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1.发明授权Preparation of alternating olefin/carbon monoxide copolymers by means of a heterogeneous supported catalyst 失效通过非均相负载催化剂制备交替的烯烃/一氧化碳共聚物
公开(公告)号：US5408030A
公开(公告)日：1995-04-18
申请号：US198274
申请日：1994-02-18
CPC分类号： C08G67/02 , B01J31/1625 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2243 , B01J31/2409 , B01J2531/824 , B01J31/223
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) Pd(O.sub.2 CNEt.sub.2).sub.2 (NHET.sub.2).sub.2 supported on a solid carrier preferably constituted by hydroxylated silica,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 用于制备交替烯烃/一氧化碳（CO）共聚物的催化剂由以下组成：（a）负载在优选由羟基化二氧化硅构成的固体载体上的Pd（O 2 CNEt 2）2（NHET 2）2，（b） 或含有一个或两个能通过二价键与Pd原子连接的氮或磷原子的二齿配体，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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2.发明授权Heterogeneous catalyst for preparing alternating olefin/carbon monoxide copolymers 失效用于制备交替烯烃/一氧化碳共聚物的非均相催化剂
公开(公告)号：US5324701A
公开(公告)日：1994-06-28
申请号：US26015
申请日：1993-03-04
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) Pd(O.sub.2 CNEt.sub.2).sub.2 (NHEt.sub.2).sub.2 supported on a solid carrier preferably constituted by hydroxylated silica,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds,(c) NOBF.sub.4.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）负载在优选由羟基化二氧化硅构成的固体载体上的Pd（O 2 CNEt 2）2（NHEt 2）2，（b） 或含有一个或两个能通过二价键与Pd原子连接的氮或磷原子的二齿配体，（c）NOBF4。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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3.发明授权Catalytic system and system for copolymerizing carbon monoxide with one or more olefins 失效用于将一氧化碳与一种或多种烯烃共聚的催化体系和系统
公开(公告)号：US5346873A
公开(公告)日：1994-09-13
申请号：US29476
申请日：1993-03-11
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) at least one salt of a metal of Group IB of the Periodic System,(b) a mono or bidentate ligand base containing one or two nitrogen or phosphorus atoms capable of linking to the metal atom by means of dative bonds,(c) a mineral or organic oxidizer agent.Also disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）至少一种周期系统IB族金属的盐，（b）含有一个或多个 能够通过二价键与金属原子连接的两个氮或磷原子，（c）矿物或有机氧化剂。 还公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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4.发明授权Preparation of alternating olefin/carbon monoxide copolymers by means of a heterogeneous supported catalyst 失效通过非均相负载催化剂制备交替的烯烃/一氧化碳共聚物
公开(公告)号：US5314856A
公开(公告)日：1994-05-24
申请号：US26022
申请日：1993-03-04
CPC分类号： C08G67/02 , B01J31/1625 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2243 , B01J31/2409 , B01J2531/824 , B01J31/223
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) Pd(O.sub.2 CNEt.sub.2).sub.2 (NHET.sub.2).sub.2 supported on a solid carrier preferably constituted by hydroxylated silica,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).
摘要翻译： 用于制备交替烯烃/一氧化碳（CO）共聚物的催化剂由以下组成：（a）负载在优选由羟基化二氧化硅构成的固体载体上的Pd（O 2 CNEt 2）2（NHET 2）2，（b） 或含有一个或两个能通过二价键与Pd原子连接的氮或磷原子的二齿配体，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳（CO）的交替共聚中的用途。
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5.发明授权Homogeneous catalytic system and process for copolymerizing olefins with carbon monoxide 失效均相催化体系和烯烃与一氧化碳的共聚方法
公开(公告)号：US5369073A
公开(公告)日：1994-11-29
申请号：US29875
申请日：1993-03-11
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) at least one salt of a metal of Group IB of the Periodic System,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorus atoms capable of linking to the copper, silver or gold atom by means of dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide.
摘要翻译： 在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）至少一种周期系IB族金属的盐，（b）含有一个或多个 或能够通过二价键连接到铜，银或金原子的两个氮或磷原子，（c）矿物或有机酸。 公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳的交替共聚中的用途。
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6.发明授权Process for the preparation of N-alkyl substituted metal carbamate solutions and their use 失效制备N-烷基取代的金属氨基甲酸酯溶液及其用途的方法
公开(公告)号：US5808013A
公开(公告)日：1998-09-15
申请号：US677903
申请日：1996-07-10
申请人： Paolo Biagini , Gabriele Lugli , Fausto Calderazzo , Daniela Belli Dell'Amico , Alessandra Merigo
发明人： Paolo Biagini , Gabriele Lugli , Fausto Calderazzo , Daniela Belli Dell'Amico , Alessandra Merigo
IPC分类号： C07C269/06 , C07F5/00 , B01J31/00 , C07F7/00 , C07F9/00
CPC分类号： C07C269/06
摘要： Process for the preparation of N-alkyl substituted metal carbamate solutions characterized in that a water solution of the salt of the metal of which the corresponding carbamate is to be obtained, is reacted with an organic solution, basically consisting of an aprotic solvent and a secondary amine, saturated with carbon dioxide. The above solutions can be used as catalysts in polymerization reactions of unsaturated monomers or for supporting metals on inorganic oxides.
摘要翻译： 制备N-烷基取代的金属氨基甲酸酯溶液的方法，其特征在于将要得到相应氨基甲酸酯的金属盐的水溶液与基本上由非质子溶剂和仲 胺，饱和二氧化碳。 上述溶液可用作不饱和单体的聚合反应中的催化剂或用于在无机氧化物上负载金属的催化剂。
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公开(公告)号：US4024228A
公开(公告)日：1977-05-17
申请号：US447644
申请日：1974-03-04
摘要： Anhydrous gold trichloride is prepared by stirring a suspension of finely divided tetrachloro-auric acid, having the thionyl chloride at a temperature in the range from 20.degree. to 65.degree. C in the absence of light, whereby said tetrachloro-auric acid and thionyl chloride react to form the desired end product.
摘要翻译： 通过在不存在光的情况下搅拌具有亚硫酰氯的温度在20℃至65℃的细分四氯 - 乙酸的悬浮液来制备无水三氯化铝，由此所述四氯 - 柠檬酸和亚硫酰氯反应 以形成期望的最终产品。
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8.发明授权Silicon and aluminum N,N-dialkylcarbamates and their hydrolysis products and process for their preparation 失效硅和铝N，N-二烷基氨基甲酸酯及其水解产物及其制备方法
公开(公告)号：US5198565A
公开(公告)日：1993-03-30
申请号：US766113
申请日：1991-09-27
摘要： Silicon and aluminum N,N-dialkylcarbamates are prepared by reacting a secondary amine and CO.sub.2 with respectively a silicon and an aluminum halide in a reaction medium consisting of an organic solvent and then hydrolyzed by treatment with water in an anhydrous organic solvent.
摘要翻译： 硅和铝N，N-二烷基氨基甲酸酯通过在由有机溶剂组成的反应介质中分别具有硅和卤化铝的仲胺和CO 2反应制备，然后通过在无水有机溶剂中用水处理而水解。
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9.发明授权Silicon and aluminum N,N-dialkylcarbamates and their hydrolysis products and process for their preparation 失效硅和铝N，N-二烯基甲酸酯及其水解产物及其制备方法
公开(公告)号：US5075260A
公开(公告)日：1991-12-24
申请号：US500997
申请日：1990-03-29
摘要： Silicon and aluminium N,N-dialkylcarbamates are prepared by reacting a secondary amine and CO.sub.2 with respectively a silicon and an aluminium halide in a reaction medium consisting of an organic solvent. The respective hydrolysis products are obtained from said N,N-dialkylcarbamates by treatment with water in tetrahydrofuran.
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公开(公告)号：US5003094A
公开(公告)日：1991-03-26
申请号：US391981
申请日：1989-08-10
CPC分类号： C07F15/025 , C07F1/08 , C07F15/045 , C07F15/06 , H01M4/581
摘要： Transition metal complex sulfides containing the NH.sub.2 R.sub.2.sup.+ group are prepared by treating the hydrogen sulfide an organic solution of a carbomate having the general formula:Me.sup.z (O.sub.2 CNR.sub.2).sub.zin which Me is a transition metal and R an alkyl group.
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