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16 条记录 (耗时 0.018 秒)

    Preparation of C.sub.3 -C.sub.25 -alkanols
    1.
    发明授权
    Preparation of C.sub.3 -C.sub.25 -alkanols 失效
    制备C3-C25-链烷醇

    公开(公告)号：US4709105A

    公开(公告)日：1987-11-24

    申请号：US932637

    申请日：1986-11-19

    申请人： Armin V. Grenacher ,  Max Strohmeyer ,  Herwig Hoffmann ,  Heinrich Elliehausen

    发明人： Armin V. Grenacher ,  Max Strohmeyer ,  Herwig Hoffmann ,  Heinrich Elliehausen

    IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/88 ,  C07C27/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/02 ,  C07C67/00 ,  C07C31/125

    CPC分类号： C07C29/141

    摘要： Preparation of C.sub.3 - to C.sub.25 -alkanols by catalytic hydrogenation of corresponding crude C.sub.3 - to C.sub.25 -alkanols, as obtained in the cobalt-catalyzed hydroformylation of C.sub.2 - to C.sub.24 -olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C.sub.9 -C.sub.11 - and C.sub.13 -C.sub.15 -alkanols which are used to prepare high-grade plasticizer esters.

    摘要翻译： 通过在C2-至C24-烯烃的钴催化加氢甲酰基化中获得的相应的粗C3-至C25-链烷醇的催化氢化，通过在第一阶段中部分80-95％氢化转化使C3-至C25-链烷醇的制备 二氧化硅负载的镍和氧化钼催化剂，然后使用含有铜，锰，钼和任选的其它活化添加剂的钴催化剂在第二阶段完成转化。 该方法特别适用于用于制备高级增塑剂酯的C9-C11-和C13-C15-链烷醇的经济性制备。

    Recovery of aldehydes from hydroformylation reaction gas
    2.
    发明授权
    Recovery of aldehydes from hydroformylation reaction gas 失效
    从加氢甲酰化反应气中回收醛

    公开(公告)号：US4479012A

    公开(公告)日：1984-10-23

    申请号：US363565

    申请日：1982-03-30

    申请人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

    发明人： Karl Fischer ,  Armin V. Grenacher ,  Manfred Herr ,  Max Strohmeyer

    IPC分类号： B01J23/00 ,  B01J23/46 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C45/81 ,  C07C45/82 ,  C07C47/02 ,  C07C67/00 ,  B01D3/14

    CPC分类号： C07C45/81 ,  C07C45/50 ,  C07C45/82 ,  Y02P20/582 ,  Y10S203/06 ,  Y10S203/09

    摘要： Aldehydes are obtained from the gaseous product of the hydroformylation of olefinically unsaturated compounds using a rhodium catalyst by a process (cf. FIG. 2) in which(a) this gaseous product is introduced, without being cooled or depressured, into a distillation column D,(b) the top fraction from this column is cooled in a condenser K so that the greater part of the aldehydes contained therein is condensed,(c) the condensate is separated, in a separator A, into a gas phase and a liquid phase,(d) the gas phase from A, after waste gas has been separated off, is again brought to the hydroformylation pressure by means of a compressor P, and is returned to the reactor as a recycle gas,(e) the liquid phase from A is returned to D, and(f) the aldehydes are taken off from column D as liquid bottom products and/or as a vaporous side stream.

    摘要翻译： 醛通过使用铑催化剂的方法（参见图2）从烯属不饱和化合物的加氢甲酰化的气态产物获得，其中（a）将该气态产物不经冷却或减压引入蒸馏塔D ，（b）将该塔的顶部馏分在冷凝器K中冷却，使其中含有的大部分醛缩合，（c）冷凝物在分离器A中分离成气相和液相 ，（d）在废气分离后，来自A的气相再次通过压缩机P进入加氢甲酰化反应器，并作为循环气体返回到反应器，（e）液相从 A返回到D，和（f）醛作为液体底部产物和/或作为蒸气侧流从塔D中取出。

    Continuous hydroformylation of olefinically unsaturated compounds
    4.
    发明授权
    Continuous hydroformylation of olefinically unsaturated compounds 失效
    烯属不饱和化合物的连续加氢甲酰化

    公开(公告)号：US4778929A

    公开(公告)日：1988-10-18

    申请号：US70963

    申请日：1987-07-08

    申请人： Peter Zehner ,  Herwig Hoffmann ,  Wolfgang Richter ,  Dieter Stuetzer ,  Max Strohmeyer ,  Helmut Walz ,  Erich Weippert

    发明人： Peter Zehner ,  Herwig Hoffmann ,  Wolfgang Richter ,  Dieter Stuetzer ,  Max Strohmeyer ,  Helmut Walz ,  Erich Weippert

    IPC分类号： C07B61/00 ,  B01J31/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00

    CPC分类号： C07C45/50

    摘要： Olefinically unsaturated compounds are hydroformylated continuously, the olefin being passed into the lower region of the reactor, under from 1 to 40 bar and at from 50.degree. to 140.degree. C. with the aid of a rhodium complex as a catalyst in a hydroformylation reactor having a liquid reaction zone which occupies about 60-85% of the reactor volume, the gaseous products and reactants being removed from the hydroformylation reactor, the products being isolated and the major part of the remaining gas being recycled to the reactor by the cycle gas method, by a process in which from 20 to 80% by volume of the cycle gas is fed into the hydroformylation reactor above the liquid reaction zone and/or below the liquid surface in the top fourth of the liquid reaction zone.

    摘要翻译： 烯化不饱和化合物连续加氢甲酰化，在加氢甲酰化反应器中借助于铑络合物作为催化剂，将烯烃在1至40巴和50至140℃下进入反应器的下部区域， 占反应器体积约60-85％的液体反应区，气态产物和反应物从加氢甲酰化反应器中除去，产物被分离，剩余气体的主要部分通过循环气体法再循环到反应器 ，其中循环气体的20至80体积％被输入到液体反应区上方的加氢甲酰化反应器和/或液体反应区顶部第四个液体表面下方的流程。

    Recovery of carboxylic acids from oxo residues
    6.
    发明授权
    Recovery of carboxylic acids from oxo residues 失效
    从羰基残基中回收羧酸

    公开(公告)号：US4002539A

    公开(公告)日：1977-01-11

    申请号：US508162

    申请日：1974-09-23

    申请人： Max Strohmeyer ,  Werner Hagen ,  Heinz Hohenschutz

    发明人： Max Strohmeyer ,  Werner Hagen ,  Heinz Hohenschutz

    IPC分类号： C07C53/122 ,  C07C27/00 ,  C07C27/20 ,  C07C45/00 ,  C07C45/50 ,  C07C51/00 ,  C07C51/02 ,  C07C51/487 ,  C07C53/124 ,  C07C67/00 ,  B01D3/34

    CPC分类号： C07C51/02 ,  C07C45/50 ,  C07C51/487

    摘要： A process for isolating carboxylic acids from residues of the oxo reaction which are obtained as residues, on hydroformylation of ethylene or propylene, optionally after removing a part of the aldehydes produced, subsequent hydrogenation, treatment with aqueous alkali metal hydroxide solutions and subsequent distillation, wherein the residues are acidified with strong mineral acids to a pH of from 2-4, the acidified mixture not containing more than 5 parts by weight of water per part by weight of the carboxylic acids contained in the mixture, the organic phase is then separated off and the carboxylic acids are isolated therefrom by distillation at pressures below 150 mbar. The carboxylic acids obtained can be used as solvents or for the manufacture of esters.

    摘要翻译： 从羰基反应的残留物中分离出羧酸的方法，其作为残余物，在乙烯或丙烯的加氢甲酰化作用下，任选地在除去一部分所生成的醛后，随后氢化，用碱金属氢氧化物水溶液处理和随后的蒸馏而获得，其中 残留物用强无机酸酸化至pH为2-4，酸化混合物不含每重量份混合物中所含的羧酸5重量份以上的水，然后将有机相分离 并且通过在低于150毫巴的压力下蒸馏分离羧酸。 所得羧酸可用作溶剂或用于制备酯。

    Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents
    9.
    发明授权
    Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents 失效
    在有机溶剂中连续制造羰基钴和羰基钴钴溶液

    公开(公告)号：US3957684A

    公开(公告)日：1976-05-18

    申请号：US482251

    申请日：1974-06-24

    申请人： Max Strohmeyer ,  Hans Juergen Nienburg ,  Rudolf Kummer ,  Heinz Hohenschutz

    发明人： Max Strohmeyer ,  Hans Juergen Nienburg ,  Rudolf Kummer ,  Heinz Hohenschutz

    IPC分类号： C01G51/02 ,  C07C45/50 ,  C07C45/85 ,  B01J27/20

    CPC分类号： C07C45/50 ,  C01G51/02 ,  C07C45/85

    摘要： Solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents are prepared by treating aqueous solutions of cobalt salts with carbon monoxide and hydrogen at a temperature of from 50.degree. to 200.degree.C and a pressure of from 50 to 500 atmospheres in the presence of solvents which are sparingly water-miscible or are water-immiscible and which have a content of cobalt carbonyl, cobalt carbonyl hydride or mixtures thereof, the starting materials and the organic solvents being passed cocurrently through a zone in which a turbulent flow is maintained. The improvement includes using n-butanol as solvent. Solutions of cobalt carbonyl and cobalt carbonyl hydride in n-butanol are suitable as catalyst solutions for oxo syntheses.

    摘要翻译： 羰基钴和羰基氢化钴在有机溶剂中的溶液通过在溶剂存在下，在50至200℃的温度和50-500大气压的条件下处理钴盐与一氧化碳和氢气的水溶液来制备 其易于水混溶或与水不混溶并且具有钴羰基钴，羰基氢化钴或其混合物的含量，原料和有机溶剂并流通过维持湍流的区域。 改进之处在于使用正丁醇作为溶剂。 羰基羰基钴和羰基氢化钴在正丁醇中的溶液适合用作氧代合成的催化剂溶液。