer, B) from 10 to 20% by weight of a first graft polymer having an average particle diameter d50 from 400 to 600 nm, having an n-butyl acrylate based rubber-elastic graft core, and a styrene or &agr;-methylstyrene (co)polymer graft shell, C) from 1.5 to 8% by weight of a second graft polymer having a bimodal particle size distribution, the average particle diameter d50 being from 25 to 200 nm and from 350 to 550 nm, having a butadiene or isoprene polymer or copolymer based rubber-elastic graft core, and a styrene or &agr;-methylstyrene (co)polymer graft shell, D) from 0 to 50% by weight of conventional additives, where the graft polymers B) and C) constitute from 11.5 to 25% by weight of components A), B) and C), and components A) to D) amount to 100% by weight.

摘要翻译： A）热塑性成型材料（A）为72〜88.5重量％的热塑性苯乙烯或α-甲基苯乙烯聚合物或共聚物，B）10〜20重量％的平均粒径d50为400〜600nm的第一接枝聚合物， 具有丙烯酸正丁酯基橡胶弹性接枝芯和苯乙烯或α-甲基苯乙烯（共）聚合物接枝壳，C）1.5至8重量％的具有双峰粒径分布的第二接枝聚合物，平均 粒径d50为25〜200nm，350〜550nm，具有丁二烯或异戊二烯聚合物或共聚物基橡胶弹性接枝芯，苯乙烯或α-甲基苯乙烯（共）聚合物接枝壳，D）为0〜 50重量％的常规添加剂，其中接枝聚合物B）和C）构成组分A），B）和C）的11.5至25重量％，组分A）至D）占100重量％。

公开(公告)号：US06605665B1

公开(公告)日：2003-08-12

申请号：US09889402

申请日：2001-07-17

申请人： Michael Fischer ,  Manfred Knoll ,  Christophe Ginss ,  Stephan Berz

发明人： Michael Fischer ,  Manfred Knoll ,  Christophe Ginss ,  Stephan Berz

IPC分类号： C08L6700

CPC分类号： C08L55/02 ,  C08L51/04 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/14 ,  C08L2666/24 ,  C08L2666/02

摘要： A process for the preparation of fiber-reinforced moldings for motor vehicles wherein the molding comprises a) from 1 to 96.86% by weight of at least one polycondensate, b) from 1 to 12% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm, c) from 1 to 12% by weight of at least one copolymer made from the following monomers, c1) from 50 to 90% by weight of at least one vinylaromatic monomer, and c2) from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, based in each case on component c, d) from 0 to 20% by weight of e) from 0.01 to 15% by weight of a polycarbonate, f) from 0.01 to 2% by weight of a carbon black, g) from 0 to 12% by weight of a polymer other than component B, h) from 0 to 20% by weight of a polyester other than component A, i) from 0.1 to 10% by weight of conventional additives, such as UV stabilizers, oxidation retarders, lubricants and mold-release agents. Moldings and composites made from these molding compositions are as described as is the use of the molding compositions, the moldings and the composites.

摘要翻译： 一种用于机动车辆的纤维增强模制品的制备方法，其中所述模制品包含a）1至96.86重量％的至少一种缩聚物，b）1至12重量％的至少一种颗粒接枝共聚物，其软相 玻璃化转变温度低于0℃，中值粒径为50-1000nm，c）1至12重量％的至少一种由以下单体制得的共聚物，c1）为50-90％ 至少一种乙烯基芳族单体的重量，和c）10至50重量％的丙烯腈和/或甲基丙烯腈，基于每种情况下基于组分c，d）0至20重量％的e）0.01至15重量％ 的聚碳酸酯，f）0.01至2重量％的炭黑，g）0至12重量％的除组分B以外的聚合物，h）0至20重量％的除组分 A，i）0.1至10重量％的常规添加剂，例如UV稳定剂，氧化延迟剂，润滑剂和脱模剂 e代理商。 由这些模塑组合物制成的模制品和复合材料与模塑组合物，模制品和复合材料的用途一样。

公开(公告)号：US06562902B1

公开(公告)日：2003-05-13

申请号：US09806146

申请日：2001-03-28

申请人： Michael Fischer ,  Manfred Knoll ,  Christophe Ginss ,  Stephan Berz

发明人： Michael Fischer ,  Manfred Knoll ,  Christophe Ginss ,  Stephan Berz

IPC分类号： C08L3302

CPC分类号： C08L55/02 ,  C08F265/04 ,  C08F279/02 ,  C08L25/08 ,  C08L25/12 ,  C08L25/14 ,  C08L51/003 ,  C08L51/06 ,  C08L67/02 ,  C08L2666/02 ,  C08L2666/14

摘要： A thermoplastic molding composition comprises, based on the total of components A to C and, if desired, D and E, which in total give 100% by weight, a) as component A, from 10 to 98% by weight of at least one aromatic polyester, b) as component B, from 1 to 50% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm, c) as component C, from 1 to 50% by weight of at least one copolymer made from the following monomers c1) as component C1, from 50 to 90% by weight of at least one vinylaromatic monomer, and c2) as component C2, from 10 to 25% by weight of acrylonitrile and/or methacrylonitrile, d) as component D, from 0 to 25% by weight of other compatible polymers hormogeneously miscible with components A and/or C or dispersible in these, and e) as component E, from 0 to 10% by weight of conventional additives, such as UV stabilizers, carbon black, pigments, oxidation retarders, lubricants and mold-release agents. Moldings made from these molding compositions and used in motor vehicle interiors are also described, as is the use of the molding compositions to produce the moldings.

摘要翻译： 根据组合物A至C的总和以及如果需要，D和E总共给出100重量％的a）作为组分A的热塑性模塑组合物包含10至98重量％的至少一种 芳族聚酯，b）作为组分B，1至50重量％的至少一种微相接枝共聚物，其软相具有低于0℃的玻璃化转变温度，其中值粒径为50-1000纳米，c） 作为组分C的1至50重量％的至少一种由以下单体制备的共聚物c1）作为组分C1，50至90重量％的至少一种乙烯基芳族单体，和c2）作为组分C2，10至25 丙烯腈和/或甲基丙烯腈的重量％，d）作为组分D，0至25重量％的其它相容性聚合物，其与组分A和/或C可以混合，或可分散在这些，ande中）作为组分E，从0至 10％重量的常规添加剂，如紫外线稳定剂，炭黑，颜料，氧化缓凝剂， 润滑剂和脱模剂。也描述了由这些模塑组合物制成并用于机动车内部的模具，以及模制组合物用于生产模制品的用途。