摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n and m are each a distribution of integers, and the n units of R1—Si—X1—Ar1 and m units of R2—Si—X2—Ar2—X3-Z form either a random, an alternative, or a block copolymer; R1 and R2 comprise, each independently, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; X1, X2, and X3 comprise, each independently, a bond or a linking group; A1 and A2 are each a terminal group; Ar1 and Ar2 comprise, each independently, an aromatic group; and Z comprises a functional group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of preparing the polymeric charge transport material are described.
摘要翻译:改进的有机光感受器包括在导电基底上的导电基底和光电导元件,光导元件包括:(a)具有下式的聚合物电荷传输材料,其中n和m各自是整数分布,R的n个单元 1个-Si-X 1 -Ar 1个和m个R 2 -Si -X基团的单元, 2 -Z 2 -Z 3 -Z形成无规的,替代的或嵌段共聚物; R 1和R 2各自独立地包括烷基,烷氧基,烯基,炔基,杂环基或芳族基; X 1,X 2和X 3各自独立地包含键或连接基团; A 1< 1>和< 2< 2>各自为端基; Ar 1和Ar 2各自独立地包含芳族基团; Z包含官能团; 和(b)电荷产生化合物。 描述了相应的电子照相设备,成像方法和制备聚合物电荷传输材料的方法。
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n and m are each a distribution of integers, and the n units of R1—Si—X1—Ar1 and m units of R2—Si—X2—Ar2—X3-Z form either a random, an alternative, or a block copolymer; R1 and R2 comprise, each independently, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; X1, X2, and X3 comprise, each independently, a bond or a linking group; A1 and A2 are each a terminal group; Ar1 and Ar2 comprise, each independently, an aromatic group; and Z comprises a functional group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of preparing the polymeric charge transport material are described.
摘要翻译:改进的有机光感受器包括在导电基底上的导电基底和光电导元件,光导元件包括:(a)具有下式的聚合物电荷传输材料,其中n和m各自是整数分布,R的n个单元 1个-Si-X 1 -Ar 1个和m个R 2 -Si -X基团的单元, 2 -Z 2 -Z 3 -Z形成无规的,替代的或嵌段共聚物; R 1和R 2各自独立地包括烷基,烷氧基,烯基,炔基,杂环基或芳族基; X 1,X 2和X 3各自独立地包含键或连接基团; A 1< 1>和< 2< 2>各自为端基; Ar 1和Ar 2各自独立地包含芳族基团; Z包含官能团; 和(b)电荷产生化合物。 描述了相应的电子照相设备,成像方法和制备聚合物电荷传输材料的方法。
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar comprises an aromatic group; X comprises a bond or a linking group; and R1, R2, R3, R4, and R5 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar is an aryl group; X comprises a bond or a linking group; R1, R2, and R3 each comprise H, a carboxyl, an amino group, a halogen, an alkyl group, an acyl group, an alkoxy group, an alkylsulfanyl group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; R4 comprises H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and R5, R6, R7, and R8 each comprise an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译:改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件,光电导元件包括:(a)具有下式的电荷传输材料其中Ar是芳基; X包含键或连接基团; R 1,R 2,R 3和R 3各自包含H,羧基,氨基,卤素,烷基,酰基 烷氧基,烷基硫烷基,烯基,炔基,杂环基,芳族基或环基的一部分; R 4包括H,烷基,烯基,炔基,芳基或杂环基; R 5,R 6,R 7和R 8各自包含烷基,链烯基 ,炔基,芳基,杂环基或环基的一部分; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a bond or a —(CH2)m— group; X3 is a —(CH2)n— group; and Q1, Q2, and Q3 are, each independently, O, S, or NR where R is H, an alkyl group, an acyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, R4, R5, and R6 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a —(CH2)n— group, where n is an integer between 1 and 10, inclusive; p1 X3 is linking group; and Q1, Q2, Q3, Q4, Q5, and Q6 are, each independently, O, S, NR, NC(═O)R′ where R and R′ are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译:改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件,光电导元件包括:(a)具有下式的电荷传输材料:其中R 1,R 2, R 3,R 3,R 4,R 5和R 6各自独立地包含H, 烷基,烯基,炔基,芳基或杂环基; X 1和X 2各自独立地为 - (CH 2)n - n - ,其中n 是1到10之间的整数,包括1和10; p1 X 3是连接基团; 和Q 1,Q 2,Q 3,Q 4,Q 5, 和Q 6各自独立地为O,S,NR,NC(-O)R',其中R和R'各自独立地为H,烷基,烯基, 炔基,杂环基或芳基; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
摘要:
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X1 and X2 are, independently, a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR5 group, a CHR6 group, or a CR7R8 group where R4, R5, R6, and R7 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and Y1, Y2, and Y3 are, independently, an arylamine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
摘要翻译:改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件,光电导元件包括:(a)具有下式的电荷传输材料:其中R 1,R 2, R 3,R 3和R 4独立地是H,烷基,烷芳基或芳基; X 1和X 2独立地是具有下式的连接基团 - (CH 2 CH 2)m - 支链或直链,其中m是1至20的整数,包括1和20,并且一个或多个亚甲基任选被O,S,CO,OSO,杂环基,芳族基团,氨基甲酸酯,脲, 酯基团,NR 5基团,CHR 6 N基团或CR 7 R 8 N基团,其中R R 5,R 5,R 6和R 7独立地是H,羟基,硫醇基 ,烷基,烷芳基,杂环基或芳基; 和Y 1,Y 2和Y 3独立地是芳基胺基; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
摘要:
Improved charge transport material comprises the formula: where M comprises a metallocenyl group; Y comprises a functional group selected from the group consisting of a metallocenyl group, a hydrazone group, an azine group, a reactive ring group, an ethylenically unsaturated group, and combinations thereof; R1 and R2 comprise, each independently, H, an organic group, or an organometallic group; and X is a bond, O, S, an aminylene group, a sulfonyl group, an organic linking group, or a combination thereof.
摘要翻译:改进的电荷传输材料包括下式:其中M包括金属茂基; Y包括选自茂金属基,腙基,吖嗪基,反应性环基,烯属不饱和基团及其组合的官能团; R 1和R 2各自独立地包含H,有机基团或有机金属基团; 并且X为键,O,S,亚氨基,磺酰基,有机连接基或其组合。
摘要:
Improved charge transport material comprises the formula: where M comprises a metallocenyl group; Y comprises a functional group selected from the group consisting of a metallocenyl group, a hydrazone group, an azine group, a reactive ring group, an ethylenically unsaturated group, and combinations thereof; R1 and R2 comprise, each independently, H, an organic group, or an organometallic group; and X is a bond, O, S, an aminylene group, a sulfonyl group, an organic linking group, or a combination thereof.
摘要翻译:改进的电荷传输材料包括下式:其中M包括金属茂基; Y包括选自茂金属基,腙基,吖嗪基,反应性环基,烯属不饱和基团及其组合的官能团; R 1和R 2各自独立地包含H,有机基团或有机金属基团; 并且X为键,O,S,亚氨基,磺酰基,有机连接基或其组合。
摘要:
A photoreceptor with good mechanical and physical properties is provided with an overcoat layer comprising a copolymer of an α,β-ethylenically unsaturated carboxylic acid and an α,β-ethylenically unsaturated monomer wherein the weight percent of the α,β-ethylenically unsaturated carboxylic-acid is at least 25% up to 99% of the copolymer. The copolymer may comprise an α,β-ethylenically unsaturated carboxylic acid and an α,β-ethylenically unsaturated monomer wherein the copolymer has an acid value of at least 150 mg KOH/g the copolymer. The copolymer may be present in a blend with a second polymer or copolymer comprised of units derived from a second α,β-ethylenically unsaturated monomer that is different from the an α,β-ethylenically unsaturated carboxylic acid and/or the α,β-ethylenically unsaturated monomer. The copolymer or the copolymer blend may be present in a layer that is crosslinked or crosslinkable, the crosslinking being effected through a distinct crosslinking agent that reacts with group(s) on the an α,β-ethylenically unsaturated carboxylic acid or the α,β-ethylenically unsaturated monomer.