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1.发明授权Proton conductors which are thermally stable over a wide range and have good proton conductivities 失效在宽范围内热稳定且具有良好质子电导率的质子导体公开(公告)号：US06264857B1
公开(公告)日：2001-07-24
申请号：US09242036
申请日：1999-07-02
申请人： Klaus-Dieter Kreuer , Annette Fuchs , Joachim Maier , Georg Frank , Thomas Soczka-Guth , Joachim Clauss
发明人： Klaus-Dieter Kreuer , Annette Fuchs , Joachim Maier , Georg Frank , Thomas Soczka-Guth , Joachim Clauss
IPC分类号： H01B100
CPC分类号： C25B13/04 , H01M2/1653 , H01M8/0289 , H01M8/08 , H01M10/02
摘要： Proton conductors comprising from 1 to 99% by weight of an acid and from 99 to 1% by weight of a nonaqueous amphoteric material which are thermally stable from −50° C. to 400° C. and have a proton conductivity of ≧10−5 S/cm. The invention further relates to membranes comprising the proton conductors of the invention, processes for preparing the membranes and their use in electrochromic cells, secondary batteries and electrochromic displays.
摘要翻译： 包含1至99重量％的酸和99至1重量％的非水性两性材料的质子导体，其在-50℃至400℃下热稳定且质子传导率≥10 -5 S / cm。 本发明还涉及包含本发明的质子导体的膜，制备膜的方法及其在电致变色电池，二次电池和电致变色显示器中的应用。
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2.发明授权Alkaline single ion conductors with high conductivity and transference number and methods for preparing the same 有权具有高导电性和转移次数的碱性单离子导体及其制备方法公开(公告)号：US09299501B2
公开(公告)日：2016-03-29
申请号：US13882535
申请日：2011-11-02
IPC分类号： H01M8/10 , H01G9/035 , H01B1/12 , H01M10/0565 , H01M10/0568 , H01M10/0569
CPC分类号： H01G9/035 , H01B1/122 , H01M8/1018 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0082
摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydrocarbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).
摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非极性极性溶剂中的步骤a）的烃低聚物或聚合物溶剂足够的时间来实现 溶剂吸收量为至少5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物具有至少10 -5 S / 室温（24℃）。
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3.发明申请ALKALINE SINGLE ION CONDUCTORS WITH HIGH CONDUCTIVITY AND TRANSFERENCE NUMBER AND METHODS FOR PREPARING THE SAME 有权具有高电导率和转移数的碱性单离子导体及其制备方法公开(公告)号：US20130216936A1
公开(公告)日：2013-08-22
申请号：US13882535
申请日：2011-11-02
IPC分类号： H01G9/035 , H01M8/10 , H01M10/0565
CPC分类号： H01G9/035 , H01B1/122 , H01M8/1018 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0082
摘要： A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydro-carbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10−5 S/cm at room temperature (24° C.).
摘要翻译： 制备具有高导电性的碱性单离子导体的方法包括：a）提供具有选自磺酸基，磺酰胺基，膦酸基或羧基的固定的酸性取代基的烃低聚物或聚合物 以其碱性离子形式，其中取代基的至少一部分酸性质子已经被碱金属阳离子交换，和b）将非氢化极性溶剂中的步骤a）的氢碳低聚物或聚合物溶剂足够的时间 以使溶剂吸收至少为5重量％，并获得溶剂化产物，其中溶剂/碱性阳离子的摩尔比为1:1至10,000:1，并且该溶剂化产物的导电率至少为10-5 在室温（24℃）下S / cm。
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4.发明申请Sulfonated Poly(Arylenes) as Hydrolytically and Thermo-Oxidatively Stable Polymers 有权磺化聚（亚芳基）作为水解和热氧化稳定的聚合物公开(公告)号：US20080207781A1
公开(公告)日：2008-08-28
申请号：US11885904
申请日：2006-03-07
CPC分类号： C08G75/20 , C08J5/2256 , C08J2381/06 , C08L81/06 , C08L2666/02
摘要： Hydrolytically and thermo-oxidatively stable sulfonated polyarylenes include the structural element —X—Ar(SO3M)n-Y—. The aromatic ring carrying the sulfonic acid group is substituted exclusively by electron-acceptor bridge groups X and Y and, if applicable, by other non-electron-donor substituents. Their synthesis and application are also included.
摘要翻译： 水解和热氧化稳定的磺化聚芳烯包括结构单元-X-Ar（SO 3 M）N - Y - 。 携带磺酸基团的芳环仅被电子受体桥基团X和Y取代，并且如果适用，被其它非电子给体取代基取代。 它们的合成和应用也包括在内。
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5.发明授权Sulfonated poly(arylenes) as hydrolytically and thermo-oxidatively stable polymers 有权磺化聚（亚芳基）作为水解和热氧化稳定的聚合物公开(公告)号：US08349993B2
公开(公告)日：2013-01-08
申请号：US11885904
申请日：2006-03-07
IPC分类号： C08G75/00
CPC分类号： C08G75/20 , C08J5/2256 , C08J2381/06 , C08L81/06 , C08L2666/02
摘要： Hydrolytically and thermo-oxidatively stable sulfonated polyarylenes include the structural element —X—Ar(SO3M)n-Y—. The aromatic ring carrying the sulfonic acid group is substituted exclusively by electron-acceptor bridge groups X and Y and, if applicable, by other non-electron-donor substituents. Their synthesis and application are also included.
摘要翻译： 水解和热氧化稳定的磺化聚芳烯包括结构单元-X-Ar（SO3M）n-Y-。 携带磺酸基团的芳环仅被电子受体桥基团X和Y取代，并且如果适用，被其它非电子给体取代基取代。 它们的合成和应用也包括在内。
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公开(公告)号：US4495078A
公开(公告)日：1985-01-22
申请号：US396953
申请日：1982-07-09
IPC分类号： C01B39/04 , C01B39/14 , C01B39/22 , C01B39/24 , C01B39/28 , C01B39/34 , C01B39/52 , C25B13/04 , C30B7/00 , H01B1/08 , H01G9/025 , H01M2/16 , H01M6/18 , H01M8/10 , H01M8/1016 , H01M10/36 , H01G9/00 , H01B1/06
CPC分类号： H01M6/18 , C25B13/04 , C30B29/34 , C30B7/00 , C30B7/005 , H01M10/0562 , H01M2/1646 , H01M8/1016
摘要： Solid proton conductors are described, which are based on zeolites having oton-containing cations and having six-member and larger rings as secondary structural groups of the zeolitic structure, and in whose crystal lattice passages a phase is present which promotes proton transport. Their use as separator material and electrolyte for electrochemical cells is also described.
摘要翻译： 描述了固体质子导体，其基于具有含质子阳离子的沸石，并且具有六个和更大的环作为沸石结构的次要结构基团，并且其晶格通道中存在促进质子转运的相。 还描述了它们用作电化学电池的隔板材料和电解质。
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公开(公告)号：US4513069A
公开(公告)日：1985-04-23
申请号：US396954
申请日：1982-07-09
CPC分类号： H01M6/185
摘要： A galvanic cell is described, having a metal oxide or metal sulfide electe and a metal electrode, and between them an electrolyte or separator, which is characterized by the fact that it contains as electrolyte a solid proton conductor, namely a zeolite having a proton-containing cation, which has in its crystal lattice passages a phase promoting proton transport.
摘要翻译： 描述了一种电池，其具有金属氧化物或金属硫化物电极和金属电极，并且在它们之间是电解质或隔膜，其特征在于，其包含作为电解质的固体质子导体，即具有质子 - 其在其晶格通道中具有促进质子转运的相。
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