公开(公告)号：US4709105A

公开(公告)日：1987-11-24

申请号：US932637

申请日：1986-11-19

申请人： Armin V. Grenacher ,  Max Strohmeyer ,  Herwig Hoffmann ,  Heinrich Elliehausen

发明人： Armin V. Grenacher ,  Max Strohmeyer ,  Herwig Hoffmann ,  Heinrich Elliehausen

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  C07C27/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/02 ,  C07C67/00 ,  C07C31/125

CPC分类号： C07C29/141

摘要： Preparation of C.sub.3 - to C.sub.25 -alkanols by catalytic hydrogenation of corresponding crude C.sub.3 - to C.sub.25 -alkanols, as obtained in the cobalt-catalyzed hydroformylation of C.sub.2 - to C.sub.24 -olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C.sub.9 -C.sub.11 - and C.sub.13 -C.sub.15 -alkanols which are used to prepare high-grade plasticizer esters.

摘要翻译： 通过在C2-至C24-烯烃的钴催化加氢甲酰基化中获得的相应的粗C3-至C25-链烷醇的催化氢化，通过在第一阶段中部分80-95％氢化转化使C3-至C25-链烷醇的制备 二氧化硅负载的镍和氧化钼催化剂，然后使用含有铜，锰，钼和任选的其它活化添加剂的钴催化剂在第二阶段完成转化。 该方法特别适用于用于制备高级增塑剂酯的C9-C11-和C13-C15-链烷醇的经济性制备。

公开(公告)号：US4479012A

公开(公告)日：1984-10-23

申请号：US363565

申请日：1982-03-30

申请人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

发明人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

IPC分类号： B01J23/00 ,  B01J23/46 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C45/81 ,  C07C45/82 ,  C07C47/02 ,  C07C67/00 ,  B01D3/14

CPC分类号： C07C45/81 ,  C07C45/50 ,  C07C45/82 ,  Y02P20/582 ,  Y10S203/06 ,  Y10S203/09

摘要： Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. FIG. 2) in which(a) this gaseous product is introduced, without being cooled or depressured, into a distillation column D,(b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed,(c) the condensate is separated, in a separator A, into a gas phase and a liquid phase,(d) the gas phase from A, after waste gas has been separated off, is again brought to the hydroformylation pressure by means of a compressor P, and is returned to the reactor as a recycle gas,(e) the liquid phase from A is returned to D, and(f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.

摘要翻译： 醛通过使用铑催化剂的方法（参见图2）从烯属不饱和化合物的加氢甲酰化的气态产物获得，其中（a）将该气态产物不经冷却或减压引入蒸馏塔D ，（b）将该塔的顶部馏分在冷凝器K中冷却，使其中含有的大部分醛缩合，（c）冷凝物在分离器A中分离成气相和液相 ，（d）在废气分离后，来自A的气相再次通过压缩机P进入加氢甲酰化反应器，并作为循环气体返回到反应器，（e）液相从 A返回到D，和（f）醛作为液体底部产物和/或作为蒸气侧流从塔D中取出。

公开(公告)号：US5026920A

公开(公告)日：1991-06-25

申请号：US433661

申请日：1989-11-08

申请人： Michael Roeper ,  Franz Merger ,  Joerg Liebe ,  Armin V. Grenacher ,  Edgar Hahl

发明人： Michael Roeper ,  Franz Merger ,  Joerg Liebe ,  Armin V. Grenacher ,  Edgar Hahl

IPC分类号： C07C47/02 ,  C07C45/50 ,  C07C45/75 ,  C07C45/82 ,  C07C45/85

CPC分类号： C07C45/82 ,  C07C45/50 ,  C07C45/75 ,  C07C45/85

摘要： Alkanals having a 2-alkyl branch are obtained from mixtures which contain the alkanals having a 2-alkyl branch in addition to n-alkanals, 3-alkylalkanals and/or further isomers by a process in whicha) the alkanal mixture is reacted with an aqueous formaldehyde solution in the presence of a secondary amine and of a carboxylic acid as a catalyst,b) the aqueous phase containing the catalyst and any unconverted excess formaldehyde is separated off andc) the alkanals having a 2-alkyl branch are isolated by distillation from the condensates of the other alkanals with formaldehyde.

摘要翻译： 具有2-烷基支链的烷烃由含有具有2-烷基支链的亚烷基的链烷烃，3-烷基链烷醇和/或其它异构体的混合物通过以下方法获得：其中a）使所述链烷醛混合物与 在仲胺和羧酸作为催化剂存在下的甲醛水溶液，b）分离含有催化剂和任何未转化的过量甲醛的水相，并且c）通过蒸馏分离具有2-烷基支链的链烷烃 从其他链烷烃与甲醛的缩合物。