公开(公告)号：US07410610B2

公开(公告)日：2008-08-12

申请号：US10987887

申请日：2004-11-12

申请人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti ,  David Alan Utah ,  Alan Glen Turner

发明人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti ,  David Alan Utah ,  Alan Glen Turner

IPC分类号： B22F3/00 ,  B22F9/18

CPC分类号： F01D5/28 ,  B22F9/20 ,  B22F9/28 ,  C22C1/1031 ,  F04D29/023 ,  F05D2300/133 ,  F05D2300/174 ,  F05D2300/30 ,  F05D2300/502 ,  Y02T50/672

摘要： An article made of constituent elements is prepared by furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively contain the constituent elements. The constituent elements include a titanium-base metallic composition, boron present at a level greater than its room-temperature solid solubility limit, and, optionally, a stable-oxide-forming additive element present at a level greater than its room-temperature solid solubility limit. The precursor compounds are chemically reduced to produce a material comprising a titanium-base metallic composition having titanium boride particles therein, without melting the titanium-base metallic composition. The titanium-base metallic composition having the titanium boride particles therein is consolidated without melting.

摘要翻译： 通过提供至少一种非金属前体化合物制备由构成元素制成的制品，其中所有非金属前体化合物共同含有构成元素。 组成元素包括钛基金属组合物，以大于其室温固溶度极限的水平存在的硼，以及任选地，以大于其室温固溶度的水平存在的稳定氧化物形成添加元素 限制。 前体化合物被化学还原以产生包含其中具有钛硼化物颗粒的钛基金属组合物，而不熔化钛基金属组合物的材料。 其中具有硼化钛颗粒的钛基金属组合物被固化而不熔化。

公开(公告)号：US07842231B2

公开(公告)日：2010-11-30

申请号：US12105800

申请日：2008-04-18

申请人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Gigliotti ,  David Alan Utah ,  Alan Glen Turner

发明人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Gigliotti ,  David Alan Utah ,  Alan Glen Turner

IPC分类号： B22F3/00 ,  B22F9/18

CPC分类号： F01D5/28 ,  B22F9/20 ,  B22F9/28 ,  C22C1/1031 ,  F04D29/023 ,  F05D2300/133 ,  F05D2300/174 ,  F05D2300/30 ,  F05D2300/502 ,  Y02T50/672

摘要： An article made of constituent elements is prepared by furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively contain the constituent elements. The constituent elements include a titanium-base metallic composition, boron present at a level greater than its room-temperature solid solubility limit, and, optionally, a stable-oxide-forming additive element present at a level greater than its room-temperature solid solubility limit. The precursor compounds are chemically reduced to produce a material comprising a titanium-base metallic composition having titanium boride particles therein, without melting the titanium-base metallic composition. The titanium-base metallic composition having the titanium boride particles therein is consolidated without melting.

摘要翻译： 通过提供至少一种非金属前体化合物制备由构成元素制成的制品，其中所有非金属前体化合物共同含有构成元素。 组成元素包括钛基金属组合物，以大于其室温固溶度极限的水平存在的硼，以及任选地，以大于其室温固溶度的水平存在的稳定氧化物形成添加元素 限制。 前体化合物被化学还原以产生包含其中具有钛硼化物颗粒的钛基金属组合物，而不熔化钛基金属组合物的材料。 其中具有硼化钛颗粒的钛基金属组合物被固化而不熔化。

公开(公告)号：US08088231B2

公开(公告)日：2012-01-03

申请号：US12834046

申请日：2010-07-12

申请人： Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： C22C14/00

CPC分类号： B22F9/24 ,  B22F3/001 ,  B22F9/18 ,  B22F9/20 ,  B22F9/28 ,  C22C1/10 ,  C22C32/0031 ,  C22C2001/1089

摘要： A metallic article is prepared by first furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively containing the constituent elements of the metallic article in their respective constituent-element proportions. The constituent elements together form a titanium-base alloy having a stable-oxide-forming additive element therein, such as magnesium, calcium, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, and mixtures thereof. The stable-oxide-forming additive element forms a stable oxide in a titanium-based alloy. At least one additive element is present at a level greater than its room-temperature solid solubility limit in the titanium-base alloy. The precursor compounds are chemically reduced to produce an alloy material, without melting the alloy material. The alloy material may be consolidated. The alloy material, or consolidated metallic article, is thereafter desirably exposed to an oxygen-containing environment at a temperature greater than room temperature.

摘要翻译： 通过首先提供至少一种非金属前体化合物制备金属制品，其中所有非金属前体化合物以其各自的构成元素比例共同含有金属制品的组成元素。 组成元素一起形成其中具有稳定氧化物形成添加元素的钛基合金，例如镁，钙，钪，钇，镧，铈，镨，钕，ium，钐，铕，钆，铽，镝 ，钬，铒，ium，镱和镥，及其混合物。 稳定氧化物形成添加元素在钛基合金中形成稳定的氧化物。 在钛基合金中，至少一种添加元素的含量大于其室温固溶度极限。 前体化合物被化学还原以产生合金材料，而不熔化合金材料。 合金材料可以被固结。 之后，合金材料或固结的金属制品在大于室温的温度下暴露于含氧环境中。

公开(公告)号：US20100288075A1

公开(公告)日：2010-11-18

申请号：US12834046

申请日：2010-07-12

申请人： Andrew Philip WOODFIELD ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Andrew Philip WOODFIELD ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： C22C14/00

CPC分类号： B22F9/24 ,  B22F3/001 ,  B22F9/18 ,  B22F9/20 ,  B22F9/28 ,  C22C1/10 ,  C22C32/0031 ,  C22C2001/1089

摘要： A metallic article is prepared by first furnishing at least one nonmetallic precursor compound, wherein all of the nonmetallic precursor compounds collectively containing the constituent elements of the metallic article in their respective constituent-element proportions. The constituent elements together form a titanium-base alloy having a stable-oxide-forming additive element therein, such as magnesium, calcium, scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium, and mixtures thereof. The stable-oxide-forming additive element forms a stable oxide in a titanium-based alloy. At least one additive element is present at a level greater than its room-temperature solid solubility limit in the titanium-base alloy. The precursor compounds are chemically reduced to produce an alloy material, without melting the alloy material. The alloy material may be consolidated. The alloy material, or consolidated metallic article, is thereafter desirably exposed to an oxygen-containing environment at a temperature greater than room temperature.

摘要翻译： 通过首先提供至少一种非金属前体化合物制备金属制品，其中所有非金属前体化合物以其各自的构成元素比例共同含有金属制品的组成元素。 组成元素一起形成其中具有稳定氧化物形成添加元素的钛基合金，例如镁，钙，钪，钇，镧，铈，镨，钕，ium，钐，铕，钆，铽，镝 ，钬，铒，ium，镱和镥，及其混合物。 稳定氧化物形成添加元素在钛基合金中形成稳定的氧化物。 在钛基合金中，至少一种添加元素的含量大于其室温固溶度极限。 前体化合物被化学还原以产生合金材料，而不熔化合金材料。 合金材料可以被固结。 之后，合金材料或固结的金属制品在大于室温的温度下暴露于含氧环境中。

公开(公告)号：US07604680B2

公开(公告)日：2009-10-20

申请号：US10814965

申请日：2004-03-31

申请人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： C22B3/44 ,  C22B3/00 ,  C22B5/16 ,  C22C1/02

CPC分类号： C22B23/021 ,  C21B13/006 ,  C22B4/005 ,  C22B4/06 ,  C22B23/023 ,  C22B34/1268 ,  C22C1/00 ,  C22C1/03 ,  C22C19/056 ,  Y02P10/136

摘要： A metallic article is produced by furnishing one or more nonmetallic precursor compound comprising the metallic base nickel, cobalt, iron, iron-nickel, or iron-nickel-cobalt, and at least one alloying element. The nonmetallic precursor compound(s) are chemically reduced to produce an initial metallic particle without melting the initial metallic particle. The initial metallic particle is thereafter melted and solidified to produce the metallic article. The melted-and-solidified metal may be used in the as-cast form, or it may be converted to billet and further worked to the final form.

摘要翻译： 通过提供一种或多种包含金属基底镍，钴，铁，铁 - 镍或铁 - 镍 - 钴的非金属前体化合物和至少一种合金元素来制造金属制品。 化学还原非金属前体化合物以产生初始金属颗粒而不熔化初始金属颗粒。 然后将初始金属颗粒熔化并固化以制备金属制品。 熔融和固化的金属可以铸造形式使用，或者可以转化成坯料并进一步加工成最终形式。

公开(公告)号：US07553383B2

公开(公告)日：2009-06-30

申请号：US10423288

申请日：2003-04-25

申请人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： C21C7/00

CPC分类号： C22B5/00 ,  B22F2003/248 ,  B22F2998/00 ,  C21B13/146 ,  C21C5/56 ,  C22B9/14 ,  B22F3/12 ,  B22F3/15 ,  B22F3/17 ,  B22F3/20

摘要： A martensitic steel metallic article (20) made of metallic constituent elements is fabricated from a mixture of nonmetallic precursor compounds of the metallic constituent elements. The mixture of nonmetallic precursor compounds is chemically reduced to produce a metallic martensitic steel, without melting the metallic martensitic steel. The metallic martensitic steel is consolidated to produce a consolidated metallic article (20), without melting the metallic martensitic steel and without melting the consolidated metallic article (20).

摘要翻译： 由金属组成元素的非金属前体化合物的混合物制成由金属构成元素制成的马氏体钢金属制品（20）。 化学还原非金属前体化合物的混合物，以生产金属马氏体钢，而不熔化金属马氏体钢。 金属马氏体钢被固结以产生固结的金属制品（20），而不熔化金属马氏体钢并且不熔化固结的金属制品（20）。

公开(公告)号：US07384596B2

公开(公告)日：2008-06-10

申请号：US10896702

申请日：2004-07-22

申请人： Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： B22F3/02

CPC分类号： B22F9/20 ,  B22F3/001 ,  B22F3/02

摘要： A method for preparing a metallic article made of metallic constituent elements includes furnishing a mixture of nonmetallic precursor compounds of the metallic constituent elements. The method further includes chemically reducing the mixture of nonmetallic precursor compounds to produce an initial metallic material, without melting the initial metallic material, and consolidating the initial metallic material to produce a consolidated metallic article, without melting the initial metallic material and without melting the consolidated metallic article. A net macroscopic composition of the consolidated metallic article varies spatially according to a pre-selected pattern

摘要翻译： 制备金属构成元件金属制品的方法包括提供金属构成元素的非金属前体化合物的混合物。 该方法还包括化学还原非金属前体化合物的混合物以产生初始金属材料，而不熔化初始金属材料，并固化初始金属材料以产生固结的金属制品，而不熔化初始金属材料并且不熔化固结的 金属制品。 固结的金属制品的净肉眼组合物根据预选图案在空间上变化

公开(公告)号：US06921510B2

公开(公告)日：2005-07-26

申请号：US10350968

申请日：2003-01-22

申请人： Eric Allen Ott ,  Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti

发明人： Eric Allen Ott ,  Andrew Philip Woodfield ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti

IPC分类号： B22F3/00 ,  B22F9/28 ,  C22C1/10

CPC分类号： C22C1/10 ,  B22F3/001 ,  B22F9/28 ,  B22F2999/00

摘要： An article has a metallic matrix made of its constituent elements with a dispersoid distributed therein. The article is prepared by furnishing at least one nonmetallic matrix precursor compound. All of the nonmetallic matrix precursor compounds collectively include the constituent elements of the metallic matrix in their respective constituent-element proportions. A mixture of an initial metallic material and the dispersoid is produced. The matrix precursor compounds are chemically reduced to produce the initial metallic material, without melting the initial metallic material, and the dispersoid is distributed in the initial metallic material. The mixture of the initial metallic material and the dispersoid is consolidated to produce a consolidated article having the dispersoid distributed in the metallic matrix comprising the initial metallic material. The initial metallic material, the dispersoid, and the consolidated article are not melted during the consolidation.

摘要翻译： 一种制品具有由其组成元素制成的金属基质，其中分散有分散体。 通过提供至少一种非金属基质前体化合物制备制品。 所有非金属基质前体化合物在其各自构成元素比例中共同地包括金属基质的构成元素。 产生初始金属材料和分散质的混合物。 基质前体化合物被化学还原以产生初始金属材料，而不熔化初始金属材料，并且分散质分布在初始金属材料中。 将初始金属材料和分散质的混合物固结以产生具有分散在分布在包含初始金属材料的金属基质中的分散质的固结制品。 初始金属材料，分散质和固结制品在固结过程中不会熔化。

公开(公告)号：US10100386B2

公开(公告)日：2018-10-16

申请号：US13523941

申请日：2012-06-15

申请人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti

发明人： Andrew Philip Woodfield ,  Eric Allen Ott ,  Clifford Earl Shamblen ,  Michael Francis Xavier Gigliotti

IPC分类号： B22F1/02 ,  C22B34/12 ,  B22F3/00 ,  B22F9/18 ,  B22F9/20 ,  B22F9/28 ,  C21B13/00 ,  C21B13/14 ,  C22B5/12 ,  C22C1/04 ,  C22C1/10 ,  C22B4/06

摘要： A method for preparing an article of a base metal alloyed with an alloying element includes the steps of preparing a compound mixture by the steps of providing a chemically reducible nonmetallic base-metal precursor compound of a base metal, providing a chemically reducible nonmetallic alloying-element precursor compound of an alloying element, and thereafter mixing the base-metal precursor compound and the alloying-element precursor compound to form a compound mixture. The compound mixture is thereafter reduced to a metallic alloy, without melting the metallic alloy. The step of preparing or the step of chemically reducing includes the step of adding an other additive constituent. The metallic alloy is thereafter consolidated to produce a consolidated metallic article, without melting the metallic alloy and without melting the consolidated metallic article.

公开(公告)号：US07419528B2

公开(公告)日：2008-09-02

申请号：US10371743

申请日：2003-02-19

申请人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

发明人： Clifford Earl Shamblen ,  Andrew Philip Woodfield ,  Eric Allen Ott ,  Michael Francis Xavier Gigliotti

IPC分类号： B22F3/00

CPC分类号： B22F3/001 ,  C22C1/0433

摘要： A metallic article made of metallic constituent elements is fabricated from a mixture of nonmetallic precursor compounds of the metallic constituent elements. The mixture of nonmetallic precursor compounds contains more of a base-metal element, such as nickel, cobalt, iron, iron-nickel, and iron-nickel-cobalt than any other metallic element. The mixture of nonmetallic precursor compounds is chemically reduced to produce a metallic superalloy material, without melting the metallic superalloy material. The metallic superalloy material is consolidated to produce a consolidated metallic article, without melting the metallic superalloy material and without melting the consolidated metallic article.

摘要翻译： 由金属构成元件制成的金属制品由金属构成元素的非金属前体化合物的混合物制成。 非金属前体化合物的混合物比任何其它金属元素含有更多的贱金属元素，例如镍，钴，铁，铁 - 镍和铁 - 镍 - 钴。 化学还原非金属前体化合物的混合物以产生金属超耐热合金材料，而不熔化金属超耐热合金材料。 金属超合金材料被固结以产生固结的金属制品，而不熔化金属超合金材料，而不熔化固结的金属制品。